EBK CHEMISTRY
4th Edition
ISBN: 8220102797864
Author: Burdge
Publisher: YUZU
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Textbook Question
Chapter 4, Problem 126AP
Someone spilled concentrated sulfuric acid on the floor of a chemistry laboratory. To neutralize the acid, would it be preferable to pour concentrated sodium hydroxide solution or spray solid sodium bicarbonate over the arid? Explain your choice and the chemical basis for the action.
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Using reaction free energy to predict equilibrium composition
Consider the following equilibrium:
2NH3 (g) = N2 (g) +3H₂
—N2 (g) AGº = 34. kJ
Now suppose a reaction vessel is filled with 4.19 atm of ammonia (NH3) and 9.94 atm of nitrogen (N2) at 378. °C. Answer the following questions about this
system:
rise
Under these conditions, will the pressure of NH 3 tend to rise or fall?
☐ x10
fall
Х
Is it possible to reverse this tendency by adding H₂?
In other words, if you said the pressure of NH 3 will tend to rise, can that
be changed to a tendency to fall by adding H₂? Similarly, if you said the
pressure of NH3 will tend to fall, can that be changed to a tendency to
rise by adding H₂?
If you said the tendency can be reversed in the second question, calculate
the minimum pressure of H₂ needed to reverse it.
Round your answer to 2 significant digits.
yes
no
atm
00.
18
Ar
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?
Identifying the major species in weak acid or weak base equilibria
The preparations of two aqueous solutions are described in the table below. For each solution, write the chemical formulas of the major species present at
equilibrium. You can leave out water itself.
Write the chemical formulas of the species that will act as acids in the 'acids' row, the formulas of the species that will act as bases in the 'bases' row, and the
formulas of the species that will act as neither acids nor bases in the 'other' row.
You will find it useful to keep in mind that HF is a weak acid.
2.2 mol of NaOH is added to
1.0 L of a 1.4M HF
solution.
acids:
П
bases:
Х
other: ☐
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acids:
0.51 mol of KOH is added to
1.0 L of a solution that is
bases:
1.3M in both HF and NaF.
other: ☐
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Using reaction free energy to predict equilibrium composition
Consider the following equilibrium:
N2O4 (g) 2NO2 (g)
AG⁰ = 5.4 kJ
Now suppose a reaction vessel is filled with 1.68 atm of dinitrogen tetroxide (N204) at 148. °C. Answer the following questions about this system:
rise
Under these conditions, will the pressure of N2O4 tend to rise or fall?
x10
fall
Is it possible to reverse this tendency by adding NO2?
In other words, if you said the pressure of N2O4 will tend to rise, can that
be changed to a tendency to fall by adding NO2? Similarly, if you said the
pressure of N2O4 will tend to fall, can that be changed to a tendency to
rise by adding NO2?
If you said the tendency can be reversed in the second question, calculate
the minimum pressure of NO 2 needed to reverse it.
Round your answer to 2 significant digits.
yes
no
0.42 atm
☑
5
0/5
?
مله
Ar
Chapter 4 Solutions
EBK CHEMISTRY
Ch. 4.1 - Prob. 1PPACh. 4.1 - Prob. 1PPBCh. 4.1 - Prob. 1PPCCh. 4.1 - Prob. 1CPCh. 4.1 - Soluble molecular compounds are __________. a)...Ch. 4.1 - Which of the following compounds is a weak...Ch. 4.1 - 4.1.4 Which of the following compounds is a strong...Ch. 4.2 - Prob. 1PPACh. 4.2 - Prob. 1PPBCh. 4.2 - Practice Problem CONCEPTUALIZE
Using Tables 4.2...
