Study Guide for Chemistry: Structure and Properties
2nd Edition
ISBN: 9780134460680
Author: Nivaldo Tro
Publisher: PEARSON
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Chapter 3, Problem 84E
Interpretation Introduction
To determine:
The element with higher first ionization energy in each given pair.
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5 (a). Using the peak information you listed in the tables for
both structures, assign each peak to that portion of the
structure that produces the peak in the NMR spectrum. Draw
this diagram on your own sheet of paper and attach the sketch
of your drawing to this question.
Question 6
5 (b). Using the peak information you listed in the tables for
both structures, assign each peak to that portion of the
structure that produces the peak in the NMR spectrum. Draw
this diagram on your own sheet of paper and attach the sketch
of your drawing to this question.
Question 7
6. Are there any differences between the spectra you obtained
in Beyond Labz and the predicted spectra? If so, what were
the differences?
<
2. Predict the NMR spectra for each of these two
compounds by listing, in the NMR tables below, the
chemical shift, the splitting, and the number of
hydrogens associated with each predicted peak. Sort the
peaks from largest chemical shift to lowest.
**Not all slots must be filled**
Peak
Chemical Shift (d)
5.7
1
Multiplicity
multiplate
..........
5.04
double of doublet
2
4.98
double of doublet
3
4.05
doublet of quartet
4
5
LO
3.80
quartet
1.3
doublet
6
Peak
Chemical Shift (d)
Multiplicity
Chapter 3 Solutions
Study Guide for Chemistry: Structure and Properties
Ch. 3 - What are periodic properties?Ch. 3 - Use aluminum as an example to explain how density...Ch. 3 - Explain the contributions of Dobereiner and...Ch. 3 - Who is credited with arranging the periodic table?...Ch. 3 - Prob. 5ECh. 3 - Prob. 6ECh. 3 - What is an electron configuration? Provide an...Ch. 3 - Prob. 8ECh. 3 - Prob. 9ECh. 3 - What is penetration? How does the penetration of...
Ch. 3 - Why are the sublevels within a principal level...Ch. 3 - Prob. 12ECh. 3 - Prob. 13ECh. 3 - What are degenerate orbitals? According to Hund’s...Ch. 3 - List all orbitals from 1s through 5s according to...Ch. 3 - Prob. 16ECh. 3 - Copy this blank periodic table onto a sheet of...Ch. 3 - Explain why the s block in the periodic table has...Ch. 3 - Explain why the rows in the periodic table become...Ch. 3 - Explain the relationship between a main-group...Ch. 3 - Explain the relationship between an element's row...Ch. 3 - Which of the transition elements in the first...Ch. 3 - Explain how to write the electron configuration...Ch. 3 - Explain the relationship between the properties of...Ch. 3 - Prob. 25ECh. 3 - Prob. 26ECh. 3 - What is effective nuclear charge? What is...Ch. 3 - When an alkali metal forms an ion, what is the...Ch. 3 - When a halogen forms an ion, what is the charge of...Ch. 3 - Use the concepts of effective nuclear charge,...Ch. 3 - For transition elements, describe the trends in...Ch. 3 - Prob. 32ECh. 3 - Explain how to write an electron configuration for...Ch. 3 - Prob. 34ECh. 3 - Prob. 35ECh. 3 - Prob. 36ECh. 3 - What are the exceptions to the periodic trends in...Ch. 3 - Prob. 38ECh. 3 - Prob. 39ECh. 3 - What is metallic character? What are the observed...Ch. 3 - Prob. 41ECh. 3 - Prob. 42ECh. 3 - Determine whether each element is a main-group...Ch. 3 - Determine whether each element is a transition...Ch. 3 - Write the full electron configuration for each...Ch. 3 - Prob. 46ECh. 3 - Write the full orbital diagram for each element. N...Ch. 3 - Prob. 48ECh. 3 - Use the periodic table to write the electron...Ch. 3 - Use the periodic table to determine the element...Ch. 3 - Use the periodic table to determine each quantity....Ch. 3 - Use the periodic table to determine each quantity....Ch. 3 - Prob. 53ECh. 3 - Prob. 54ECh. 3 - Determine the number of valence electrons in each...Ch. 3 - Prob. 56ECh. 3 - Which outer electron configuration would you...Ch. 3 - Prob. 58ECh. 3 - Prob. 59ECh. 3 - List the number of valence electrons in each...Ch. 3 - Which pair of elements do you expect to be most...Ch. 3 - Prob. 62ECh. 3 - Predict the charge of the ion formed by each...Ch. 3 - Predict the charge of the ion formed by each...Ch. 3 - According to Coulomb’s law, which pair of charged...Ch. 3 - Prob. 66ECh. 3 - Prob. 67ECh. 3 - Arrange the atoms according to decreasing...Ch. 3 - If core electrons completely shielded valence...Ch. 3 - In Section 3.6/, we estimated the effective...Ch. 3 - Prob. 71ECh. 3 - Choose the larger atom in each pair. Sn or Si Br...Ch. 3 - Arrange these elements in order of increasing...Ch. 3 - Arrange these elements in order of decreasing...Ch. 3 - Write the electron configuration for each ion. O2...Ch. 3 - Write the electron configuration for each ion. Cl...Ch. 3 - Write orbital diagrams for each ion and determine...Ch. 3 - Write orbital diagrams for each ion and determine...Ch. 3 - Which is the larger species in each