CHEMISTRY
2nd Edition
ISBN: 9781593995782
Author: OpenStax
Publisher: XANEDU PUBLISHING
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Chapter 3, Problem 67E
What volume of a
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One method for the analysis of Fe3+, which is used with a variety of sample matrices, is to form the highly colored Fe3+–thioglycolic acid complex. The complex absorbs strongly at 535 nm. Standardizing the method is accomplished using external standards. A 10.00-ppm Fe3+ working standard is prepared by transferring a 10-mL aliquot of a 100.0 ppm stock solution of Fe3+ to a 100-mL volumetric flask and diluting to volume. Calibration standards of 1.00, 2.00, 3.00, 4.00, and 5.00 ppm are prepared by transferring appropriate amounts of the 10.0 ppm working solution into separate 50-mL volumetric flasks, each of which contains 5 mL of thioglycolic acid, 2 mL of 20% w/v ammonium citrate, and 5 mL of 0.22 M NH3. After diluting to volume and mixing, the absorbances of the external standards are measured against an appropriate blank. Samples are prepared for analysis by taking a portion known to contain approximately 0.1 g of Fe3+, dissolving it in a minimum amount of HNO3, and diluting to…
Absorbance and transmittance are related by:
A = -log(T)
A solution has a transmittance of 35% in a 1-cm-pathlength cell at a certain wavelength. Calculate the transmittance if you dilute 25.0 mL of the solution to 50.0 mL? (A = εbc)
What is the transmittance of the original solution if the pathlength is increased to 10 cm?
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When the absorbing species is very dilute.
When the absorbing species participates in a concentration-dependent equilibrium.
When the solution being studied contains a mixture of ions.
Chapter 3 Solutions
CHEMISTRY
Ch. 3 - What is the total mass (amu) of carbon in each of...Ch. 3 - What is the total mass of hydrogen in each of the...Ch. 3 - Calculate the molecular or formula mass of each of...Ch. 3 - Determine the molecular mass of the following...Ch. 3 - Determine the molecular mass of the following...Ch. 3 - Which molecule has a molecular mass of 28.05 amu?Ch. 3 - Write a sentence that describes how to determine...Ch. 3 - Compare 1 mole of H2, 1 mole of O2, and 1 mole of...Ch. 3 - Which contains the greatest mass of oxygen: 0.75...Ch. 3 - Which contains the greatest number of moles of...
Ch. 3 - How are the molecular mass and the molar mass of a...Ch. 3 - Calculate the molar mass of each of the following...Ch. 3 - Calculate the molar mass of each of the following:...Ch. 3 - Calculate the empirical or molecular formula mass...Ch. 3 - Calculate the molar mass of each of the following:...Ch. 3 - Determine the number of moles of compound and the...Ch. 3 - Determine the mass of each of the following: 0.0...Ch. 3 - Determine the number of moles of the compound and...Ch. 3 - Determine the mass of each of the following: 2.345...Ch. 3 - The approximate minimum daily dietary requirement...Ch. 3 - Determine the mass in grams of each of the...Ch. 3 - A 55-kg woman has 7.5103 mol of hemoglobin (molar...Ch. 3 - Determine the number of atoms and the mass of...Ch. 3 - Determine which of the following contains the...Ch. 3 - Determine which of the following contains the...Ch. 3 - Diamond is one form of elemental carbon. An...Ch. 3 - The Cullinan diamond was the largest natural...Ch. 3 - One 55-gram serving of a particular cereal...Ch. 3 - A certain nut crunch cereal contains 11.0 grams of...Ch. 3 - A tube of toothpaste contains 0.76 g of sodium...Ch. 3 - Which of the following represents the least number...Ch. 3 - What information do we need to determine the...Ch. 3 - Calculate the following to four significant...Ch. 3 - Determine the following to four significant...Ch. 3 - Determine the percent ammonia, NH3, in Co(...Ch. 3 - Determine the percent water in CuSO45H2O to three...Ch. 3 - Determine the empirical formulas for compounds...Ch. 3 - Determine the empirical formulas for compounds...Ch. 3 - A compound of carbon and hydrogen contains 92.3% C...Ch. 3 - Dichioroethane, a compound that is often used for...Ch. 3 - Determine the empirical and molecular formula for...Ch. 3 - Polymers are large molecules composed of simple...Ch. 3 - A major textile dye manufacturer developed a new...Ch. 3 - Explain what changes and what stays the same when...Ch. 3 - What information do we need to calculate the...Ch. 3 - What does it mean when we say that a 200-mL sample...Ch. 3 - Determine the molarity for each of the following...Ch. 3 - Determine the molarity of each of the following...Ch. 3 - Consider this question: What is the mass of the...Ch. 3 - Consider this question: What is the mass of solute...Ch. 3 - Calculate the number of moles and the mass of the...Ch. 3 - Calculate the number of moles and the mass of the...Ch. 3 - Consider this question: What is the molarity of...Ch. 3 - Consider this question: What is the molarity of...Ch. 3 - Calculate the molarity of each of the following...Ch. 3 - Calculate the molarity of each of the following...Ch. 3 - There is about 1.0 g of calcium, as Ca2+, in LO L...Ch. 3 - What volume of a 1.00MFe( NO3)3 solution can be...Ch. 3 - If 0.1718 L of a 0.3556-M C3H7OH solution is...Ch. 3 - If 4.12 L of a 0.850 MH3PO4 solution is be diluted...Ch. 3 - What volume of a 0.33MC12H22O11 solution can be...Ch. 3 - What is the concentration of the NaCl solution...Ch. 3 - What is the molarity of the diluted solution when...Ch. 3 - What is the final concentration of the solution...Ch. 3 - A 2.00-L bottle of a solution of concentrated HCl...Ch. 3 - An experiment in a general chemistry laboratory...Ch. 3 - What volume of a 0.20MK2SO4 solution contains 57 g...Ch. 3 - The US Environmental Protection Agency (EPA)...Ch. 3 - Consider this question: What mass of a...Ch. 3 - What mass of a 4.00% NaOH solution by mass...Ch. 3 - What mass of solid NaOH (97.0% NaOH by mass) is...Ch. 3 - What mass of HCl is contained in 45.0 mL of an...Ch. 3 - The hardness of water (hardness count) is usually...Ch. 3 - The hardness of water (hardness count) is usually...Ch. 3 - In Canada and the United Kingdom, devices that...Ch. 3 - A throat spray is 1.40% by mass phenol, C6H5OH, in...Ch. 3 - Copper(I) iodide (CuI) is often added to table...Ch. 3 - A cough syrup contains 5.0% ethyl alcohol, C2H5OH,...Ch. 3 - D5W is a solution used as an intravenous fluid. It...Ch. 3 - Find the molarity of a 40.0% by mass aqueous...
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- Compared to incident (exciting) radiation, fluorescence emission will have a: Higher energy Higher frequency Longer wavelengtharrow_forwardLin and Brown described a quantitative method for methanol based on its effect on the visible spectrum of methylene blue. In the absence of methanol, methylene blue has two prominent absorption bands at 610 nm and 663 nm, which correspond to the monomer and the dimer, respectively. In the presence of methanol, the intensity of the dimer’s absorption band decreases, while that for the monomer increases. For concentrations of methanol between 0 and 30% v/v, the ratio of the two absorbance, A663/ A610, is a linear function of the amount of methanol. Use the following standardization data to determine the %v/v methanol in a sample if A610 is 0.75 and A663 is 1.07.arrow_forwardThe crystal field splitting energy, Δ, of a complex is determined to be 2.9 × 10-19 What wavelength of light would this complex absorb? What color of light is this? What color would the compound be in solution?arrow_forward
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- Each of the highlighted carbon atoms is connected to hydrogen atoms.arrow_forwardく Complete the reaction in the drawing area below by adding the major products to the right-hand side. If there won't be any products, because nothing will happen under these reaction conditions, check the box under the drawing area instead. Note: if the products contain one or more pairs of enantiomers, don't worry about drawing each enantiomer with dash and wedge bonds. Just draw one molecule to represent each pair of enantiomers, using line bonds at the chiral center. More... No reaction. Explanation Check O + G 1. Na O Me Click and drag to start drawing a structure. 2. H + 2025 McGraw Hill LLC. All Rights Reserved. Terms of Use | Privacy Center | Accessibility 000 Ar Parrow_forwardDraw a tetramer of this alternating copolymer.arrow_forward
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Solutions: Crash Course Chemistry #27; Author: Crash Course;https://www.youtube.com/watch?v=9h2f1Bjr0p4;License: Standard YouTube License, CC-BY