Ch. 4.2 - Which of the following are water-soluble? (Choose...Ch. 4.2 - Which of the following are water-insoluble?...Ch. 4.2 - 4.2.3 What are the spectator ions in the ionic...Ch. 4.2 - Select the correct net ionic equation for the...Ch. 4.2 - 4.2.5 Which reaction is represented by the net...Ch. 4.2 - Which reaction is represented by the net ionic...Ch. 4.3 - Prob. 1PPACh. 4.3 - Practice Problem BUILD
Write the molecular,...Ch. 4.3 - Prob. 1PPCCh. 4.3 - Identify the Brø�nsted acid in the following...Ch. 4.3 - Identify the Brø�nsted base in the following...Ch. 4.3 - Which of the following is the correct net ionic...Ch. 4.3 - 4.3.4 Which of the following is the correct net...Ch. 4.3 - Which diagram best represents the ions remaining...Ch. 4.3 - Which diagram best represents the ions remaining...Ch. 4.4 - Prob. 1PPACh. 4.4 - Prob. 1PPBCh. 4.4 - Prob. 1PPCCh. 4.4 - Determine the oxidation number of sulfur in each...Ch. 4.5 - Practice Problem ATTEMPT
Assign oxidation numbers...Ch. 4.5 - Practice ProblemBUILD Assign oxidation numbers to...Ch. 4.5 - Practice ProblemCONCEPTUALIZE Write the balanced...Ch. 4.5 - Calculate the molar concentration of a solution...Ch. 4.5 - What mass of glucose (C 6 H 12 O 6 ) in grams must...Ch. 4.5 - What volume in milliliters of a 1 .20 M HCl...Ch. 4.5 - A solution that is 0 .18 M in Na 2 CO 3 is...Ch. 4.5 - Prob. 5CPCh. 4.5 - Prob. 6CPCh. 4.6 - Prob. 1PPACh. 4.6 - Prob. 1PPBCh. 4.6 - Prob. 1PPCCh. 4.6 - What mass of AgCl will be recovered if a solution...Ch. 4.6 - A 10.0-g sample of an unknown ionic compound is...Ch. 4.6 - 4.6.3 Which of the following best represents the...Ch. 4.6 - If 25.0 mL of an H 2 SO 4 solution requires 39 .9...Ch. 4.6 - 4.6.5 What volume of is required to neutralize
Ch. 4.6 - Which of the following best represents the...Ch. 4.7 - Prob. 1PPACh. 4.7 - Prob. 1PPBCh. 4.7 - Prob. 1PPCCh. 4.8 - Practice ProblemATTEMPT For an aqueous solution of...Ch. 4.8 - Prob. 1PPBCh. 4.8 - Prob. 1PPCCh. 4.9 - Practice Problem ATTEMPT
What volume of is...Ch. 4.9 - Prob. 1PPBCh. 4.9 - Prob. 1PPCCh. 4.10 - Practice ProblemATTEMPT Starting with a 6.552-M...Ch. 4.10 - Practice ProblemBUILD Five standard solutions of...Ch. 4.10 - Practice ProblemCONCEPTUALIZE The first diagram...Ch. 4.11 - Practice ProblemATTEMPT Using the square-bracket...Ch. 4.11 - Practice ProblemBUILD Using the square-bracket...Ch. 4.11 - Prob. 1PPCCh. 4.12 - Prob. 1PPACh. 4.12 - Prob. 1PPBCh. 4.12 - Practice ProblemCONCEPTUALIZE Which diagram best...Ch. 4.13 - Prob. 1PPACh. 4.13 - Prob. 1PPBCh. 4.13 - Practice Problem CONCEPTUALIZE
Which diagram best...Ch. 4.14 - Practice ProblemATTEMPT How many milliliters of a...Ch. 4.14 - Practice Problem BUILD
How many milliliters of a ...Ch. 4.14 - Practice ProblemCONCEPTUALIZE Which diagram best...Ch. 4.15 - Prob. 1PPACh. 4.15 - Prob. 1PPBCh. 4.15 - Practice Problem CONCEPTUALIZE
Consider aqueous...Ch. 4.16 - Prob. 1PPACh. 4.16 - Prob. 1PPBCh. 4.16 - Prob. 1PPCCh. 4 - Prob. 1KSPCh. 4 - 4.2
