Organic Chemistry 3rd.ed. Klein Evaluation/desk Copy
Organic Chemistry 3rd.ed. Klein Evaluation/desk Copy
3rd Edition
ISBN: 9781119320524
Author: Klein
Publisher: WILEY
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Chapter 3.4, Problem 14ATS
Interpretation Introduction

Interpretation:

More acidic Proton in the given compound has to be predicted.

Concept Introduction:

Bronsted-Lowry Acidity: Qualitative analysis; without using pKa values, the acids are compared by their structures.

Conjugate base stability: As the acid deprotonates, the stability of conjugate base formed is analyzed on the basis of electronegativity.

Factors affecting the stability of Negative charges:

  • Compare the atoms bearing the negative charge. If the negative charge is on high electronegative atom, more the conjugate base is stabilized and the compound readily donates proton.
  • Compare the atoms in the same column. If the negative charge is in the same column of periodic table, no more electronegativity will be the dominant effect. Instead dominant effect is SIZE. Larger the size of the atom, better stabilize a negative charge by that atom.

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Chapter 3 Solutions

Organic Chemistry 3rd.ed. Klein Evaluation/desk Copy

Ch. 3.2 - Prob. 1LTSCh. 3.2 - All of the following acid-base reactions are...Ch. 3.2 - Prob. 2PTSCh. 3.2 - Prob. 3ATSCh. 3.3 - Prob. 2LTSCh. 3.3 - Prob. 4PTSCh. 3.3 - Prob. 5ATSCh. 3.3 - Prob. 6ATSCh. 3.3 - Prob. 3LTSCh. 3.3 - Prob. 7PTS
Ch. 3.3 - Prob. 8ATSCh. 3.3 - Prob. 9ATSCh. 3.3 - Prob. 4LTSCh. 3.3 - Prob. 10PTSCh. 3.3 - Prob. 11ATSCh. 3.3 - Prob. 12CCCh. 3.4 - Prob. 5LTSCh. 3.4 - Prob. 13PTSCh. 3.4 - Prob. 14ATSCh. 3.4 - Prob. 6LTSCh. 3.4 - Prob. 15PTSCh. 3.4 - Prob. 16ATSCh. 3.4 - Prob. 17ATSCh. 3.4 - Prob. 7LTSCh. 3.4 - Prob. 18PTSCh. 3.4 - Prob. 19PTSCh. 3.4 - Prob. 20ATSCh. 3.4 - Prob. 8LTSCh. 3.4 - Prob. 21PTSCh. 3.4 - Prob. 22ATSCh. 3.4 - Prob. 9LTSCh. 3.4 - Prob. 23PTSCh. 3.4 - Prob. 24PTSCh. 3.4 - Prob. 25ATSCh. 3.4 - Prob. 26ATSCh. 3.5 - Prob. 10LTSCh. 3.5 - Prob. 27PTSCh. 3.5 - The development of chemical sensors that can...Ch. 3.5 - Determine whether H2O would be a suitable reagent...Ch. 3.5 - Prob. 29PTSCh. 3.5 - Prob. 30ATSCh. 3.7 - Prob. 31CCCh. 3.9 - Prob. 12LTSCh. 3.9 - Prob. 32PTSCh. 3.9 - Prob. 33ATSCh. 3 - Prob. 34PPCh. 3 - Prob. 35PPCh. 3 - Prob. 36PPCh. 3 - Prob. 37PPCh. 3 - Prob. 38PPCh. 3 - Prob. 39PPCh. 3 - Prob. 40PPCh. 3 - Prob. 41PPCh. 3 - Prob. 42PPCh. 3 - Prob. 43PPCh. 3 - Prob. 44PPCh. 3 - Prob. 45PPCh. 3 - Prob. 46PPCh. 3 - Prob. 47PPCh. 3 - Prob. 48PPCh. 3 - Prob. 49IPCh. 3 - Prob. 50IPCh. 3 - Prob. 51IPCh. 3 - Prob. 52IPCh. 3 - Prob. 53IPCh. 3 - Prob. 54IPCh. 3 - Prob. 55IPCh. 3 - Prob. 56IPCh. 3 - Prob. 57IPCh. 3 - Prob. 58IPCh. 3 - Prob. 59IPCh. 3 - Prob. 60IPCh. 3 - Prob. 61IPCh. 3 - Prob. 62IPCh. 3 - Prob. 63IPCh. 3 - Prob. 64IPCh. 3 - The bengamides are a series of natural products...Ch. 3 - Prob. 66IPCh. 3 - Prob. 67IPCh. 3 - Prob. 68IPCh. 3 - Prob. 69IPCh. 3 - Prob. 70CPCh. 3 - Prob. 71CPCh. 3 - Prob. 72CPCh. 3 - Prob. 73CP
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