
Bundle: Chemistry: The Molecular Science, 5th, Loose-Leaf + OWLv2 with Quick Prep 24-Months Printed Access Card
5th Edition
ISBN: 9781305367487
Author: John W. Moore, Conrad L. Stanitski
Publisher: Cengage Learning
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Question
Chapter 4, Problem 1QRT
Interpretation Introduction
Interpretation:
The two laws given in this chapter has to be explained in own words.
Expert Solution & Answer

Explanation of Solution
First law of
First law of thermodynamics – Law of conservation of energy: Energy is always converted from one form to another but it cannot be created or destroyed.
Hess’s Law: The production of specific products from specific reactants involves series of steps. The summation of enthalpy change of that individual steps will be equal to the net reaction enthalpy change.
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Using the conditions of spontaneity to deduce the signs of AH and AS
Use the observations about each chemical reaction in the table below to decide the sign (positive or negative) of the reaction enthalpy AH and reaction entropy
AS.
Note: if you have not been given enough information to decide a sign, select the "unknown" option.
reaction
observations
conclusions
A
This reaction is always spontaneous, but
proceeds slower at temperatures above
120. °C.
ΔΗ is
(pick one)
AS is
(pick one)
ΔΗ is
(pick one)
B
This reaction is spontaneous except above
117. °C.
AS is
(pick one)
ΔΗ is
(pick one)
This reaction is slower below 20. °C than
C
above.
AS is
|(pick one)
?
18
Ar
1
Calculating the pH at equivalence of a titration
Try Again
Your answer is incorrect.
0/5
a
A chemist titrates 70.0 mL of a 0.7089 M hydrocyanic acid (HCN) solution with 0.4574M KOH solution at 25 °C. Calculate the pH at equivalence. The pK of
hydrocyanic acid is 9.21.
Round your answer to 2 decimal places.
Note for advanced students: you may assume the total volume of the solution equals the initial volume plus the volume of KOH solution added.
pH
=
11.43]
G
00.
18
Ar
B•
Chapter 4 Solutions
Bundle: Chemistry: The Molecular Science, 5th, Loose-Leaf + OWLv2 with Quick Prep 24-Months Printed Access Card
Ch. 4.1 - (a) If you eat a hot dog, it will provide 160...Ch. 4.2 - Prob. 4.1CECh. 4.2 - Prob. 4.2CECh. 4.3 - Prob. 4.3CECh. 4.3 - Prob. 4.2PSPCh. 4.4 - A piece of aluminum with a mass of 250. g is at an...Ch. 4.4 - Prob. 4.4CECh. 4.4 - Prob. 4.5CECh. 4.4 - Prob. 4.4PSPCh. 4.4 - Prob. 4.5PSP
Ch. 4.5 - Prob. 4.6PSPCh. 4.5 - Prob. 4.6ECh. 4.5 - Assume you have 1 cup of ice (237 g) at 0.0 C....Ch. 4.6 - Prob. 4.9CECh. 4.6 - Prob. 4.10CECh. 4.6 - Prob. 4.11ECh. 4.6 - The reaction enthalpy for sublimation of 1 mol...Ch. 4.6 - Prob. 4.12ECh. 4.6 - Prob. 4.8PSPCh. 4.7 - Prob. 4.13CECh. 4.7 - Prob. 4.14CECh. 4.8 - Prob. 4.9PSPCh. 4.8 - Prob. 4.15CECh. 4.8 - Prob. 4.10PSPCh. 4.8 - Prob. 4.16CECh. 4.8 - Prob. 4.17ECh. 4.9 - When iron is obtained from iron ore, an important...Ch. 4.10 - Write an appropriate thermochemical expression in...Ch. 4.10 - Prob. 4.18CECh. 4.10 - Prob. 4.13PSPCh. 4.10 - Use data from Table 4.2 to calculate the standard...Ch. 4.11 - Prob. 4.15PSPCh. 4.11 - Correlate the fuel values and caloric values...Ch. 4.11 - Prob. 4.20ECh. 4.11 - Prob. 4.21ECh. 4 - Prob. 1QRTCh. 4 - For each situation, define a system and its...Ch. 4 - What is the value of the standard formation...Ch. 4 - Prob. 4QRTCh. 4 - Prob. 5QRTCh. 4 - Name two exothermic processes and two endothermic...Ch. 4 - Prob. 7QRTCh. 4 - Prob. 8QRTCh. 