Consider the following net ionic equation: If...Ch. 4 - 4.3
The net ionic equation for the neutralization...Ch. 4 - When steel wool [ Fe ( s ) ] is placed in a...Ch. 4 - Define solute, solvent, and solution by describing...Ch. 4 - what is the difference between a nonelectrolyte...Ch. 4 - What is the difference between the symbols → and ⇄...Ch. 4 - Water is an extremely weak electrolyte and...Ch. 4 - Prob. 5QPCh. 4 - Prob. 6QPCh. 4 - Which of the following diagrams best represents...Ch. 4 - Identify each of the following substances as a...Ch. 4 - 4.9 Identify each of the following substances as a...Ch. 4 - The passage of electricity through an electrolyte...Ch. 4 - Predict and explain which of the following systems...Ch. 4 - You are given a water-soluble compound X. Describe...Ch. 4 - 4.13 Explain why a solution of in benzene does...Ch. 4 - 4.14 Describe hydration. What properties of water...Ch. 4 - 4.15 What is the difference between an ionic...Ch. 4 - 4.16 What is the advantage of writing net ionic...Ch. 4 - Prob. 17QPCh. 4 - Prob. 18QPCh. 4 - 4.19 Characterize the following compounds as...Ch. 4 - Characterize the following compounds as soluble or...Ch. 4 - Write ionic and net ionic equations for the...Ch. 4 - 4.22 Write ionic and net ionic equations for the...Ch. 4 - Which of the following processes will likely...Ch. 4 - 4.24 List the general properties of acids and...Ch. 4 - Give Arrhenius’s and Brø�nsted's definitions of an...Ch. 4 - Give an example of a monoprotic acid, a diprotic...Ch. 4 - What are the products of an acid-base...Ch. 4 - 4.28 what factors qualify a compound as a salt?...Ch. 4 - Prob. 29QPCh. 4 - 4.30 Identify each of the following species as a...Ch. 4 - Prob. 31QPCh. 4 - 4.32 Balance the following equations and write the...Ch. 4 - 4.33 Balance the following equations and write the...Ch. 4 - Prob. 34QPCh. 4 - Prob. 35QPCh. 4 - Prob. 36QPCh. 4 - Prob. 37QPCh. 4 - How is the activity series organized? How is it...Ch. 4 - 4.39 Use the following reaction to define the...Ch. 4 - Prob. 40QPCh. 4 - For the complete redox reactions given here, break...Ch. 4 - For the complete redox reactions given here, write...Ch. 4 - Arrange the following species in order of...Ch. 4 - Phosphorus forms many oxoacids. Indicate the...Ch. 4 - Give the oxidation numbers for the underlined...Ch. 4 - Give the oxidation number for the following...Ch. 4 - Prob. 47QPCh. 4 - Give the oxidation numbers for the underlined...Ch. 4 - Prob. 49QPCh. 4 - Prob. 50QPCh. 4 - Prob. 51QPCh. 4 - Prob. 52QPCh. 4 - Prob. 53QPCh. 4 - Prob. 54QPCh. 4 - Prob. 55QPCh. 4 - Prob. 56QPCh. 4 - Prob. 57QPCh. 4 - 4.58 Write the equation that enables us to...Ch. 4 - Prob. 59QPCh. 4 - 4.60 Describe how you would prepare
