Chemistry: An Introduction to General, Organic, and Biological Chemistry, Books a la Carte Edition (13th Edition)
13th Edition
ISBN: 9780134554631
Author: Karen C. Timberlake
Publisher: PEARSON
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Question
Chapter 3, Problem 5CI
Interpretation Introduction
To determine: The following,
- The volume, in cubic centimeters, of the iron nails in the box.
- The new level of water in milliliters, in the cylinders after adding 30 nails.
- The amount of heat that must be added to the nails to raise the temperature from 160C to 1250C.
- The amount of heat required to heat up one nail from 250C to its melting point.
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d) Determine the formal charge on the nitrogen atom in each of the structures.
NH3
NH2
N
C
бобкат
: N
N
H
H
Н
H2N-OH
A
B
C
D
E
F
G
Lewis Structure, Hybridization & Molecular Geometry
a) Draw the Lewis Structure of the molecules; Label the hybridization of each carbon atom;
Predict the approximate molecular geometry around each carbon atom.
CH3CHO
CH3CN
b) Draw the Lewis Structure of Nitromethane; Predict the approximate molecular geometry
around the nitrogen atom.
CH3NO2
c) Draw the Lewis Structure; Label the hybridization of the boron atom; Predict the
approximate molecular geometry.
BF3
BF4
a. The structure of the bicarbonate (hydrogen carbonate) ion, HCO3-, HCO3 " is
best described as a hybrid of several contributing resonance forms, two of which
are shown here.
HO
:0:
HO
+
:Ö:
Bicarbonate is crucial for the control of body pH (for example, blood pH
7.4). A more self-indulgent use is in baking soda, where it serves as a
source of CO2 CO2 gas, which gives bread and pastry their fluffy
constituency.
(i) Draw at least one additional resonance form.
=
(ii) Using curved "electron-pushing" arrows, show how these Lewis structures may
be interconverted by movement of electron pairs. (iii) Determine which form or
forms will be the major contributor(s) to the real structure of bicarbonate,
explaining your answer on the basis of the criteria in Section 1-5.
Chapter 3 Solutions
Chemistry: An Introduction to General, Organic, and Biological Chemistry, Books a la Carte Edition (13th Edition)
Ch. 3.1 - Prob. 3.1PPCh. 3.1 - Prob. 3.2PPCh. 3.1 - Classify each of the following as a pure substance...Ch. 3.1 - Classify each of the following as a pure substance...Ch. 3.1 - Prob. 3.5PPCh. 3.1 - Prob. 3.6PPCh. 3.2 - Indicate whether each of the following describes a...Ch. 3.2 - Indicate whether each of the following describes a...Ch. 3.2 - Describe each of the following as a physical or...Ch. 3.2 - Describe each of the following as a physical or...
Ch. 3.2 - Prob. 3.11PPCh. 3.2 - What type of change, physical or chemical, takes...Ch. 3.2 - Describe each property of the element fluorine as...Ch. 3.2 - Describe each property of the element zirconium as...Ch. 3.3 - Prob. 3.15PPCh. 3.3 - Prob. 3.16PPCh. 3.3 - Prob. 3.17PPCh. 3.3 - Calculate the unknown temperature in each of the...Ch. 3.3 - Prob. 3.19PPCh. 3.3 - a. Water is heated to 145 °F. What is the...Ch. 3.4 - Discuss the changes in the potential and kinetic...Ch. 3.4 - Prob. 3.22PPCh. 3.4 - Indicate whether each of the following statements...Ch. 3.4 - Prob. 