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Chapter 36, Problem 53P

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If elements beyond Z = 120 are ever synthesized, electrons in these heavy atoms will begin filling a g subshell, corresponding to l = 4. How many states will be in a g subshell?

Consider the elements selenium (Z = 34), bromine (Z = 35), and krypton (Z = 36). In their part of the periodic table, the subshells of the electronic states are filled in the sequence 1s 2s 2p 3s 3p 3d 4s 4p . . . . What are (a) the highest occupied subshell for selenium and (b) the number of electrons in it, (c) the highest occupied subshell for bromine and (d) the number of electrons in it, and (e) the highest occupied subshell for krypton and (f) the number of electrons in it?

= . Using the formula for the hydrogen atom energy levels, En constant can be written in terms of fundamental quantities, RH = Me 4 8€, ²h³c Me 4 1 860²h² n²¹ the Rydberg and its value approaches, RH → R∞ = 10,973,731.6 m-¹ in the limit u → me. (a) How would this constant be defined for a one-electron species containing Z protons in its nucleus? Consider how this changes the form of the Hamiltonian and the energy levels for that Hamiltonian. (b) The hydrogen atom emission lines in the Balmer series (n₂ = 2) lie in the visible portion of the electromagnetic spectrum. Would this also be true if Z> 1? Find the wavelength (in nm) of the n = 32 emission in hydrogen and that for a one-electron species with Z = 2. (You will be asked to report a quantity on the quiz that depends on these two values.)