Chemistry In Focus
7th Edition
ISBN: 9781337670425
Author: Tro
Publisher: Cengage
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Chapter 3, Problem 3E
What defines an element? How many naturally occurring elements exist?
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When 15.00 mL of 3.00 M NaOH was mixed in a calorimeter with 12.80 mL of 3.00 M HCl, both initially at room temperature (22.00 C), the temperature increased to 29.30 C. The resultant salt solution had a mass of 27.80 g and a specific heat capacity of 3.74 J/Kg. What is heat capacity of the calorimeter (in J/C)? Note: The molar enthalpy of neutralization per mole of HCl is -55.84 kJ/mol.
Q6: Using acetic acid as the acid, write the balanced chemical equation for the protonation of
the two bases shown (on the -NH2). Include curved arrows to show the mechanism.
O₂N-
O₂N.
-NH2
-NH2
a) Which of the two Bronsted bases above is the stronger base? Why?
b) Identify the conjugate acids and conjugate bases for the reactants.
c) Identify the Lewis acids and bases in the reactions.
Chapter 3 Solutions
Chemistry In Focus
Ch. 3 - Determining the Number of Protons and Electrons in...Ch. 3 - Prob. 3.2YTCh. 3 - Determining Protons, Neutrons, and Electrons How...Ch. 3 - Calculating Atomic Mass Magnesium has three...Ch. 3 - The Mole Concept A diamond, which is pure carbon,...Ch. 3 - The Mole Concept II Calculate the number of atoms...Ch. 3 - