Principles of Modern Chemistry
8th Edition
ISBN: 9781305079113
Author: David W. Oxtoby, H. Pat Gillis, Laurie J. Butler
Publisher: Cengage Learning
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Textbook Question
Chapter 4, Problem 39P
Chapter 3 introduced the concept of a double bond between carbon atoms, represented by
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Using reaction free energy to predict equilibrium composition
Consider the following equilibrium:
2NO2 (g) = N2O4(g)
AGº = -5.4 kJ
Now suppose a reaction vessel is filled with 4.53 atm of dinitrogen tetroxide (N2O4) at 279. °C. Answer the following questions about this system:
Under these conditions, will the pressure of N2O4 tend to rise or fall?
Is it possible to reverse this tendency by adding NO2?
In other words, if you said the pressure of N2O4 will tend to rise, can that
be changed to a tendency to fall by adding NO2? Similarly, if you said the
pressure of N2O4 will tend to fall, can that be changed to a tendency to
'2'
rise by adding NO2?
If you said the tendency can be reversed in the second question, calculate
the minimum pressure of NO 2 needed to reverse it.
Round your answer to 2 significant digits.
00
rise
☐ x10
fall
yes
no
☐ atm
G
Ar
1
Why do we analyse salt?
Curved arrows are used to illustrate the flow of electrons. Using
the provided starting and product structures, draw the curved
electron-pushing arrows for the following reaction or
mechanistic step(s).
Be sure to account for all bond-breaking and bond-making
steps.
H
H
CH3OH, H+
H
Select to Add Arrows
H°
0:0
'H
+
Q
HH
■ Select to Add Arrows
CH3OH,
H*
H.
H
CH3OH, H+
HH
■ Select to Add Arrows i
Please select a drawing or reagent from the question area
Chapter 4 Solutions
Principles of Modern Chemistry
Ch. 4 - Some water waves reach the beach at a rate of one...Ch. 4 - The spacing between bands of color in a chemical...Ch. 4 - An FM radio station broadcasts at a frequency of...Ch. 4 - The gamma rays emitted by 60Co are used in...Ch. 4 - Radio waves of wavelength 6.00102m can be used to...Ch. 4 - An argon ion laser emits light of wavelength of...Ch. 4 - The speed of sound in dry air at 20°C is 343.5ms1...Ch. 4 - Ultrasonic waves have frequencies too high to be...Ch. 4 - The maximum in the blackbody radiation intensity...Ch. 4 - Use the data in Figure 4.8 to estimate the ratio...
Ch. 4 - Excited lithium atoms emit light strongly at a...Ch. 4 - Excited mercury atoms emit light strongly at a...Ch. 4 - Barium atoms in a flame emit light as they undergo...Ch. 4 - Potassium atoms in a flame emit light as they...Ch. 4 - The sodium D-line is actually a pair of closely...Ch. 4 - The power output of a laser is measured by its...Ch. 4 - In a FranckHertz experiment on sodium atoms, the...Ch. 4 - In a FranckHertz experiment on hydrogen atoms, the...Ch. 4 - Use the Bohr model to calculate the radius and the...Ch. 4 - He+ ions are observed in stellar atmospheres. Use...Ch. 4 - The radiation emitted in the transition from n=3...Ch. 4 - Prob. 22PCh. 4 - Prob. 23PCh. 4 - When an intense beam of green light is directed...Ch. 4 - Cesium frequently is used in photocells because...Ch. 4 - Alarm systems use the photoelectric effect. A beam...Ch. 4 - Light with a wavelength of 2.50107m falls on the...Ch. 4 - Calculate the maximum wavelength of...Ch. 4 - Prob. 29PCh. 4 - Prob. 30PCh. 4 - Calculate the de Broglie wavelength of the...Ch. 4 - Calculate the de Broglie wavelength of the...Ch. 4 - Prob. 33PCh. 4 - Prob. 34PCh. 4 - (a) The position of an electron is known to be...Ch. 4 - No object can travel faster than the speed of...Ch. 4 - (a) Using Equation 4.36, make a graph of the n=3...Ch. 4 - Using a simple particle-in-a-box model for the...Ch. 4 - Chapter 3 introduced