Introducing Chemistry
Introducing Chemistry
6th Edition
ISBN: 9780134557373
Author: Tro
Publisher: PEARSON
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Chapter 3, Problem 50E

A 56-g sample of iron reacts with 24 g of oxygen to form how many grams of iron oxide?

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13.84. Chlorine atoms react with methane, forming HCI and CH3. The rate constant for the reaction is 6.0 × 107 M¹ s¹ at 298 K. When the experiment was run at three other temperatures, the following data were collected: T (K) k (M-1 s-1) 303 6.5 × 107 308 7.0 × 107 313 7.5 x 107 a. Calculate the values of the activation energy and the frequency factor for the reaction. b. What is the value of the rate constant in the lower stratosphere, where T = 218 K?
My Organic Chemistry textbook says about the formation of cyclic hemiacetals, "Such intramolecular reactions to form five- and six-membered rings are faster than the corresponding intermolecular reactions.  The two reacting functional groups, in this case OH and C=O, are held in close proximity, increasing the probability of reaction."According to the book, the formation of cyclic hemiacetals occurs in acidic conditions. So my question is whether the carbonyl group in this reaction reacts first with the end alcohol on the same molecule or with the ethylene glycol.  And, given the explanation in the book, if it reacts first with ethylene glycol before its own end alcohol, why would it?  I don't need to know the final answer.  I need to know WHY it would not undergo an intermolecular reaction prior to reacting with the ethylene glycol if that is the case.  Please do not use an AI answer.
Don't used hand raiting and don't used Ai solution

