
Concept explainers
Interpretation:
The concentrations of ions present in mixture of NaOH and Mg(NO3)2 solutions should be calculated.
Concept introduction:
Precipitation reaction:
If precipitate is formed, when two solutions are mixed together is known as precipitation reaction.
The mass of the precipitate is depends on the reactant masses.
Molarity:
The concentration of the solutions is given by the term of molarity and it is given by ratio between numbers of moles of solute present in litter of solution.
Molarity = No.molevolume (L)
Mole:
The mole of compound is given by the ratio between taken mass of the compound and molar mass of the compound.
Mole = Massof the compoundMolar mass of the compound
Mole:
The mole of the solute is calculated by multiplication of concentration of solution and volume of the solution and it is,
Mole = Concentration (M)× volume (L)

Answer to Problem 4.165QP
The concentrations of ions present in mixture of NaOH and Mg(NO3)2 solutions are,
Concentrations of Na+ = 0.5295 M
Concentrations of OH- = 0.09968 M
Concentrations of NO3+ = 0.4298 M
Concentrations of Mg2+ = 0
Record the given data.
Volume of Mg(NO3)2 solution = 22.02 mL
Volume of NaOH solution = 28.64 mL
Mass of Mg(NO3)2 in solution = 1.615 g
Mass of NaOH in solution = 1.073 g
Explanation of Solution
The given volume and masses of NaOH and Mg(NO3)2 their solutions are recorded as shown above.
To calculate the mole of NaOH and Mg(NO3)2 in their solutions
The reaction of Mg(NO3)2 with NaOH is,
Mg(NO3)2(aq)+2NaOH(aq)→Mg(OH)2(s)↓+Na2(NO3)2(aq)
Molar mass of Mg(NO3)2=148.33 g
Mg(NO3)2 mole = 1.615g ×1mole Mg(NO3)2148.33 g Mg(NO3)2 = 0.010888 mole Mg(NO3)2
Molar mass of NaOH=39.998 g
NaOH mole = 1.073 gNaOH×1moleNaOH39.998 g NaOH = 0.026826 mole NaOH
- The mass of substance taken is divided by molar mass of substance to give the mole of the substance present in taken mass of substance.
- The masses and molar masses of NaOH and Mg(NO3)2 are plugged in above equations to give mole of NaOH and Mg(NO3)2
- The mole of Mg(NO3)2 is 0.010888 moles
- The mole of NaOH is 0.026826 moles
To calculate the moles of ions in present the solution mixture of NaOH and Mg(NO3)2
Concentration of Na+ is,
[Na+] = 0.026826 mole NaOH×1 mole Na+1 mol NaOH×1 0.05066 L = 0.5295 M
Concentration of NO3- is,
[NO3-] = 0.010888 mole Mg(NO3)2×2 mole NO3-1 moleMg(NO3)2×10.05066 L = 0.4298 M
Concentration of OH- reacted with Mg2+ is,
[OH-] = 0.010888 mloe Mg2+×2 mole OH- 1 mole Mg2+ = 0.021776 mole OH-
Concentration of excess OH- is,
[OH-] excess= 0.26826 mole - 0.021776 mole = 0.005050 mole = 0.005050 mole0.05066 L = 0.09968 M
Concentration of excess Mg2+ is,
[Mg2+] = 0 M
- From the balanced equation the one mole of Mg(NO3)2 is required two mole of NaOH to form a Mg(OH)2 precipitate. Therefore Mg(NO3)2 is a limiting reagent.
- The Concentration of excess OH- is calculated by subtract the calculated concentration of OH- reacted with Mg2+ from total concentration of OH-.
- Moles of compounds and required number of moles of ions are plugged in the equation to give concentrations of ions present in the given solution mixture.
- Mg2+ ions are completely react give a precipitate. So, the concentration of Mg2+ present in the mixture of solution is zero.
The concentrations of ions present in mixture of NaOH and Mg(NO3)2 solutions were calculated.
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