EBK INTRODUCTORY CHEMISTRY
8th Edition
ISBN: 8220100480485
Author: DECOSTE
Publisher: CENGAGE L
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Chapter 4, Problem 12QAP
Interpretation Introduction
Interpretation:
The missing symbol and name of the given element should be identified.
Concept Introduction:
Every element in the nature has given its own symbol, which is a shorthand method for representing the element. It is an easy way to represent the
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A solution contains 0.097 M Ce3+, 1.55x10-3 M Ce4+, 1.55x10-3 M Mn2+, 0.097 M MnO4-, and 1.00 M HClO4 (F= 9.649 x 104 C/mol).
a) Write a balanced net reaction that can occur between species in this solution.
b) Calculate deltaG0 and K for the reaction.
c) Calculate E and deltaG for the conditions given.
Ce4+ + e- = Ce3+ E0= 1.70 V
MnO4- + 8H+ + 5e- = Mn2+ + 4H2O E0= 1.507 V
1. Provide a step-by-step mechanism for formation of ALL STEREOISOMERS in
the following reaction.
Na HCO3 (Sodium bicarbonate, baking soda) is not soluble in CH2Cl2. The powder is
a weak base used to neutralize strong acid (pKa < 0) produced by the reaction.
Redraw the product to show the configuration(s) that form at C-2 and C-4.
Br2
OH
CH2Cl2
Na* HCO3
Br
HO
OH
+ Na Br +
2. Specify the solvent and reagent(s) required to carry out each of the following FGI. If
two reagent sets must be used for the FGI, specify the solvent and reagent(s) for each
reagent set. If a reaction cannot be carried out with reagents (sets)
class, write NP (not possible) in the solvent box for reagent set #1.
Use the letter abbreviation for each solvent; use a number abbreviation for reagent(s).
Solvents: CH2Cl2 (A);
H₂O (B);
Reagents:
HBr (1);
R₂BH (6);
H2SO4 (2);
CH3OH (C);
Br₂ (3);
CH3CO₂H (D)
NaHCO3 (4);
Hg(OAc)2 (5);
H₂O2/HO (7);
NaBH4 (8)
Reagent Set #1
Reagent Set #2
FGI
+ enant
OH
Solvent Reagent(s) Solvent Reagent(s)
Chapter 4 Solutions
EBK INTRODUCTORY CHEMISTRY
Ch. 4.4 - Exercise 4.1 Write the formula for each of the...Ch. 4.5 - The average diameter of an atom ¡s1.31010 m. What...Ch. 4.5 - You have learned about three different models of...Ch. 4.7 - Exercise 4.2 Give the number of protons, neutrons,...Ch. 4.7 - Exercise 4.3 Give the number of protons, neutrons,...Ch. 4.7 - Exercise 4.4 Give the symbol for the phosphorus...Ch. 4.8 - Exercise 4.5 Give the symbol and atomic number for...Ch. 4.11 - Thomson and Rutherford helped to show that atoms...Ch. 4.11 - Prob. 4.6SCCh. 4 - Knowing the number of protons in the atom of a...
Ch. 4 - The average mass of a carbon atom is 12.011....Ch. 4 - Prob. 3ALQCh. 4 - Prob. 4ALQCh. 4 - The vitamin niacin (nicotinic acid,C6H5NO2 ) can...Ch. 4 - One of the best indications of a useful theory is...Ch. 4 - Prob. 7ALQCh. 4 - How does Dalton’s atomic theory account for the...Ch. 4 - Prob. 9ALQCh. 4 - These questions concern the work of J. J. Thomson:...Ch. 4 - Heat is applied to an ice cube until only steam is...Ch. 4 - What makes a carbon atom different from a nitrogen...Ch. 4 - Hundreds of years ago, alchemists tried to turn...Ch. 4 - Chlorine has two prominent isotopes,37Cl and35Cl ....Ch. 4 - Prob. 15ALQCh. 4 - Prob. 16ALQCh. 4 - Rutherford was surprised when some of theparticles...Ch. 4 - It is good practice to actively read the textbook...Ch. 4 - Why is the term “sodium chloride molecule”...Ch. 4 - Both atomic elements and molecular elements exist....Ch. 4 - Now that you have gone through Chapter 4, go back...Ch. 4 - Write the formula for each of the following...Ch. 4 - Prob. 23ALQCh. 4 - What were the four fundamental substances...Ch. 4 - Prob. 2QAPCh. 4 - Prob. 3QAPCh. 4 - Prob. 4QAPCh. 4 - What are the live most abundant elements (by mass)...Ch. 4 - Read the “Chemistry in Focus” segment Trace...Ch. 4 - Prob. 7QAPCh. 4 - The symbols for most elements are based on the...Ch. 4 - Find the symbol in Column 2 for each name in...Ch. 4 - Prob. 10QAPCh. 4 - Use the periodic table shown in Fig. 4.9 to find...Ch. 4 - Prob. 12QAPCh. 4 - Prob. 13QAPCh. 4 - Prob. 14QAPCh. 4 - A given compound always contains the same...Ch. 4 - Correct each of the following misstatements from...Ch. 4 - Prob. 17QAPCh. 