CHEMISTRY
2nd Edition
ISBN: 9781593995782
Author: OpenStax
Publisher: XANEDU PUBLISHING
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Textbook Question
Chapter 3, Problem 60E
If 4.12 L of a 0.850
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K
Problem 22 of 24
Submit
Draw the missing organic structures
in the following multistep synthesis
at physiological pH (pH = 7.4). Ignore
any inorganic byproducts formed.
0
0
ΝΘ
BrCH(CO2CH2CH3)2
Select to Draw
1. NaOCH2CH3 2.
(CH3)2CHCI
Devise electrochemical cells in which the following reactions could be made to occur. If liquid
junctions are necessary, note them in the cell schematic appropriately, but neglect their effects.
(a) H2OH + OH¯
(b) 2H2O2
H₂O
(c) 2PbSO4 + 2H2O
(d) An
TMPD
PыO₂+ Pb + 4H+ + 20%¯¯
An + TMPD (in acetonitrile, where An and An are anthracene and its
anion radical, and TMPD and TMPD are N,N,N',N'-tetramethyl-p-phenylenediamine and its
cation radical. Use anthracene potentials for DMF solutions given in Appendix C.3).
(e) 2Ce3+ + 2H + BQ 2Ce4+ + H2Q (aqueous, where BQ is p-benzoquinone and H₂Q is p-
hydroquinone)
(f) Ag +Agl (aqueous)
(g) Fe3+ + Fe(CN)6 Fe²+ + Fe(CN) (aqueous)
Consider each of the following electrode-solution interfaces, and write the equation for the elec-
trode reaction that occurs first when the potential is moved in (1) a negative direction and (2) a posi-
tive direction from the open-circuit potential. Next to each reaction write the approximate potential
for the reaction in V vs. SCE (assuming the reaction is reversible).
(a) Pt/Cu2+ (0.01 M), Cd2+ (0.01 M), H2SO4(1 M)
(b) Pt/Sn2+ (0.01 M), Sn4+ (0.01 M), HCl(1 M)
(c) Hg/Cd2+ (0.01 M), Zn2+ (0.01 M), HCl(1 M)
Chapter 3 Solutions
CHEMISTRY
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- What are the major products of both of the organic reactions. Please be sure to use wedge and dash bonds to show the stereochemistry of the products if it is needed. Please include the final product as well as a digram/drawing to show the mechanism of the reaction.arrow_forwardK Problem 16 of 24 Submit Draw the starting structure that would yield this product under these conditions. Select to Draw 1. NH4Cl, NaCN 2. HCI, H2O, A NH3 + 0arrow_forwardGive detailed me detailed mechanism Solution with explanation needed. Don't give Ai generated solution. avoid handwritten Solutionarrow_forward
- Show work with explanation needed. don't give Ai generated solutionarrow_forwardK Problem 21 of 24 Submit Draw the missing organic structures in the following multistep synthesis. Show the final product at physiological pH (pH = 7.4). Ignore any inorganic byproducts formed. H 0 NH3 Select to Draw HCN H+, H2O Select to Draw Select to Draw Δarrow_forwardShow work with explanation needed. Don't give Ai generated solution. Give correct solutionarrow_forward
- K Problem 23 of 24 Submit Draw the product of the reaction shown below at physiological pH (pH = 7.4). Ignore inorganic byproducts. S O 1. NH3, 2. HCN 3. H+, H₂O, A Select to Drawarrow_forwardGive detailed mechanism Solution with explanation needed..don't give Ai generated solutionarrow_forwardPlease correct answer and don't use hand rating and don't use Ai solutionarrow_forward
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Solutions: Crash Course Chemistry #27; Author: Crash Course;https://www.youtube.com/watch?v=9h2f1Bjr0p4;License: Standard YouTube License, CC-BY