4 - (a) A 2-inch piece of two-layer chocolate cake...Ch. 4 - Prob. 10QRTCh. 4 - Melting lead requires 5.50 cal/g. Calculate how...Ch. 4 - Prob. 12QRTCh. 4 - Prob. 13QRTCh. 4 - Prob. 14QRTCh. 4 - Prob. 15QRTCh. 4 - Analyze transfer of energy from one form to...Ch. 4 - Prob. 17QRTCh. 4 - Suppose that you are studying kinetic energy of...Ch. 4 - Solid ammonium chloride is added to water in a...Ch. 4 - Prob. 20QRTCh. 4 - Prob. 21QRTCh. 4 - Prob. 22QRTCh. 4 - Prob. 23QRTCh. 4 - Prob. 24QRTCh. 4 - Prob. 25QRTCh. 4 - Prob. 26QRTCh. 4 - The specific heat capacity of benzene, C6H6, is...Ch. 4 - The specific heat capacity of carbon...Ch. 4 - Prob. 29QRTCh. 4 - Prob. 30QRTCh. 4 - A piece of iron (400. g) is heated in a flame and...Ch. 4 - Prob. 32QRTCh. 4 - Prob. 33QRTCh. 4 - Prob. 34QRTCh. 4 - Prob. 35QRTCh. 4 - Prob. 36QRTCh. 4 - Prob. 37QRTCh. 4 - Prob. 38QRTCh. 4 - Prob. 39QRTCh. 4 - Calculate the quantity of heating required to...Ch. 4 - Prob. 41QRTCh. 4 - Prob. 42QRTCh. 4 - Prob. 43QRTCh. 4 - Prob. 44QRTCh. 4 - Prob. 45QRTCh. 4 - Calcium carbide, CaC2, is manufactured by reducing...Ch. 4 - Prob. 47QRTCh. 4 - Prob. 48QRTCh. 4 - Prob. 49QRTCh. 4 - Given the thermochemical expression CaO(s) + 3C(s)...Ch. 4 - Prob. 51QRTCh. 4 - Prob. 52QRTCh. 4 - Isooctane (2,2,4-trimethylpentane), one of the...Ch. 4 - Prob. 54QRTCh. 4 - Gasohol, a mixture of gasoline and ethanol,...Ch. 4 - White phosphorus, P4, ignites in air to produce...Ch. 4 - Prob. 57QRTCh. 4 - Prob. 58QRTCh. 4 - Which molecule, HF, HCl, HBr, or HI, has the...Ch. 4 - Which molecule, F2, Cl2, Br2, or I2, has the...Ch. 4 - For the reactions of molecular hydrogen with...Ch. 4 - Prob. 62QRTCh. 4 - A diamond can be considered a giant all-carbon...Ch. 4 - Prob. 64QRTCh. 4 - Prob. 65QRTCh. 4 - Prob. 66QRTCh. 4 - Prob. 67QRTCh. 4 - A 0.692-g sample of glucose, C6H12O6, is burned in...Ch. 4 - Benzoic acid, C7H6O2, occurs naturally in many...Ch. 4 - Prob. 70QRTCh. 4 - Prob. 71QRTCh. 4 - Prob. 72QRTCh. 4 - Three reactions very important to the...Ch. 4 - Prob. 74QRTCh. 4 - Prob. 75QRTCh. 4 - Prob. 76QRTCh. 4 - Prob. 77QRTCh. 4 - Prob. 78QRTCh. 4 - We burn 3.47 g lithium in excess oxygen at...Ch. 4 - Prob. 80QRTCh. 4 - Prob. 81QRTCh. 4 - Prob. 82QRTCh. 4 - The reaction enthalpy for oxidation of styrene,...Ch. 4 - Oxygen is not normally found in positive oxidation...Ch. 4 - Iron can react with oxygen to give iron(III)...Ch. 4 - The formation of aluminum oxide from its elements...Ch. 4 - Prob. 87QRTCh. 4 - If you want to convert 56.0 g ice (at 0 °C) to...Ch. 4 - Prob. 89QRTCh. 4 - Prob. 90QRTCh. 4 - Prob. 91QRTCh. 4 - Prob. 92QRTCh. 4 - Prob. 93QRTCh. 4 - Prob. 94QRTCh. 4 - Prob. 95QRTCh. 4 - Prob. 96QRTCh. 4 - Prob. 97QRTCh. 4 - Prob. 98QRTCh. 4 - Prob. 99QRTCh. 4 - Prob. 100QRTCh. 4 - Prob. 101QRTCh. 4 - Prob. 102QRTCh. 4 - Prob. 103QRTCh. 4 - Prob. 104QRTCh. 4 - Prob. 105QRTCh. 4 - Prob. 106QRTCh. 4 - The specific heat capacity of copper is 0.385 J g1...Ch. 4 - Consider this graph, which presents data for a...Ch. 4 - Prob. 109QRTCh. 4 - The sketch shows two identical beakers with...Ch. 4 - Prob. 111QRTCh. 4 - Prob. 112QRTCh. 4 - Prob. 113QRTCh. 4 - Prob. 114QRTCh. 4 - Prob. 115QRTCh. 4 - Prob. 116QRTCh. 4 - Prob. 117QRTCh. 4 - Prob. 118QRTCh. 4 - Prob. 119QRTCh. 4 - Prob. 120QRTCh. 4 - Prob. 121QRTCh. 4 - Prob. 122QRTCh. 4 - Prob. 123QRTCh. 4 - Prob. 124QRTCh. 4 - Prob. 4.ACPCh. 4 - Prob. 4.BCPCh. 4 - Prob. 4.CCPCh. 4 - Prob. 4.DCPCh. 4 - Prob. 4.ECPCh. 4 - Prob. 4.FCP
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