4 - A given compound always contains the same relative...Ch. 4 - Based on the following word descriptions, write...Ch. 4 - Based on the following word descriptions, write...Ch. 4 - Scientists J. J. Thomson and William Thomson (Lord...Ch. 4 - True or false? Rutherford’s bombardment...Ch. 4 - Where are neutrons found in an atom? Are neutrons...Ch. 4 - What are the positively charged particles found in...Ch. 4 - Do the proton and the neutron have exactly the...Ch. 4 - The proton and the (electron/neutron) have almost...Ch. 4 - An average atomic nucleus has a diameter of about...Ch. 4 - Prob. 28QAPCh. 4 - Prob. 29QAPCh. 4 - True or false? The mass number of a nucleus...Ch. 4 - For an isolated atom, why do we expect the number...Ch. 4 - Why do we not necessarily expect the number of...Ch. 4 - Dalton’s original atomic theory proposed that all...Ch. 4 - Prob. 34QAPCh. 4 - For each of the following elements, use the...Ch. 4 - Prob. 36QAPCh. 4 - Write the atomic symbol(ZAX) for each of the...Ch. 4 - Write the atomic symbol(ZAX) for each of the...Ch. 4 - How many protons and neutrons are contained in the...Ch. 4 - Read the Chemistry in Focus” segment “Whair”Do You...Ch. 4 - Read the “Chemistry in Focus” segmentIsotope...Ch. 4 - Complete the following table. Name Symbol Atomic...Ch. 4 - True or false? The elements are arranged in the...Ch. 4 - Prob. 44QAPCh. 4 - List the characteristic physical properties that...Ch. 4 - Where are the metallic elements found on the...Ch. 4 - Prob. 47QAPCh. 4 - List five nonmetallic elements that exist as...Ch. 4 - Under ordinary conditions, only a few pure...Ch. 4 - The elements that lie close to the “stair-step”...Ch. 4 - Prob. 51QAPCh. 4 - Without looking at your textbook or the periodic...Ch. 4 - Prob. 53QAPCh. 4 - Prob. 54QAPCh. 4 - Most substances are composed of _________ rather...Ch. 4 - Prob. 56QAPCh. 4 - Prob. 57QAPCh. 4 - Prob. 58QAPCh. 4 - Molecules of nitrogen gas and oxygen gas are said...Ch. 4 - Give three examples of gaseous elements that exist...Ch. 4 - Prob. 61QAPCh. 4 - If sodium chloride (table salt) is melted and then...Ch. 4 - Prob. 63QAPCh. 4 - The two most common elemental forms of carbon are...Ch. 4 - An isolated atom has a net charge of ________ .Ch. 4 - Prob. 66QAPCh. 4 - A simple ion with a 3+ charge (for example, A13+)...Ch. 4 - An ion that has two more electrons outside the...Ch. 4 - Prob. 69QAPCh. 4 - Prob. 70QAPCh. 4 - Prob. 71QAPCh. 4 - True or false?N3 andP3 contain a different number...Ch. 4 - How many electrons are present in each of the...Ch. 4 - Prob. 74QAPCh. 4 - For the following processes that show the...Ch. 4 - For the following ions, indicate whether electrons...Ch. 4 - For each of the following atomic numbers, use the...Ch. 4 - On the basis of the element’s location in the...Ch. 4 - List some properties of a substance that would...Ch. 4 - Prob. 80QAPCh. 4 - Prob. 81QAPCh. 4 - Prob. 82QAPCh. 4 - For each of the following positive ions, use the...Ch. 4 - For each of the following negative ions, use the...Ch. 4 - Prob. 85APCh. 4 - Prob. 86APCh. 4 - Prob. 87APCh. 4 - Which of the following is/are true regarding the...Ch. 4 - Prob. 89APCh. 4 - Which subatomic particles contribute most to the...Ch. 4 - Is it possible for the same Iwo elements to form...Ch. 4 - Carbohydrates, a class of compounds containing the...Ch. 4 - Prob. 93APCh. 4 - How many protons and neutrons are contained in the...Ch. 4 - Though the common isotope of aluminum has a mass...Ch. 4 - Prob. 96APCh. 4 - Prob. 97APCh. 4 - What is the symbol for an ion with a 1 — charge....Ch. 4 - Prob. 99APCh. 4 - Prob. 100APCh. 4 - Prob. 101APCh. 4 - A metal ion with a 2+ charge contains 34 neutrons...Ch. 4 - Prob. 103APCh. 4 - Write the simplest formula for each of the...Ch. 4 - Prob. 105APCh. 4 - Write the atomic symbol(ZAX) for each of the...Ch. 4 - How many protons and neutrons are contained in the...Ch. 4 - Prob. 108APCh. 4 - Prob. 109APCh. 4 - Prob. 110APCh. 4 - Prob. 111CPCh. 4 - Prob. 112CPCh. 4 - Complete the following table. Number of Protons...Ch. 4 - Prob. 114CPCh. 4 - Using the periodic table, complete the following...Ch. 4 - Prob. 116CPCh. 4 - Which of the following is(are) correct? a.40Ca2+...
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