(a)
Interpretation:
Most acidic proton should be identified in the given compounds.
Concept introduction:
Acidic strength of the molecule depends on the stability of the Conjugate ion.
- Conjugate ion is the ion, which is produced by de protonating the most acidic proton from the molecule.
This conjugate ion stability effected by four factors called ARIO (Atom Resonance Inductive effect Orbital) concept. If the conjugate anion is more stabilized, the acid considered as strong acid and the anion is weak base.
- If negative charge located atom is larger enough to hold the negative charge, the anion attains stability.
- If the anion is resonance stabilized, the corresponding acid is more acidic.
- If withdrawing inductive effect is present near to the negative charge located position, acidity increases.
Hybridized orbital stabilizes the negative charge better than other hybridizations.
To identify: the most acidic proton in the given molecule.
(b)
Interpretation:
Most acidic proton should be identified in the given compounds.
Concept introduction:
Acidic strength of the molecule depends on the stability of the Conjugate ion.
- Conjugate ion is the ion, which is produced by de protonating the most acidic proton from the molecule.
This conjugate ion stability effected by four factors called ARIO (Atom Resonance Inductive effect Orbital) concept. If the conjugate anion is more stabilized, the acid considered as strong acid and the anion is weak base.
- If negative charge located atom is larger enough to hold the negative charge, the anion attains stability.
- If the anion is resonance stabilized, the corresponding acid is more acidic.
- If withdrawing inductive effect is present near to the negative charge located position, acidity increases.
Hybridized orbital stabilizes the negative charge better than other hybridizations.
To identify: the most acidic proton in the given molecule.
(c)
Interpretation:
Most acidic proton should be identified in the given compounds.
Concept introduction:
Acidic strength of the molecule depends on the stability of the Conjugate ion.
- Conjugate ion is the ion, which is produced by de protonating the most acidic proton from the molecule.
This conjugate ion stability effected by four factors called ARIO (Atom Resonance Inductive effect Orbital) concept. If the conjugate anion is more stabilized, the acid considered as strong acid and the anion is weak base.
- If negative charge located atom is larger enough to hold the negative charge, the anion attains stability.
- If the anion is resonance stabilized, the corresponding acid is more acidic.
- If withdrawing inductive effect is present near to the negative charge located position, acidity increases.
Hybridized orbital stabilizes the negative charge better than other hybridizations.
To identify: the most acidic proton in the given molecule.
(d)
Interpretation:
Most acidic proton should be identified in the given compounds.
Concept introduction:
Acidic strength of the molecule depends on the stability of the Conjugate ion.
- Conjugate ion is the ion, which is produced by de protonating the most acidic proton from the molecule.
This conjugate ion stability effected by four factors called ARIO (Atom Resonance Inductive effect Orbital) concept. If the conjugate anion is more stabilized, the acid considered as strong acid and the anion is weak base.
- If negative charge located atom is larger enough to hold the negative charge, the anion attains stability.
- If the anion is resonance stabilized, the corresponding acid is more acidic.
- If withdrawing inductive effect is present near to the negative charge located position, acidity increases.
Hybridized orbital stabilizes the negative charge better than other hybridizations.
To identify: the most acidic proton in the given molecule.
(e)
Interpretation:
Most acidic proton should be identified in the given compounds.
Concept introduction:
Acidic strength of the molecule depends on the stability of the Conjugate ion.
- Conjugate ion is the ion, which is produced by de protonating the most acidic proton from the molecule.
This conjugate ion stability effected by four factors called ARIO (Atom Resonance Inductive effect Orbital) concept. If the conjugate anion is more stabilized, the acid considered as strong acid and the anion is weak base.
- If negative charge located atom is larger enough to hold the negative charge, the anion attains stability.
- If the anion is resonance stabilized, the corresponding acid is more acidic.
- If withdrawing inductive effect is present near to the negative charge located position, acidity increases.
Hybridized orbital stabilizes the negative charge better than other hybridizations.
To identify: the most acidic proton in the given molecule.
(f)
Interpretation:
Most acidic proton should be identified in the given compounds.
Concept introduction:
Acidic strength of the molecule depends on the stability of the Conjugate ion.
- Conjugate ion is the ion, which is produced by de protonating the most acidic proton from the molecule.
This conjugate ion stability effected by four factors called ARIO (Atom Resonance Inductive effect Orbital) concept. If the conjugate anion is more stabilized, the acid considered as strong acid and the anion is weak base.
- If negative charge located atom is larger enough to hold the negative charge, the anion attains stability.
- If the anion is resonance stabilized, the corresponding acid is more acidic.
- If withdrawing inductive effect is present near to the negative charge located position, acidity increases.
Hybridized orbital stabilizes the negative charge better than other hybridizations.
To identify: the most acidic proton in the given molecule.
(g)
Interpretation:
Most acidic proton should be identified in the given compounds.
Concept introduction:
Acidic strength of the molecule depends on the stability of the Conjugate ion.