3.24PPCh. 3.4 - Convert each of the following energy units: a....Ch. 3.4 - Prob. 3.26PPCh. 3.4 - The energy needed to keep a 75-wattlight bulb...Ch. 3.4 - Prob. 3.28PPCh. 3.5 - Calculate the kilocalories for each of the...Ch. 3.5 - Calculate the kilocalories for each of the...Ch. 3.5 - Using the energy values for foods (see TABLE3.7),...Ch. 3.5 - Using the energy values for foods (see TABLE3.7),...Ch. 3.5 - Prob. 3.33PPCh. 3.5 - Prob. 3.34PPCh. 3.5 - Prob. 3.35PPCh. 3.5 - Prob. 3.36PPCh. 3.6 - If the same amount of heat is supplied to samples...Ch. 3.6 - Substances A and B are the same mass and at the...Ch. 3.6 - Use the heat equation to calculate the energy for...Ch. 3.6 - Use the heat equation to calculate the energy for...Ch. 3.6 - Use the heat equation to calculate the energy, in...Ch. 3.6 - Use the heat equation to calculate the energy, in...Ch. 3.7 - Identify each of the following changes of state as...Ch. 3.7 - Identify each of the following changes of state as...Ch. 3.7 - Calculate the heat change at 0 °C for each of the...Ch. 3.7 - Prob. 3.46PPCh. 3.7 - Identify each of the following changes of state as...Ch. 3.7 - Identify each of the following changes of state as...Ch. 3.7 - Prob. 3.49PPCh. 3.7 - 3.50 Calculate the heat change at 100 °C for each...Ch. 3.7 - Prob. 3.51PPCh. 3.7 - Prob. 3.53PPCh. 3.7 - Prob. 3.54PPCh. 3.7 - Prob. 3.55PPCh. 3.7 - Prob. 3.56PPCh. 3.7 - Prob. 3.57PPCh. 3.7 - Prob. 3.58PPCh. 3 - Prob. 3.59UTCCh. 3 - Prob. 3.60UTCCh. 3 - Prob. 3.61UTCCh. 3 - Prob. 3.62UTCCh. 3 - Prob. 3.63UTCCh. 3 - Prob. 3.64UTCCh. 3 - Prob. 3.65UTCCh. 3 - Prob. 3.66UTCCh. 3 - Calculate the energy to heat two cubes (gold and...Ch. 3 - Calculate the energy to heat two cubes (silver and...Ch. 3 - Prob. 3.69UTCCh. 3 - Prob. 3.70UTCCh. 3 - Prob. 3.71APPCh. 3 - Prob. 3.72APPCh. 3 - Prob. 3.73APPCh. 3 - Prob. 3.74APPCh. 3 - Prob. 3.75APPCh. 3 - Prob. 3.76APPCh. 3 - Prob. 3.77APPCh. 3 - Prob. 3.78APPCh. 3 - Prob. 3.79APPCh. 3 - Prob. 3.80APPCh. 3 - Prob. 3.81APPCh. 3 - Calculate each of the following temperatures in...Ch. 3 - What is 15 °F in degrees Celsius and in kelvins?...Ch. 3 - Prob. 3.84APPCh. 3 - A 0.50-g sample of vegetable oil is placed in a...Ch. 3 - A 1.3-g sample of rice is placed in a calorimeter....Ch. 3 - On a hot day, the beach sand gets hot but the...Ch. 3 - On a hot sunny day, you get out of the swimming...Ch. 3 - Prob. 3.89APPCh. 3 - Prob. 3.90APPCh. 3 - The melting point of dibromomethane is 53 °C and...Ch. 3 - Prob. 3.92APPCh. 3 - Prob. 3.93APPCh. 3 - Prob. 3.94APPCh. 3 - Prob. 3.95APPCh. 3 - Prob. 3.96APPCh. 3 - Prob. 3.97CPCh. 3 - A 45-g piece of ice at 0.0 °C is added to a sample...Ch. 3 - Prob. 3.99CPCh. 3 - Prob. 3.100CPCh. 3 - Prob. 3.101CPCh. 3 - A 115-g sample of steam at 100 °C is emitted from...Ch. 3 - Prob. 3.103CPCh. 3 - 3.104 A 125-g piece of metal is heated to 288 °C...Ch. 3 - A metal is thought to be titanium or aluminum....Ch. 3 - 3.106 A metal is thought to be copper or gold....Ch. 3 - Gold, one of the most sought-after metals in the...Ch. 3 - The mileage for a motorcycle with a fuel-tank...Ch. 3 - Answer the following for water samples A and B...Ch. 3 - Prob. 4CICh. 3 - Prob. 5CICh. 3 - Prob. 6CI
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