Ch. 4 - Prob. 61QPCh. 4 - Prob. 62QPCh. 4 - Prob. 63QPCh. 4 - Prob. 64QPCh. 4 - Calculate the volume in milliliters of a solution...Ch. 4 - 4.66 Determine how many grams of each of the...Ch. 4 - Prob. 67QPCh. 4 - Prob. 68QPCh. 4 - Prob. 69QPCh. 4 - 4.70 You have 505 mL of a solution and you want...Ch. 4 - Prob. 71QPCh. 4 - Prob. 72QPCh. 4 - Determine the resulting nitrate ion concentration...Ch. 4 - Prob. 74QPCh. 4 - Describe the basic steps involved in gravimetric...Ch. 4 - Prob. 76QPCh. 4 - Prob. 77QPCh. 4 - How does an acid-base indicator work?Ch. 4 - A student carried out two titrations using an NaOH...Ch. 4 - Prob. 80QPCh. 4 -
4.81 If 30.0 mL of is added to 15.0 mL of , what...Ch. 4 - Prob. 82QPCh. 4 -
4.83 How many grams of are required to...Ch. 4 -
4.84 Calculate the concentration (in molarity) of...Ch. 4 - Calculate the volume in milliliters of a 1 .420 M...Ch. 4 - Prob. 86QPCh. 4 - Prob. 87QPCh. 4 - Determine the mass of product that will...Ch. 4 - Prob. 89QPCh. 4 - Prob. 90QPCh. 4 - Prob. 91QPCh. 4 - For each of the following pairs of combinations,...Ch. 4 - Prob. 93QPCh. 4 - Prob. 94QPCh. 4 - Prob. 95APCh. 4 - Oxygen ( O 2 ) and carbon dioxide ( CO 2 ) are...Ch. 4 - Prob. 97APCh. 4 - Prob. 98APCh. 4 - Calculate the volume of a 0 .156 M CuSO 4 solution...Ch. 4 - Prob. 100APCh. 4 - Prob. 101APCh. 4 - 4.102 Identify each of the following compounds as...Ch. 4 - Prob. 105APCh. 4 - Prob. 106APCh. 4 - 4.107 A 15.00-mL solution of potassium nitrate was...Ch. 4 - When 2.50 g of a zinc strip was placed in an AgNO...Ch. 4 - Prob. 109APCh. 4 - 4.110 Calculate the concentration of the acid (or...Ch. 4 - Prob. 111APCh. 4 - Prob. 112APCh. 4 - Prob. 113APCh. 4 - Prob. 114APCh. 4 - Prob. 115APCh. 4 - Prob. 116APCh. 4 - Prob. 117APCh. 4 - Prob. 118APCh. 4 - You are given a soluble compound of an unknown...Ch. 4 - Prob. 120APCh. 4 - Prob. 121APCh. 4 - Prob. 122APCh. 4 - Prob. 123APCh. 4 - Prob. 124APCh. 4 - Prob. 125APCh. 4 - Someone spilled concentrated sulfuric acid on the...Ch. 4 - Prob. 127APCh. 4 - Prob. 128APCh. 4 - Prob. 129APCh. 4 - A 0.8870-g sample of a mixture of NaCl and KCl is...Ch. 4 - Prob. 131APCh. 4 - Prob. 132APCh. 4 - Prob. 133APCh. 4 - Because the Acid-base and precipitation reactions...Ch. 4 - Prob. 135APCh. 4 - Prob. 136APCh. 4 - Give a chemical explanation for each of the...Ch. 4 - The recommended procedure for preparing a very...Ch. 4 - A 0.9157-g mixture of CaBr 2 and NaBr is dissolved...Ch. 4 - 4.140 Use the periodic table framework given here...Ch. 4 - A 325-mL sample of solution contains 25 .3 g of...Ch. 4 - Prob. 142APCh. 4 - Prob. 143APCh. 4 - Prob. 144APCh. 4 - Prob. 145APCh. 4 - Prob. 146APCh. 4 - Prob. 147APCh. 4 - Prob. 148APCh. 4 - Prob. 149APCh. 4 - Prob. 150APCh. 4 - 4.151 Potassium superoxide is used in some...Ch. 4 - Prob. 152APCh. 4 - 4.153 Acetylsalicylic acid is a monoprotic add...Ch. 4 - Prob. 154APCh. 4 - Prob. 155APCh. 4 - Prob. 156APCh. 4 - 4.157 The concentration of ions in the water...Ch. 4 - Prob. 158APCh. 4 - The police often use a device called a...Ch. 4 - Absorbance values for five standard solutions of a...Ch. 4 - Prob. 1SEPPCh. 4 - Prob. 2SEPPCh. 4 - Prob. 3SEPPCh. 4 - Prob. 4SEPP
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