ORGANIC CHEMISTRY BOOK& SG/SM
6th Edition
ISBN: 9781264094493
Author: SMITH
Publisher: MCG
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In the following molecule, indicate the hybridization and shape of the indicated atoms.
-z:
CH3
CH3
H3C
HO:
CI:
:
Q3: Draw the Lewis structures for nitromethane (CH3NO2) and methyl nitrite (CH3ONO). Draw at
least two resonance forms for each. Determine which form for each is the major resonance
contributor.
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Chem 0310 Organic Chemistry 1 Recitations
Q4: Draw the Lewis structures for the cyanate ion (OCN) and the fulminate ion (CNO-). Draw all
possible resonance structures for each. Determine which form for each is the major resonance
contributor.
Metallic clusters and nanomaterials.
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- 55. The photoelectric threshold energy for ytterbium metal is 4.16 × 10-19 J/atom. a. Calculate the wavelength of light that this energy corresponds to (in nm). b. Which region of the electromagnetic spectrum does this wavelength fall in? c. Would light of wavelength 490 nm produce a photoelectric effect in ytterbium? Why or why not?arrow_forward14.50 Explain why methyl vinyl ether (CH2=CHOCH 3) is not a reactive dienophile in the Diels-Alder reaction.arrow_forwardShow work with explanation needed. don't give Ai generated solutionarrow_forward
- 14.49 From what you have learned about the reaction of conjugated dienes in Section 14.10, predict the products of each of the following electrophilic additions. a. H₂O H2SO4 Br2 b. H₂Oarrow_forward14.46 Draw a stepwise mechanism for the following reaction. HBr ROOR Br + Brarrow_forwardShow work..don't give Ai generated solution....arrow_forward
- 14.47 Addition of HCI to alkene X forms two alkyl halides Y and Z. exocyclic C=C X HCI CI Y + CI Z a. Label Y and Z as a 1,2-addition product or a 1,4-addition product. b.Label Y and Z as the kinetic or thermodynamic product and explain why. c. Explain why addition of HCI occurs at the indicated C=C (called an exocyclic double bond), rather than the other C=C (called an endocyclic double bond).arrow_forward14.44 Ignoring stereoisomers, draw all products that form by addition of HBr to (E)-hexa-1,3,5-triene.arrow_forwardInclude stereochemistry Leven though the solutions manual does 14.43 Draw the products formed when each compound is treated with one not) equivalent of HBr. a. b. C.arrow_forward
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