- Conjugate ion is the ion, which is produced by de protonating the most acidic proton from the molecule.
This conjugate ion stability effected by four factors called ARIO (Atom Resonance Inductive effect Orbital) concept. If the conjugate anion is more stabilized, the acid considered as strong acid and the anion is weak base.
- If negative charge located atom is larger enough to hold the negative charge, the anion attains stability.
- If the anion is resonance stabilized, the corresponding acid is more acidic.
- If withdrawing inductive effect is present near to the negative charge located position, acidity increases.
Hybridized orbital stabilizes the negative charge better than other hybridizations.
To identify: the most acidic proton in the given molecule.
(h)
Interpretation:
Most acidic proton should be identified in the given compounds.
Concept introduction:
Acidic strength of the molecule depends on the stability of the Conjugate ion.
- Conjugate ion is the ion, which is produced by de protonating the most acidic proton from the molecule.
This conjugate ion stability effected by four factors called ARIO (Atom Resonance Inductive effect Orbital) concept. If the conjugate anion is more stabilized, the acid considered as strong acid and the anion is weak base.
- If negative charge located atom is larger enough to hold the negative charge, the anion attains stability.
- If the anion is resonance stabilized, the corresponding acid is more acidic.
- If withdrawing inductive effect is present near to the negative charge located position, acidity increases.
Hybridized orbital stabilizes the negative charge better than other hybridizations.
To identify: the most acidic proton in the given molecule.
Want to see the full answer?
Check out a sample textbook solutionChapter 3 Solutions
Organic Chemistry, Third Edition Binder Ready Version
- Speaking of composite materials, indicate the correct option:(A). Composite materials can only be: metal-polymer or polymer-polymer.(B). Composite materials can be made up of particles, but not fibers or sheets.(C). When the reinforcing particles are uniformly distributed in a composite material, there may be a greater tendency for it to have isotropic properties.(D). None of the above is correct.arrow_forwardIf we are talking about viscoelastic modulus or viscoelastic relaxation modulus in polymers, indicate the correct option.(A). It reports the variation of elastic behavior as a function of time.(B). It is only useful for defining its glass transition temperature.(C). It only allows us to define the polymer degradation temperature.(D). Neither option is correct.arrow_forwardWhen natural light falls perpendicularly on a material A, it has a reflectivity of 0.813%. Indicate the value of the refractive index.arrow_forward
- In piezoelectricity and piezoelectric ceramics, one of the following options is false:(A). Piezoelectricity allows an electrical signal to be transformed into a mechanical one.(B). PbZrO3 is a well-known piezoelectric ceramic.(C). Piezoelectricity and ferroelectricity in general have no relationship.(D). One of the applications of piezoelectricity is sonar.arrow_forward(30 MARKS) Give the major product(s ) formed including relevant stereochemistry or the complete reaction conditions for the following reactions. More than one step may be required for each reaction arrow, in which case the steps must be numbered 1), 2) etc. (2 marks each box) h) i) h) OH i) HO H3PO4, heat 2 Brarrow_forwardNonearrow_forward
- Indicate which option is false(A). Resistivity has a residual component and a thermal component.(B). In some materials resistivity increases with T and in others it decreases.(C). In insulating materials, resistivity is very low.arrow_forwardIn ceramic materials, in relation to polymorphism, the same substance crystallizes differently when external conditions vary. Is this correct?arrow_forwardIndicate the type of bond that is considered to be a hydrogen bond.(A). Permanent dipole-dipole interaction between polar molecules.(B). Mixed ionic-covalent bond.(C). Principal interatomic bond(D). Van del Waals forces.arrow_forward
- Retro aldol: NaOH H₂O H NaOH & d H₂O Harrow_forwardDraw the product of the reaction shown below. Ignore inorganic byproducts. H conc. HBr Drawing Qarrow_forwardCalculate the atomic packing factor of diamond knowing that the number of Si atoms per cm3 is 2.66·1022 and that the atomic radii of silicon and oxygen are, respectively, 0.038 and 0.117 nm.arrow_forward
- ChemistryChemistryISBN:9781305957404Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCostePublisher:Cengage LearningChemistryChemistryISBN:9781259911156Author:Raymond Chang Dr., Jason Overby ProfessorPublisher:McGraw-Hill EducationPrinciples of Instrumental AnalysisChemistryISBN:9781305577213Author:Douglas A. Skoog, F. James Holler, Stanley R. CrouchPublisher:Cengage Learning
- Organic ChemistryChemistryISBN:9780078021558Author:Janice Gorzynski Smith Dr.Publisher:McGraw-Hill EducationChemistry: Principles and ReactionsChemistryISBN:9781305079373Author:William L. Masterton, Cecile N. HurleyPublisher:Cengage LearningElementary Principles of Chemical Processes, Bind...ChemistryISBN:9781118431221Author:Richard M. Felder, Ronald W. Rousseau, Lisa G. BullardPublisher:WILEY