pair? LiorLi+...Ch. 3 - Which is the larger species in each pair? SrorSr2+...Ch. 3 - Arrange this isoelectronic series in order of...Ch. 3 - Arrange this isoelectronic series in order of...Ch. 3 - Choose the element with the higher first...Ch. 3 - Prob. 84ECh. 3 - Arrange these elements in order of increasing...Ch. 3 - Prob. 86ECh. 3 - For each element, predict where the “jump” occurs...Ch. 3 - Prob. 88ECh. 3 - Choose the element with the more negative (more...Ch. 3 - Prob. 90ECh. 3 - Choose the more metallic element in each pair....Ch. 3 - Prob. 92ECh. 3 - Prob. 93ECh. 3 - Prob. 94ECh. 3 - Prob. 95ECh. 3 - Prob. 96ECh. 3 - Both vanadium and its 3+ ion are paramagnetic. Use...Ch. 3 - Use electron configurations to explain why copper...Ch. 3 - Prob. 99ECh. 3 - Suppose you were trying to find a substitute for...Ch. 3 - Prob. 101ECh. 3 - Which pair of elements would you expect to have...Ch. 3 - Consider these elements: N, Mg, O, F, Al. Write...Ch. 3 - Consider these elements: P, Ca, Si, S, Ga. Write...Ch. 3 - Prob. 105ECh. 3 - Explain why vanadium (radius = 134 pm) and copper...Ch. 3 - The lightest noble gases, such as helium and neon,...Ch. 3 - The lightest halogen is also the most chemically...Ch. 3 - Prob. 109ECh. 3 - Prob. 110ECh. 3 - Prob. 111ECh. 3 - Write the electronic configurations of the six...Ch. 3 - You have cracked a secret code that uses elemental...Ch. 3 - The electron affinity of sodium is lower than that...Ch. 3 - Use Coulomb’s law to calculate the ionization...Ch. 3 - Prob. 116ECh. 3 - Consider the densities and atomic radii of the...Ch. 3 - Prob. 118ECh. 3 - Consider the metals in the first transition...Ch. 3 - Imagine a universe in which the value of ms can be...Ch. 3 - A carbon atom can absorb radiation of various...Ch. 3 - Only trace amounts of the synthetic element...Ch. 3 - What is the atomic number of the as yet...Ch. 3 - The trend in second ionization energy for the...Ch. 3 - Unlike the elements in groups 1A and 2A, those in...Ch. 3 - Using the data in Figures 3.19 and 3.20/,...Ch. 3 - Prob. 127ECh. 3 - Prob. 128ECh. 3 - The heaviest known alkaline earth metal is radium,...Ch. 3 - Predict the electronic configurations of the first...Ch. 3 - Prob. 131ECh. 3 - The outermost valence electron in atom A...Ch. 3 - Prob. 133ECh. 3 - Give a combination of four quantum numbers that...Ch. 3 - Prob. 135ECh. 3 - Prob. 136ECh. 3 - Prob. 137ECh. 3 - Prob. 138ECh. 3 - Prob. 139ECh. 3 - Prob. 140ECh. 3 - Prob. 141ECh. 3 - 1. According to Coulomb's law, if the separation...Ch. 3 - Prob. 2SAQCh. 3 - Choose the correct electron configuration for Se....Ch. 3 - Prob. 4SAQCh. 3 - Which set of four quantum numbers corresponds to...Ch. 3 - Prob. 6SAQCh. 3 - Which statement is true about electron shielding...Ch. 3 - Prob. 8SAQCh. 3 - What is the electron configuration for Fe2+?...Ch. 3 - Which species is diamagnetic? Zn Cr 2+ C MnCh. 3 - Prob. 11SAQCh. 3 - Prob. 12SAQCh. 3 - Prob. 13SAQCh. 3 - Prob. 14SAQCh. 3 - Prob. 15SAQCh. 3 - Prob. 16SAQ
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- Interpreting NMR spectra is a skill that often requires some amount of practice, which, in turn, necessitates access to a collection of NMR spectra. Beyond Labz Organic Synthesis and Organic Qualitative Analysis have spectral libraries containing over 700 1H NMR spectra. In this assignment, you will take advantage of this by first predicting the NMR spectra for two closely related compounds and then checking your predictions by looking up the actual spectra in the spectra library. After completing this assignment, you may wish to select other compounds for additional practice. 1. Write the IUPAC names for the following two structures: Question 2 Question 3 2. Predict the NMR spectra for each of these two compounds by listing, in the NMR tables below, the chemical shift, the splitting, and the number of hydrogens associated with each predicted peak. Sort the peaks from largest chemical shift to lowest. **Not all slots must be filled**arrow_forward11:14 ... worksheets.beyondlabz.com 3. To check your predictions, click this link for Interpreting NMR Spectra 1. You will see a list of all the - compounds in the spectra library in alphabetical order by IUPAC name. Hovering over a name in the list will show the structure on the chalkboard. The four buttons on the top of the Spectra tab in the tray are used to select the different spectroscopic techniques for the selected compound. Make sure the NMR button has been selected. 4. Scroll through the list of names to find the names for the two compounds you have been given and click on the name to display the NMR spectrum for each. In the NMR tables below, list the chemical shift, the splitting, and the number of hydrogens associated with each peak for each compound. Compare your answers to your predictions. **Not all slots must be filled** Peak Chemical Shift (d) Multiplicity 1 2 3 4 5arrow_forwardО δα HO- H -Br δα HO-- + + -Br [B] 8+ HO- -Br δα नarrow_forward
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