ORGANIC CHEMISTRY (LOOSELEAF)
6th Edition
ISBN: 9781260475630
Author: SMITH
Publisher: MCG
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Cortisone is a compound that is used as an anti-inflammatory drug to treat
2)
diseases like arthritis. Cortisone is a steroid which contains four rings (A, B, C and D), and
has the following structure:
он
"OH
Cortisone
Provide the data to complete each of the following statements:
The total number of chiral carbons (stereocentres) in Cortisone is
The maximum number of stereoisomers possible is:
The degree of unsaturation (IHD) of Cortisone is
The total number of 2° hydrogens is
The ring fusion between rings B and C is trans or cis?
The absolute configuration of the carbon with * in the structure is
The total number of n bonds is
How GC-MS separates and identify organic compounds?
Consider lisinopril, a drug used primarily in the treatment of high blood pressure, heart failure, and after heart attacks.
(a) Name the various functional groups in lisinopril.
(b) What intermolecular forces are expected to exist between molecules of lisinopril in close proximity to one another (Section 5.7)?
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- Glucose, C6H12O6, contains an aldehyde group but exist predominantly in the form of the cyclic hemiacetal show below. A cyclic hemiacetal is formed when the —OH group of one carbon bonds to the carbonyl group of another carbon. Identify which carbon provides the —OH group and which provides the —CHO? Give a functional isomer of glucose and draw its structure.arrow_forwardIdentify which functional grouparrow_forwardIs CH3F or CH3CH2OH more soluable in water.arrow_forward
- Which functional groups are present in each of the following medicines? OH HO2C, F -C=CH b. `N' NH NH, HO Tamiflu™ (antiviral) Cipro™ (antibiotic) TM YasminTM component (OCP)arrow_forwardBelow is the structure of the drug Odevixebat, which is used for treating decreased bile production. In this structure circle and name the functional groups (excluding alkanes)arrow_forwarddraw and name the two different structural isomers of C7H16arrow_forward
- Give at least 10 examples of biological compounds having an alkene functional group and identify the biochemical importance of each compound.arrow_forwardGlucose, C6H12O6, contains an aldehyde group but exist predominantly in the form of the cyclic hemiacetal show below. A cyclic hemiacetal is formed when the —OH group of one carbon bonds to the carbonyl group of another carbon. Identify which carbon provides the —OH group and which provides the —CHO? Give a functional isomer of glucose and draw its structure.arrow_forwardBy saponification of plant material and subsequent acidification, petroselenic acid (C18:1Δ6), which was forming a triglyceride, is extracted. Mark the INCORRECT option: a) The petroselenic acid was part of a vegetable oil. b) Petroselenic acid is classified as ω6. c) Petroselenic acid has a double bond between C6 and C7. d) The oil from which the petroselenic acid was extracted is liquid due to its unsaturation. e) The saponification of said oil produces a salt of petroselenic acid (soap).arrow_forward
- Draw the structures of the following molecules: (a) Biacetyl, C4H6O2, a substance with the aroma of butter; it contains no rings or carbon-carbon multiple bonds. (b) Ethylenimine, C2H5N, a substance used in the synthesis of melamine polymers; it contains no multiple bonds. (c) Glycerol, C3H8O3, a substance isolated from fat and used in cosmetics; it has an -OH group on each carbon.arrow_forward21-90 To what extent do lipids and carbohydrates play structural roles in living organisms? Do these roles differ in plants and in animals?arrow_forward7arrow_forward
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