Chemistry: An Atoms-Focused Approach
14th Edition
ISBN: 9780393912340
Author: Thomas R. Gilbert, Rein V. Kirss, Natalie Foster
Publisher: W. W. Norton & Company
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Question
Chapter 4, Problem 4.166QA
Interpretation Introduction
To Draw:
The complete Lewis structure based on the given skeleton of P4S3 molecule.
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The conversion of (CH3)3CI to (CH3)2C=CH2 can occur by either a one-step or a two-step mechanism, as shown in
Equations [1] and [2].
[1]
+ I +
H₂Ö:
:OH
[2]
q
slow
:OH
+ I¯
H₂Ö:
a. What rate equation would be observed for the mechanism in Equation [1]?
b. What rate equation would be observed for the mechanism in Equation [2]?
c. What is the order of each rate equation (i.e., first, second, and so forth)?
d. How can these rate equations be used to show which mechanism is the right one for this reaction?
e. Assume Equation [1] represents an endothermic reaction and draw an energy diagram for the reaction. Label the
axes, reactants, products, Ea, and AH°. Draw the structure for the transition state.
f. Assume Equation [2] represents an endothermic reaction and that the product of the rate-determining step is higher
in energy than the reactants or products. Draw an energy diagram for this two-step reaction. Label the axes,
reactants and products for each step, and the Ea and AH° for each…
Steps and explanations. Also provide, if possible, ways to adress this kind of problems in general.
Steps and explanations. Also provide, if possible, ways to adress this kind of problems in general.
Chapter 4 Solutions
Chemistry: An Atoms-Focused Approach
Ch. 4 - Prob. 4.3VPCh. 4 - Prob. 4.4VPCh. 4 - Prob. 4.8VPCh. 4 - Prob. 4.9VPCh. 4 - Prob. 4.10VPCh. 4 - Prob. 4.11VPCh. 4 - Prob. 4.12VPCh. 4 - Prob. 4.13QACh. 4 - Prob. 4.14QACh. 4 - Prob. 4.15QA
Ch. 4 - Prob. 4.16QACh. 4 - Prob. 4.17QACh. 4 - Prob. 4.18QACh. 4 - Prob. 4.19QACh. 4 - Prob. 4.20QACh. 4 - Prob. 4.21QACh. 4 - Prob. 4.22QACh. 4 - Prob. 4.23QACh. 4 - Prob. 4.24QACh. 4 - Prob. 4.25QACh. 4 - Prob. 4.26QACh. 4 - Prob. 4.27QACh. 4 - Prob. 4.28QACh. 4 - Prob. 4.29QACh. 4 - Prob. 4.30QACh. 4 - Prob. 4.31QACh. 4 - Prob. 4.32QACh. 4 - Prob. 4.33QACh. 4 - Prob. 4.34QACh. 4 - Prob. 4.35QACh. 4 - Prob. 4.36QACh. 4 - Prob. 4.37QACh. 4 - Prob. 4.38QACh. 4 - Prob. 4.39QACh. 4 - Prob. 4.40QACh. 4 - Prob. 4.41QACh. 4 - Prob. 4.42QACh. 4 - Prob. 4.43QACh. 4 - Prob. 4.44QACh. 4 - Prob. 4.45QACh. 4 - Prob. 4.46QACh. 4 - Prob. 4.49QACh. 4 - Prob. 4.50QACh. 4 - Prob. 4.51QACh. 4 - Prob. 4.52QACh. 4 - Prob. 4.53QACh. 4 - Prob. 4.54QACh. 4 - Prob. 