the concept of a double bond...Ch. 4 - When metallic sodium is dissolved in liquid sodium...Ch. 4 - Prob. 41PCh. 4 - Prob. 42PCh. 4 - Prob. 43PCh. 4 - Prob. 44PCh. 4 - A piano tuner uses a tuning fork that emits sound...Ch. 4 - The distant galaxy called Cygnus A is one of the...Ch. 4 - Hot objects can emit blackbody radiation that...Ch. 4 - Compare the energy (in joules) carried by an X-ray...Ch. 4 - The maximum in Planck’s formula for the emission...Ch. 4 - Prob. 50APCh. 4 - When ultraviolet light of wavelength 131 nm...Ch. 4 - Express the speed of the electron in the Bohr...Ch. 4 - Photons are emitted in the Lyman series as...Ch. 4 - Prob. 54APCh. 4 - The energies of macroscopic objects, as well as...Ch. 4 - Prob. 56APCh. 4 - Prob. 57APCh. 4 - It has been suggested that spacecraft could be...Ch. 4 - Prob. 59APCh. 4 - The normalized wave function for a particle in a...Ch. 4 - A particle of mass m is placed in a...
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- What are examples of analytical methods that can be used to analyse salt in tomato sauce?arrow_forwardA common alkene starting material is shown below. Predict the major product for each reaction. Use a dash or wedge bond to indicate the relative stereochemistry of substituents on asymmetric centers, where applicable. Ignore any inorganic byproducts H Šali OH H OH Select to Edit Select to Draw 1. BH3-THF 1. Hg(OAc)2, H2O =U= 2. H2O2, NaOH 2. NaBH4, NaOH + Please select a drawing or reagent from the question areaarrow_forwardWhat is the MOHR titration & AOAC method? What is it and how does it work? How can it be used to quantify salt in a sample?arrow_forward
- Predict the major products of this reaction. Cl₂ hv ? Draw only the major product or products in the drawing area below. If there's more than one major product, you can draw them in any arrangement you like. Be sure you use wedge and dash bonds if necessary, for example to distinguish between major products with different stereochemistry. If there will be no products because there will be no significant reaction, just check the box under the drawing area and leave it blank. Note for advanced students: you can ignore any products of repeated addition. Explanation Check Click and drag to start drawing a structure. 80 10 m 2025 McGraw Hill LLC. All Rights Reserved. Terms of Use | Privacy Center | Accessibility DII A F1 F2 F3 F4 F5 F6 F7 F8 EO F11arrow_forwardGiven a system with an anodic overpotential, the variation of η as a function of current density- at low fields is linear.- at higher fields, it follows Tafel's law.Calculate the range of current densities for which the overpotential has the same value when calculated for both cases (the maximum relative difference will be 5%, compared to the behavior for higher fields).arrow_forwardUsing reaction free energy to predict equilibrium composition Consider the following equilibrium: N2 (g) + 3H2 (g) = 2NH3 (g) AGº = -34. KJ Now suppose a reaction vessel is filled with 8.06 atm of nitrogen (N2) and 2.58 atm of ammonia (NH3) at 106. °C. Answer the following questions about this system: rise Under these conditions, will the pressure of N2 tend to rise or fall? ☐ x10 fall Is it possible to reverse this tendency by adding H₂? In other words, if you said the pressure of N2 will tend to rise, can that be changed to a tendency to fall by adding H2? Similarly, if you said the pressure of N will tend to fall, can that be changed to a tendency to rise by adding H₂? If you said the tendency can be reversed in the second question, calculate the minimum pressure of H₂ needed to reverse it. Round your answer to 2 significant digits. yes no ☐ atm Х ด ? olo 18 Ararrow_forward
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