ORGANIC CHEMISTRY (LL)-PACKAGE
ORGANIC CHEMISTRY (LL)-PACKAGE
8th Edition
ISBN: 9781319316389
Author: VOLLHARDT
Publisher: MAC HIGHER
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Chapter 4, Problem 31P

(a)

Interpretation Introduction

Interpretation: The isomer type needs to be determined and the stable conformation needs to be drawn.

  ORGANIC CHEMISTRY (LL)-PACKAGE, Chapter 4, Problem 31P , additional homework tip  1

Concept Introduction: If the conformer shows the minimum steric hindrance of the substituent and minimum torsional strain then that conformer is in stable form.

(b)

Interpretation Introduction

Interpretation: The isomer type needs to be determined and the stable conformation needs to be drawn.

  ORGANIC CHEMISTRY (LL)-PACKAGE, Chapter 4, Problem 31P , additional homework tip  2

Concept Introduction: Trans-isomer has opposite attachment of all groups on the ring.

(c)

Interpretation Introduction

Interpretation: The isomer type needs to be determined and the stable conformation needs to be drawn.

  ORGANIC CHEMISTRY (LL)-PACKAGE, Chapter 4, Problem 31P , additional homework tip  3

Concept Introduction:All groups are situated in one side, it is cis-isomer. Stability is defined in terms of axial interactions.

(d)

Interpretation Introduction

Interpretation: The isomer type needs to be determined and the stable conformation needs to be drawn.

  ORGANIC CHEMISTRY (LL)-PACKAGE, Chapter 4, Problem 31P , additional homework tip  4

Concept Introduction:In trans-isomer all groups are attached in opposite side of the ring.

(e)

Interpretation Introduction

Interpretation: The isomer type needs to be determined and the stable conformation needs to be drawn.

  ORGANIC CHEMISTRY (LL)-PACKAGE, Chapter 4, Problem 31P , additional homework tip  5

Concept Introduction:When groups are on one side then that isomer is cis-isomer.

(f)

Interpretation Introduction

Interpretation: The isomer type needs to be determined and the stable conformation needs to be drawn.

  ORGANIC CHEMISTRY (LL)-PACKAGE, Chapter 4, Problem 31P , additional homework tip  6

Concept Introduction:Trans-isomer consist all different groups on the opposite side of the ring.

(g)

Interpretation Introduction

Interpretation: The isomer type needs to be determined and the stable conformation needs to be drawn.

  ORGANIC CHEMISTRY (LL)-PACKAGE, Chapter 4, Problem 31P , additional homework tip  7

Concept Introduction:If all groups of the ring are attached on same side then that isomer is cis-isomer.

(h)

Interpretation Introduction

Interpretation: The isomer type needs to be determined and the stable conformation needs to be drawn.

  ORGANIC CHEMISTRY (LL)-PACKAGE, Chapter 4, Problem 31P , additional homework tip  8

Concept Introduction:If the groups are attached on the same side then that isomer is cis-isomer.

(i)

Interpretation Introduction

Interpretation: The isomer type needs to be determined and the stable conformation needs to be drawn.

  ORGANIC CHEMISTRY (LL)-PACKAGE, Chapter 4, Problem 31P , additional homework tip  9

Concept Introduction:In cis-isomer the all different groups are situated on the same side of the ring.

(j)

Interpretation Introduction

Interpretation: The isomer type needs to be determined and the stable conformation needs to be drawn.

  ORGANIC CHEMISTRY (LL)-PACKAGE, Chapter 4, Problem 31P , additional homework tip  10

Concept Introduction:Trans-isomers have the different groups on the opposite side of the ring.

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