4.55QACh. 4 - Prob. 4.56QACh. 4 - Prob. 4.57QACh. 4 - Prob. 4.58QACh. 4 - Prob. 4.59QACh. 4 - Prob. 4.60QACh. 4 - Prob. 4.61QACh. 4 - Prob. 4.62QACh. 4 - Prob. 4.63QACh. 4 - Prob. 4.64QACh. 4 - Prob. 4.66QACh. 4 - Prob. 4.67QACh. 4 - Prob. 4.68QACh. 4 - Prob. 4.69QACh. 4 - Prob. 4.70QACh. 4 - Prob. 4.71QACh. 4 - Prob. 4.72QACh. 4 - Prob. 4.73QACh. 4 - Prob. 4.74QACh. 4 - Prob. 4.75QACh. 4 - Prob. 4.76QACh. 4 - Prob. 4.77QACh. 4 - Prob. 4.78QACh. 4 - Prob. 4.79QACh. 4 - Prob. 4.80QACh. 4 - Prob. 4.81QACh. 4 - Prob. 4.82QACh. 4 - Prob. 4.83QACh. 4 - Prob. 4.84QACh. 4 - Prob. 4.85QACh. 4 - Prob. 4.86QACh. 4 - Prob. 4.87QACh. 4 - Prob. 4.88QACh. 4 - Prob. 4.89QACh. 4 - Prob. 4.90QACh. 4 - Prob. 4.91QACh. 4 - Prob. 4.92QACh. 4 - Prob. 4.93QACh. 4 - Prob. 4.94QACh. 4 - Prob. 4.95QACh. 4 - Prob. 4.96QACh. 4 - Prob. 4.97QACh. 4 - Prob. 4.98QACh. 4 - Prob. 4.99QACh. 4 - Prob. 4.100QACh. 4 - Prob. 4.101QACh. 4 - Prob. 4.102QACh. 4 - Prob. 4.103QACh. 4 - Prob. 4.104QACh. 4 - Prob. 4.105QACh. 4 - Prob. 4.106QACh. 4 - Prob. 4.107QACh. 4 - Prob. 4.108QACh. 4 - Prob. 4.109QACh. 4 - Prob. 4.110QACh. 4 - Prob. 4.111QACh. 4 - Prob. 4.112QACh. 4 - Prob. 4.113QACh. 4 - Prob. 4.114QACh. 4 - Prob. 4.115QACh. 4 - Prob. 4.116QACh. 4 - Prob. 4.117QACh. 4 - Prob. 4.118QACh. 4 - Prob. 4.119QACh. 4 - Prob. 4.120QACh. 4 - Prob. 4.121QACh. 4 - Prob. 4.122QACh. 4 - Prob. 4.123QACh. 4 - Prob. 4.124QACh. 4 - Prob. 4.125QACh. 4 - Prob. 4.126QACh. 4 - Prob. 4.127QACh. 4 - Prob. 4.128QACh. 4 - Prob. 4.129QACh. 4 - Prob. 4.130QACh. 4 - Prob. 4.131QACh. 4 - Prob. 4.132QACh. 4 - Prob. 4.133QACh. 4 - Prob. 4.134QACh. 4 - Prob. 4.135QACh. 4 - Prob. 4.136QACh. 4 - Prob. 4.137QACh. 4 - Prob. 4.138QACh. 4 - Prob. 4.139QACh. 4 - Prob. 4.140QACh. 4 - Prob. 4.141QACh. 4 - Prob. 4.142QACh. 4 - Prob. 4.143QACh. 4 - Prob. 4.144QACh. 4 - Prob. 4.145QACh. 4 - Prob. 4.146QACh. 4 - Prob. 4.147QACh. 4 - Prob. 4.148QACh. 4 - Prob. 4.149QACh. 4 - Prob. 4.150QACh. 4 - Prob. 4.151QACh. 4 - Prob. 4.152QACh. 4 - Prob. 4.153QACh. 4 - Prob. 4.154QACh. 4 - Prob. 4.155QACh. 4 - Prob. 4.156QACh. 4 - Prob. 4.157QACh. 4 - Prob. 4.158QACh. 4 - Prob. 4.159QACh. 4 - Prob. 4.160QACh. 4 - Prob. 4.161QACh. 4 - Prob. 4.162QACh. 4 - Prob. 4.163QACh. 4 - Prob. 4.164QACh. 4 - Prob. 4.165QACh. 4 - Prob. 4.166QACh. 4 - Prob. 4.167QACh. 4 - Prob. 4.168QACh. 4 - Prob. 4.169QACh. 4 - Prob. 4.170QACh. 4 - Prob. 4.171QACh. 4 - Prob. 4.172QACh. 4 - Prob. 4.173QACh. 4 - Prob. 4.174QACh. 4 - Prob. 4.175QACh. 4 - Prob. 4.176QACh. 4 - Prob. 4.177QACh. 4 - Prob. 4.178QACh. 4 - Prob. 4.179QACh. 4 - Prob. 4.180QA
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