Introductory Chemistry (5th Edition) (Standalone Book)
5th Edition
ISBN: 9780321910295
Author: Nivaldo J. Tro
Publisher: PEARSON
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Textbook Question
Chapter 3, Problem 62E
In a chemical cold pack, two substances are kept separate by a divider. When the divider is broken, the substances mix and absorb heat form the surroundings. The chemical cold pack feels cold. Is reaction exothermic or endothermic? Draw an energy diagram showing the relative energies of the reactants and products in the reaction.
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Part VII. The H-NMR of a compound with molecular formula C5 H 10 O2 is given below.
Find the following:
(a) The no. of protons corresponding to each signal in the spectra
(6) Give the structure of the compound and assign the signals to each
proton in the compound.
a
70.2
Integration Values
C5H10O2
b
47.7
C
46.5
d
69.5
3.6 3.5
3.4 3.3 3.2 3.1 3.0
2.9 2.8
2.7
2.6 2.5
2.4 2.3 2.2 2.1 2.0
Chemical Shift (ppm)
1.9
1.8
1.7 1.6
1.5
1.4 1.3 1.2
1.1 1.0
0.9 0.8
Part 111. 1 H-NMR spectrum of a compound with integration values in red is given below.
Answer the following:
(a) write the signals in the 'H-NMR spectrum to the corresponding protons on the structure
of the molecule below.
(b) Identify the theoretical multiplicities for each proton in the compound. Also give the possible.
complex splitting patterns assuming J values are not similar.
там
Br
22
2
3
6
4 7.2 7.0 6.8 6.6 6.4 6.2 6.0 5.8 5.6 5.4 5.2 5.0 4.8 4.6 4.4 4.2 4.0 3.8 3.6 3.4 3.2 3.0 2.8 2.6 2.4 2.2 2.0 1.8 1.6 1.4 1.2 1.0 0.8 0
Chemical Shift (ppm)
ra.
Br
2
3
6
6
2.5
2.4
2.3
2.2
2.1
2.0
1.9
1.8
1.7
1.6
1.5
1.4
1.3
1.2
1.1
1.0
0.9
0.8
Chemical Shift (ppm)
2
2
Br
7.3
7.2
7.1
7.0 6.9
6.7 6.6 6.5
6.4
6.3
6.2
6.1
6.0
Chemical Shift (ppm)
5.9
5.8 5.7
5.5 5.4 5.3 5.2
5.0 4.9
1600°
1538°C
1493°C
In the diagram, the letter L indicates
that it is a liquid. Indicate its
components in the upper region
where only L is indicated.
The
iron-iron carbide phase
diagram.
Temperature (°C)
1400
8
1394°C
y+L
1200
2.14
y, Austenite
10000
912°C
800a
0.76
0.022
600
400
(Fe)
a, Ferrite
Composition (at% C)
15
1147°C
a + Fe3C
2
3
Composition (wt% C)
L
2500
4.30
2000
y + Fe3C
727°C
1500
Cementite (Fe3C)
1000
4
5
6
6.70
Temperature (°F)
Chapter 3 Solutions
Introductory Chemistry (5th Edition) (Standalone Book)
Ch. 3 - Which substance is a pure compound? a. Gold b....Ch. 3 - Which property of trinitrotoluene (TNT) is most...Ch. 3 - Which change is a chemical change? a. The...Ch. 3 - Q4. Which process is endothermic?
a. The burning...Ch. 3 - Q5. A 35-g sample of potassium completely reacts...Ch. 3 - Prob. 6SAQCh. 3 - Convert the boiling point of water (100.00C) to K....Ch. 3 - Q8. A European doctor reports that you have fever...Ch. 3 - Q9. How much heat must be absorbed by 125 g of...Ch. 3 - Q10. Substance A has a heat capacity that is much...
Ch. 3 - Define matter and list some examples.Ch. 3 - Prob. 2ECh. 3 - What are the three states of matter?Ch. 3 - Prob. 4ECh. 3 - Prob. 5ECh. 3 - Prob. 6ECh. 3 - Prob. 7ECh. 3 - Prob. 8ECh. 3 - 9. What is a mixture?
Ch. 3 - 10. What is the difference between a homogeneous...Ch. 3 - What is a pure substance?Ch. 3 - What is an element? A compound?Ch. 3 - What is the difference between a mixture and a...Ch. 3 - Prob. 14ECh. 3 - 15. What is the difference between a physical...Ch. 3 - Prob. 16ECh. 3 - Prob. 17ECh. 3 - Prob. 18ECh. 3 - Prob. 19ECh. 3 - What is chemical energy? List some examples of...Ch. 3 - Prob. 21ECh. 3 - 22. What is an exothermic reaction? Which has...Ch. 3 - 23. What is an endothermic reaction? Which has...Ch. 3 - Prob. 24ECh. 3 - Prob. 25ECh. 3 - 26. How do the three temperature scales differ?