Chapter 3 Solutions

Introducing Chemistry

Ch. 3 - Define matter and list some examples.Ch. 3 - Prob. 2ECh. 3 - What are the three states of matter?Ch. 3 - Prob. 4ECh. 3 - Prob. 5ECh. 3 - Prob. 6ECh. 3 - Prob. 7ECh. 3 - Prob. 8ECh. 3 - 9. What is a mixture? Ch. 3 - 10. What is the difference between a homogeneous...Ch. 3 - What is a pure substance?Ch. 3 - What is an element? A compound?Ch. 3 - What is the difference between a mixture and a...Ch. 3 - Prob. 14ECh. 3 - 15. What is the difference between a physical...Ch. 3 - Prob. 16ECh. 3 - Prob. 17ECh. 3 - Prob. 18ECh. 3 - Prob. 19ECh. 3 - What is chemical energy? List some examples of...Ch. 3 - Prob. 21ECh. 3 - 22. What is an exothermic reaction? Which has...Ch. 3 - 23. What is an endothermic reaction? Which has...Ch. 3 - Prob. 24ECh. 3 - Prob. 25ECh. 3 - 26. How do the three temperature scales differ? Ch. 3 - Prob. 27ECh. 3 - Prob. 28ECh. 3 - The following equation can be used to convert...Ch. 3 - Prob. 30ECh. 3 - Classify each pure substance as an element or a...Ch. 3 - 32. Classify each pure substance as an element or...Ch. 3 - 33. Classify each mixture as homogeneous or...Ch. 3 - 34. Classify each mixture as homogeneous or...Ch. 3 - 35. Classify each substance as a pure substance or...Ch. 3 - 36. Classify each substance as a pure substance or...Ch. 3 - Classify each property as physical or chemical. a....Ch. 3 - Classify each property as physical or chemical. a....Ch. 3 - Which of the following properties of ethylene(a...Ch. 3 - Which of the following properties of ozone (a...Ch. 3 - 41. Classify each change as physical or...Ch. 3 - 42. Classify each change as physical or...Ch. 3 - A block of aluminum is (a) ground into aluminum...Ch. 3 - 44. Several pieces of graphite from a mechanical...Ch. 3 - 45. An automobile gasoline tank holds 42 kg of...Ch. 3 - In the explosion of a hydrogen-filled balloon,...Ch. 3 - 47. Are these data sets on chemical changes...Ch. 3 - 48. Are these data sets on chemical changes...Ch. 3 - Prob. 49ECh. 3 - 50. A 56-g sample of iron reacts with 24 g of...Ch. 3 - Prob. 51ECh. 3 - Prob. 52ECh. 3 - Prob. 53ECh. 3 - Prob. 54ECh. 3 - Prob. 55ECh. 3 - Prob. 56ECh. 3 - Prob. 57ECh. 3 - Prob. 58ECh. 3 - Prob. 59ECh. 3 - Prob. 60ECh. 3 - 61 A common type of handwarmer contains Iron...Ch. 3 - 62. In a chemical cold pack, two substances are...Ch. 3 - 63. Classify each process as exothermic or...Ch. 3 - Classify each process as exothermic or...Ch. 3 - Perform each temperature conversion. a.212 F to...Ch. 3 - Prob. 66ECh. 3 - The coldest temperature ever measured in the...Ch. 3 - 68. The warmest temperature ever measured in the...Ch. 3 - 69. Vodka does not freeze in the freezer because...Ch. 3 - Liquid helium boils at 4.2 K. Convert this...Ch. 3 - 71. The temperature in the South Pole during the...Ch. 3 - Prob. 72ECh. 3 - Prob. 73ECh. 3 - Prob. 74ECh. 3 - 75. Calculate the amount of heat required to raise...Ch. 3 - 76. Calculate the amount of heat required to raise...Ch. 3 - Calculate the amount of heat required to heat a...Ch. 3 - 78. Calculate the amount of heat required to heat...Ch. 3 - If 89 J of heat are added to a pure gold coin with...Ch. 3 - If 57 J heat are added to an aluminum can with a...Ch. 3 - An iron nail with a mass of 12 g absorbs 15 J of...Ch. 3 - Prob. 82ECh. 3 - Prob. 83ECh. 3 - 84. A lead fishing weight with a mass of 57 g...Ch. 3 - An unknown metal with a mass of 28 g absorbs 58 J...Ch. 3 - When 2.8 J of heat are added to 5.6 g of an...Ch. 3 - When 56 J of heat are added to 11 g of a liquid,...Ch. 3 - Prob. 88ECh. 3 - Prob. 89ECh. 3 - Prob. 90ECh. 3 - How much energy (In J) lost when a sample of iron...Ch. 3 - Prob. 92ECh. 3 - Prob. 93ECh. 3 - Prob. 94ECh. 3 - A pure gold ring with a volume of 1.57 cm3 is...Ch. 3 - Prob. 96ECh. 3 - Prob. 97ECh. 3 - Prob. 98ECh. 3 - 99. What is the temperature change (ΔT) in Celsius...Ch. 3 - Prob. 100ECh. 3 - Prob. 101ECh. 3 - Prob. 102ECh. 3 - A backpacker wants to carry enough fuel to heat...Ch. 3 - 104. A cook wants to heat 1.35 kg of water from...Ch. 3 - Evaporating sweat cools the body because...Ch. 3 - Prob. 106ECh. 3 - A 15.7-g aluminum block is warmed to 53.2C and...Ch. 3 - A 25.0-mL sample of ethanol (density = 0.789g/mL)...Ch. 3 - The wattage of an appliance indicates its average...Ch. 3 - Prob. 110ECh. 3 - What temperature is the same whether it is...Ch. 3 - What temperature on the Celsius scale is equal to...Ch. 3 - 113. Classify each as pure substance or a...Ch. 3 - Classify each as a pure substance or a mixture. If...Ch. 3 - This molecular drawing shows images of acetone...Ch. 3 - This molecular drawing shows of methane molecules...Ch. 3 - Prob. 117ECh. 3 - Global warming refers to the rise in average...Ch. 3 - 119. Examine the data for the maximum and minimum...Ch. 3 - Using white and black circles to represent...Ch. 3 - Prob. 121QGWCh. 3 - 122. A friend asks you to invest in a new...Ch. 3 - Prob. 123QGW
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