Organic Chemistry
3rd Edition
ISBN: 9781119316152
Author: Klein, David R.
Publisher: WILEY
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Chapter 3, Problem 66IP
Interpretation Introduction
Interpretation:
The strongest base that is after methyl magnesium bromide is treated with water has to be identified.
Concept Introduction:
Lewis acid: A compound or ionic species which can accept an electron pair from a donor compound.
Lewis base: A compound or ionic species which can donate an electron pair to an acceptor compound.
Resonance Contributor: The appropriate structure with the localized electrons is called a resonance contributor, a resonance structure, or a contributing resonance structure.
Delocalized electrons: The sharing of electrons between two or more atoms known as delocalization of electrons. In order to have delocalized electrons, the system must be planar and have alternative double bonds and single bonds.
Resonance hybrid: The actual structure with delocalized electrons is called a resonance hybrid.
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Experiment:
Each team will be provided with 5g of a mixture of acetanilide and salicylic acid. You will divide it into three 1.5 g portions in separate 125 mL Erlenmeyer flasks savıng some for melting point analysis. Dissolve the mixture in each flask in ~60mL of DI water by heating to boiling on a hotplate. Take the flasks off the hotplate once you have a clear solution and let them stand on the bench top for 5 mins and then allow them to cool as described below.
Sample A-Let the first sample cool slowly to room temperature by letting it stand on your lab bench, with occasional stirring to promote crystallization.
Sample B-Cool the second sample 1n a tap-water bath to 10-15 °C
Sample C-Cool the third sample in an ice-bath to 0-2 °C
Results:
weight after recrystalization and melting point temp.
A=0.624g,102-115°
B=0.765g, 80-105°
C=1.135g, 77-108
What is the percent yield of A,B, and C.
Rel. Intensity
Q
1. Which one of the following is true of the compound
whose mass spectrum is shown
here? Explain how you decided.
100
a) It contains chlorine.
b) It contains bromine.
c) It contains neither chlorine nor bromine.
80-
60-
40-
20-
0.0
0.0
TT
40
80
120
160
m/z
2. Using the Table of IR Absorptions how could you
distinguish between these two
compounds in the IR?
What absorbance would one compound have that the
other compound does not?
HO
CI
Illustrate reaction mechanisms of
alkenes with water in the presence of
H2SO4, detailing each step of the
process. Please show steps of
processing. Please do both, I will
thumb up for sure
#1
#3
Chapter 3 Solutions
Organic Chemistry
Ch. 3.2 - Prob. 1LTSCh. 3.2 - All of the following acid-base reactions are...Ch. 3.2 - Prob. 2PTSCh. 3.2 - Prob. 3ATSCh. 3.3 - Prob. 2LTSCh. 3.3 - Prob. 4PTSCh. 3.3 - Prob. 5ATSCh. 3.3 - Prob. 6ATSCh. 3.3 - Prob. 3LTSCh. 3.3 - Prob. 7PTS
Ch. 3.3 - Prob. 8ATSCh. 3.3 - Prob. 9ATSCh. 3.3 - Prob. 4LTSCh. 3.3 - Prob. 10PTSCh. 3.3 - Prob. 11ATSCh. 3.3 - Prob. 12CCCh. 3.4 - Prob. 5LTSCh. 3.4 - Prob. 13PTSCh. 3.4 - Prob. 14ATSCh. 3.4 - Prob. 6LTSCh. 3.4 - Prob. 15PTSCh. 3.4 - Prob. 16ATSCh. 3.4 - Prob. 17ATSCh. 3.4 - Prob. 7LTSCh. 3.4 - Prob. 18PTSCh. 3.4 - Prob. 19PTSCh. 3.4 - Prob. 20ATSCh. 3.4 - Prob. 8LTSCh. 3.4 - Prob. 21PTSCh. 3.4 - Prob. 22ATSCh. 3.4 - Prob. 9LTSCh. 3.4 - Prob. 23PTSCh. 3.4 - Prob. 24PTSCh. 3.4 - Prob. 25ATSCh. 3.4 - Prob. 26ATSCh. 3.5 - Prob. 10LTSCh. 3.5 - Prob. 27PTSCh. 3.5 - The development of chemical sensors that can...Ch. 3.5 - Determine whether H2O would be a suitable reagent...Ch. 3.5 - Prob. 29PTSCh. 3.5 - Prob. 30ATSCh. 3.7 - Prob. 31CCCh. 3.9 - Prob. 12LTSCh. 3.9 - Prob. 32PTSCh. 3.9 - Prob. 33ATSCh. 3 - Prob. 34PPCh. 3 - Prob. 35PPCh. 3 - Prob. 36PPCh. 3 - Prob. 37PPCh. 3 - Prob. 38PPCh. 3 - Prob. 39PPCh. 3 - Prob. 40PPCh. 3 - Prob. 41PPCh. 3 - Prob. 42PPCh. 3 - Prob. 43PPCh. 3 - Prob. 44PPCh. 3 - Prob. 45PPCh. 3 - Prob. 46PPCh. 3 - Prob. 47PPCh. 3 - Prob. 48PPCh. 3 - Prob. 49IPCh. 3 - Prob. 50IPCh. 3 - Prob. 51IPCh. 3 - Prob. 52IPCh. 3 - Prob. 53IPCh. 3 - Prob. 54IPCh. 3 - Prob. 55IPCh. 3 - Prob. 56IPCh. 3 - Prob. 57IPCh. 3 - Prob. 58IPCh. 3 - Prob. 59IPCh. 3 - Prob. 60IPCh. 3 - Prob. 61IPCh. 3 - Prob. 62IPCh. 3 - Prob. 63IPCh. 3 - Prob. 64IPCh. 3 - The bengamides are a series of natural products...Ch. 3 - Prob. 66IPCh. 3 - Prob. 67IPCh. 3 - Prob. 68IPCh. 3 - Prob. 69IPCh. 3 - Prob. 70CPCh. 3 - Prob. 71CPCh. 3 - Prob. 72CPCh. 3 - Prob. 73CP
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