Ch. 3 - Prob. 27ECh. 3 - Prob. 28ECh. 3 - The following equation can be used to convert...Ch. 3 - Prob. 30ECh. 3 - Classify each pure substance as an element or a...Ch. 3 - 32. Classify each pure substance as an element or...Ch. 3 - 33. Classify each substance as a compound or a...Ch. 3 - 34. Classify each substance as a compound or a...Ch. 3 - 35. Classify each mixture as homogeneous or...Ch. 3 - 36. Classify each substance as a pure substance or...Ch. 3 - 37. Classify each property as physical or...Ch. 3 - Classify each property as physical or chemical. a....Ch. 3 - Which of the following processes involving bromine...Ch. 3 - Which of the following properties of ozone (a...Ch. 3 - 41. Classify each change as physical or...Ch. 3 - 42. Classify each change as physical or...Ch. 3 - A block of aluminum is (a) ground into aluminum...Ch. 3 - 44. Several pieces of graphite from a mechanical...Ch. 3 - 45. An automobile gasoline tank holds 42 kg of...Ch. 3 - In the explosion of a hydrogen-filled balloon,...Ch. 3 - 47. Are these data sets on chemical changes...Ch. 3 - 48. Are these data sets on chemical changes...Ch. 3 - Prob. 49ECh. 3 - Prob. 50ECh. 3 - Prob. 51ECh. 3 - Prob. 52ECh. 3 - Prob. 53ECh. 3 - Prob. 54ECh. 3 - Prob. 55ECh. 3 - Prob. 56ECh. 3 - Prob. 57ECh. 3 - Prob. 58ECh. 3 - Prob. 59ECh. 3 - Prob. 60ECh. 3 - 61 A common type of handwarmer contains Iron...Ch. 3 - 62. In a chemical cold pack, two substances are...Ch. 3 - 63. Classify each process as exothermic or...Ch. 3 - Classify each process as exothermic or...Ch. 3 - Perform each temperature conversion. a.212 F to...Ch. 3 - Prob. 66ECh. 3 - The coldest temperature ever measured in the...Ch. 3 - 68. The warmest temperature ever measured in the...Ch. 3 - Prob. 69ECh. 3 - Prob. 70ECh. 3 - 71. The temperature in the South Pole during the...Ch. 3 - Prob. 72ECh. 3 - Prob. 73ECh. 3 - Prob. 74ECh. 3 - 75. Calculate the amount of heat required to raise...Ch. 3 - 76. Calculate the amount of heat required to raise...Ch. 3 - Calculate the amount of heat required to heat a...Ch. 3 - 78. Calculate the amount of heat required to heat...Ch. 3 - If 89 J of heat are added to a pure gold coin with...Ch. 3 - If 57 J heat are added to an aluminum can with a...Ch. 3 - An iron nail with a mass of 12 g absorbs 15 J of...Ch. 3 - Prob. 82ECh. 3 - Prob. 83ECh. 3 - 84. A lead fishing weight with a mass of 57 g...Ch. 3 - An unknown metal with a mass of 28 g absorbs 58 J...Ch. 3 - When 2.8 J of heat are added to 5.6 g of an...Ch. 3 - When 56 J of heat are added to 11 g of a liquid,...Ch. 3 - Prob. 88ECh. 3 - Prob. 89ECh. 3 - Prob. 90ECh. 3 - How much energy (In J) lost when a sample of iron...Ch. 3 - Prob. 92ECh. 3 - Prob. 93ECh. 3 - Prob. 94ECh. 3 - A pure gold ring with a volume of 1.57 cm3 is...Ch. 3 - Prob. 96ECh. 3 - Prob. 97ECh. 3 - Prob. 98ECh. 3 - 99. What is the temperature change (ΔT) in Celsius...Ch. 3 - Prob. 100ECh. 3 - Prob. 101ECh. 3 - Prob. 102ECh. 3 - A backpacker wants to carry enough fuel to heat...Ch. 3 - 104. A cook wants to heat 1.35 kg of water from...Ch. 3 - Evaporating sweat cools the body because...Ch. 3 - Prob. 106ECh. 3 - A 25.0-mL sample of ethanol (density = 0.789g/mL)...Ch. 3 - The wattage of an appliance indicates its average...Ch. 3 - Prob. 110ECh. 3 - What temperature is the same whether it is...Ch. 3 - What temperature on the Celsius scale is equal to...Ch. 3 - 113. Classify each as pure substance or a...Ch. 3 - Classify each as a pure substance or a mixture. If...Ch. 3 - This molecular drawing shows images of acetone...Ch. 3 - This molecular drawing shows of methane molecules...Ch. 3 - Prob. 117ECh. 3 - Global warming refers to the rise in average...Ch. 3 - 119. Examine the data for the maximum and minimum...Ch. 3 - Using white and black circles to represent...Ch. 3 - Prob. 121ECh. 3 - 122. A friend asks you to invest in a new...Ch. 3 - Prob. 123E
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