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(a)
Interpretation: The isomer type needs to be determined and the stable conformation needs to be drawn.
Concept Introduction: If the conformer shows the minimum steric hindrance of the substituent and minimum torsional strain then that conformer is in stable form.
(b)
Interpretation: The isomer type needs to be determined and the stable conformation needs to be drawn.
Concept Introduction: Trans-isomer has opposite attachment of all groups on the ring.
(c)
Interpretation: The isomer type needs to be determined and the stable conformation needs to be drawn.
Concept Introduction:All groups are situated in one side, it is cis-isomer. Stability is defined in terms of axial interactions.
(d)
Interpretation: The isomer type needs to be determined and the stable conformation needs to be drawn.
Concept Introduction:In trans-isomer all groups are attached in opposite side of the ring.
(e)
Interpretation: The isomer type needs to be determined and the stable conformation needs to be drawn.
Concept Introduction:When groups are on one side then that isomer is cis-isomer.
(f)
Interpretation: The isomer type needs to be determined and the stable conformation needs to be drawn.
Concept Introduction:Trans-isomer consist all different groups on the opposite side of the ring.
(g)
Interpretation: The isomer type needs to be determined and the stable conformation needs to be drawn.
Concept Introduction:If all groups of the ring are attached on same side then that isomer is cis-isomer.
(h)
Interpretation: The isomer type needs to be determined and the stable conformation needs to be drawn.
Concept Introduction:If the groups are attached on the same side then that isomer is cis-isomer.
(i)
Interpretation: The isomer type needs to be determined and the stable conformation needs to be drawn.
Concept Introduction:In cis-isomer the all different groups are situated on the same side of the ring.
(j)
Interpretation: The isomer type needs to be determined and the stable conformation needs to be drawn.
Concept Introduction:Trans-isomers have the different groups on the opposite side of the ring.
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Chapter 4 Solutions
ORGANIC CHEMISTRY (LL)-PACKAGE
- Please sirrr soollveee these parts pleaseeee and thank youuuuuarrow_forward4. Read paragraph 4.15 from your textbook, use your calculated lattice energy values for CuO, CuCO3 and Cu(OH)2 an explain thermal decomposition reaction of malachite: Cu2CO3(OH)2 →2CuO + H2O + CO2 (3 points)arrow_forwardPlease sirrr soollveee these parts pleaseeee and thank youuuuuarrow_forward
- III O Organic Chemistry Using wedges and dashes in skeletal structures Draw a skeletal ("line") structure for each of the molecules below. Be sure your structures show the important difference between the molecules. key O O O O O CHON Cl jiii iiiiiiii You can drag the slider to rotate the molecules. Explanation Check Click and drag to start drawing a structure. Q Search X G ©2025 McGraw Hill LLC. All Rights Reserved. Terms of Use F 3 W C 3/5arrow_forward3. Use Kapustinskii's equation and data from Table 4.10 in your textbook to calculate lattice energies of Cu(OH)2 and CuCO3 (4 points)arrow_forward2. Copper (II) oxide crystalizes in monoclinic unit cell (included below; blue spheres 2+ represent Cu²+, red - O²-). Use Kapustinski's equation (4.5) to calculate lattice energy for CuO. You will need some data from Resource section of your textbook (p.901). (4 points) CuOarrow_forward
- What is the IUPAC name of the following compound? OH (2S, 4R)-4-chloropentan-2-ol O (2R, 4R)-4-chloropentan-2-ol O (2R, 4S)-4-chloropentan-2-ol O(2S, 4S)-4-chloropentan-2-olarrow_forwardIn the answer box, type the number of maximum stereoisomers possible for the following compound. A H H COH OH = H C Br H.C OH CHarrow_forwardSelect the major product of the following reaction. Br Br₂, light D Br Br Br Brarrow_forward
- Select all molecules which are chiral. Brarrow_forwardUse the reaction coordinate diagram to answer the below questions. Type your answers into the answer box for each question. (Watch your spelling) Energy A B C D Reaction coordinate E A) Is the reaction step going from D to F endothermic or exothermic? A F G B) Does point D represent a reactant, product, intermediate or transition state? A/ C) Which step (step 1 or step 2) is the rate determining step? Aarrow_forward1. Using radii from Resource section 1 (p.901) and Born-Lande equation, calculate the lattice energy for PbS, which crystallizes in the NaCl structure. Then, use the Born-Haber cycle to obtain the value of lattice energy for PbS. You will need the following data following data: AH Pb(g) = 196 kJ/mol; AHƒ PbS = −98 kJ/mol; electron affinities for S(g)→S¯(g) is -201 kJ/mol; S¯(g) (g) is 640kJ/mol. Ionization energies for Pb are listed in Resource section 2, p.903. Remember that enthalpies of formation are calculated beginning with the elements in their standard states (S8 for sulfur). The formation of S2, AHF: S2 (g) = 535 kJ/mol. Compare the two values, and explain the difference. (8 points)arrow_forward
Organic Chemistry: A Guided InquiryChemistryISBN:9780618974122Author:Andrei StraumanisPublisher:Cengage Learning
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