Chemistry: The Molecular Nature of Matter and Change
9th Edition
ISBN: 9781260477467
Author: Martin Silberberg
Publisher: Mcgraw-hill Higher Education (us)
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Chapter 3.3, Problem 3.11BFP
Interpretation Introduction
Interpretation: The balanced equation is to be interpreted for the given important industrial reaction.
Concept Introduction: The transformation of reactant molecules into product molecules is represented by a
Chemical equations can be used to represent a chemical reaction. The conversion is represented by a single-headed arrow and the chemical formula of the reactant and product molecules.
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Indicate the processes in the dismutation of Cu2O.
1. Consider these three reactions as the elementary steps in the mechanism for a chemical reaction.
2600
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1200
1000
800
Potential Energy (kJ)
600
400
200
0
-200-
-400
-600-
-800
(i) Cl₂ (g) + Pt(s) → 2Cl (g) + Pt(s)
(ii) Cl (g)+ CO (g) + Pt (s) → CICO (g) + Pt (s)
Ea = 1550 kJ
Ea = 2240 kJ
(iii) Cl (g) + CICO (g) → Cl₂CO (g)
Ea
= 2350 kJ
AH=-950 kJ
ΔΗ = 575 ΚΙ
AH=-825 kJ
a. Draw the potential energy diagram for the reaction. Label the data points for clarity.
The potential energy of the reactants is 600 kJ
Reaction Progress
b. What is the overall chemical equation?
c. What is the overall change in enthalpy for the above chemical reaction?
d. What is the overall amount of activation energy for the above chemical reaction?
e. Which reaction intermediate would be considered a catalyst (if any) and why?
f. If you were to add 2700kJ of energy to the reaction (e.g. 2700 kl of heat or electricity), would
you be able to make the reaction reverse itself (i.e. have…
draw the enolate anion and the carbonyl that would be needed to make this product through an aldol addition reaction.
Chapter 3 Solutions
Chemistry: The Molecular Nature of Matter and Change
Ch. 3.1 - Graphite is the crystalline form of carbon used in...Ch. 3.1 - Prob. 3.1BFPCh. 3.1 - At rest, a person inhales 9.72×1021 nitrogen...Ch. 3.1 - Prob. 3.2BFPCh. 3.1 - Prob. 3.3AFPCh. 3.1 - Prob. 3.3BFPCh. 3.1 - Tetraphosphorus decoxide reacts with water to form...Ch. 3.1 - Prob. 3.4BFPCh. 3.1 - Prob. 3.5AFPCh. 3.1 - For many years, compounds known as...
Ch. 3.1 - Use the information in Follow-up Problem 3.6A to...Ch. 3.1 - Prob. 3.6BFPCh. 3.2 - Prob. 3.7AFPCh. 3.2 - Prob. 3.7BFPCh. 3.2 - Prob. 3.8AFPCh. 3.2 - Prob. 3.8BFPCh. 3.2 - Prob. 3.9AFPCh. 3.2 - Prob. 3.9BFPCh. 3.3 - Prob. 3.10AFPCh. 3.3 - Prob. 3.10BFPCh. 3.3 - Prob. 3.11AFPCh. 3.3 - Prob. 3.11BFPCh. 3.4 - Prob. 3.12AFPCh. 3.4 - Prob. 3.12BFPCh. 3.4 - Prob. 3.13AFPCh. 3.4 - Prob. 3.13BFPCh. 3.4 - Prob. 3.14AFPCh. 3.4 - Prob. 3.14BFPCh. 3.4 - Prob. 3.15AFPCh. 3.4 - Prob. 3.15BFPCh. 3.4 - Prob. 3.16AFPCh. 3.4 - Prob. 3.16BFPCh. 3.4 - Prob. 3.17AFPCh. 3.4 - Prob. 3.17BFPCh. 3.4 - Prob. 3.18AFPCh. 3.4 - Prob. 3.18BFPCh. 3 - Prob. 3.1PCh. 3 - Prob. 3.2PCh. 3 - Why might the expression “1 mol of chlorine” be...Ch. 3 - Prob. 3.4PCh. 3 - Prob. 3.5PCh. 3 - Prob. 3.6PCh. 3 - Prob. 3.7PCh. 3 - Prob. 3.8PCh. 3 - Calculate the molar mass of each of the...Ch. 3 - Prob. 3.10PCh. 3 - Prob. 3.11PCh. 3 - Calculate each of the following quantities:
Mass...Ch. 3 - Calculate each of the following quantities:
Amount...Ch. 3 - Prob. 3.14PCh. 3 - Prob. 3.15PCh. 3 - Prob. 3.16PCh. 3 - Prob. 3.17PCh. 3 - Prob. 3.18PCh. 3 - Prob. 3.19PCh. 3 - Calculate each of the following:
Mass % of H in...Ch. 3 - Calculate each of the following:
Mass % of I in...Ch. 3 - Calculate each of the following:
Mass fraction of...Ch. 3 - Calculate each of the following:
Mass fraction of...Ch. 3 - Oxygen is required for the metabolic combustion of...Ch. 3 - Cisplatin (right), or Platinol, is used in the...Ch. 3 - Allyl sulfide (below) gives garlic its...Ch. 3 - Iron reacts slowly with oxygen and water to form a...Ch. 3 - Prob. 3.28PCh. 3 - Prob. 3.29PCh. 3 - The mineral galena is composed of lead(II) sulfide...Ch. 3 - Prob. 3.31PCh. 3 - Prob. 3.32PCh. 3 - List three ways compositional data may be given in...Ch. 3 - Prob. 3.34PCh. 3 - Prob. 3.35PCh. 3 - Prob. 3.36PCh. 3 - Prob. 3.37PCh. 3 - Prob. 3.38PCh. 3 - Prob. 3.39PCh. 3 - What is the molecular formula of each...Ch. 3 - Prob. 3.41PCh. 3 - Prob. 3.42PCh. 3 - Find the empirical formula of each of the...Ch. 3 - An oxide of nitrogen contains 30.45 mass % N. (a)...Ch. 3 - Prob. 3.45PCh. 3 - A sample of 0.600 mol of a metal M reacts...Ch. 3 - Prob. 3.47PCh. 3 - Prob. 3.48PCh. 3 - Prob. 3.49PCh. 3 - Prob. 3.50PCh. 3 - Prob. 3.51PCh. 3 - Prob. 3.52PCh. 3 - Prob. 3.53PCh. 3 - Prob. 3.54PCh. 3 - Prob. 3.55PCh. 3 - Prob. 3.56PCh. 3 - Prob. 3.57PCh. 3 - Prob. 3.58PCh. 3 - Prob. 3.59PCh. 3 - Prob. 3.60PCh. 3 - Prob. 3.61PCh. 3 - Prob. 3.62PCh. 3 - Prob. 3.63PCh. 3 - Prob. 3.64PCh. 3 - Prob. 3.65PCh. 3 - Prob. 3.66PCh. 3 - Prob. 3.67PCh. 3 - Prob. 3.68PCh. 3 - Prob. 3.69PCh. 3 - Prob. 3.70PCh. 3 - Prob. 3.71PCh. 3 - Prob. 3.72PCh. 3 - Prob. 3.73PCh. 3 - Prob. 3.74PCh. 3 - Elemental phosphorus occurs as tetratomic...Ch. 3 - Prob. 3.76PCh. 3 - Solid iodine trichloride is prepared in two steps:...Ch. 3 - Prob. 3.78PCh. 3 - Prob. 3.79PCh. 3 - Prob. 3.80PCh. 3 - Prob. 3.81PCh. 3 - Prob. 3.82PCh. 3 - Prob. 3.83PCh. 3 - Prob. 3.84PCh. 3 - Prob. 3.85PCh. 3 - Prob. 3.86PCh. 3 - Prob. 3.87PCh. 3 - Prob. 3.88PCh. 3 - Prob. 3.89PCh. 3 - Prob. 3.90PCh. 3 - Prob. 3.91PCh. 3 - Prob. 3.92PCh. 3 - Prob. 3.93PCh. 3 - Prob. 3.94PCh. 3 - When 20.5 g of methane and 45.0 g of chlorine gas...Ch. 3 - Prob. 3.96PCh. 3 - Prob. 3.97PCh. 3 - Prob. 3.98PCh. 3 - Prob. 3.99PCh. 3 - Prob. 3.100PCh. 3 - Sodium borohydride (NaBH4) is used industrially in...Ch. 3 - Prob. 3.102PCh. 3 - The first sulfur-nitrogen compound was prepared in...Ch. 3 - Prob. 3.104PCh. 3 - Prob. 3.105PCh. 3 - Prob. 3.106PCh. 3 - Serotonin () transmits nerve impulses between...Ch. 3 - In 1961, scientists agreed that the atomic mass...Ch. 3 - Prob. 3.109PCh. 3 - Isobutylene is a hydrocarbon used in the...Ch. 3 - The multistep smelting of ferric oxide to form...Ch. 3 - Prob. 3.112PCh. 3 - Prob. 3.113PCh. 3 - Prob. 3.114PCh. 3 - Prob. 3.115PCh. 3 - Prob. 3.116PCh. 3 - Prob. 3.117PCh. 3 - Prob. 3.118PCh. 3 - Prob. 3.119PCh. 3 - Prob. 3.120PCh. 3 - For the reaction between solid tetraphosphorus...Ch. 3 - Prob. 3.122PCh. 3 - Prob. 3.123PCh. 3 - Prob. 3.124PCh. 3 - Prob. 3.125PCh. 3 - Prob. 3.126PCh. 3 - Prob. 3.127PCh. 3 - Prob. 3.128PCh. 3 - Ferrocene, synthesized in 1951, was the first...Ch. 3 - Prob. 3.130PCh. 3 - Prob. 3.131PCh. 3 - Citric acid (below) is concentrated in citrus...Ch. 3 - Prob. 3.133PCh. 3 - Nitrogen monoxide reacts with elemental oxygen to...Ch. 3 - Prob. 3.135PCh. 3 - Prob. 3.136PCh. 3 - Manganese is a key component of extremely hard...Ch. 3 - The human body excretes nitrogen in the form of...Ch. 3 - Aspirin (acetylsalicylic acid, C9H8O4) is made by...Ch. 3 - Prob. 3.140PCh. 3 - Prob. 3.141PCh. 3 - Prob. 3.142PCh. 3 - When powdered zinc is heated with sulfur, a...Ch. 3 - Cocaine (C17H21O4N) is a natural substance found...Ch. 3 - Prob. 3.145P
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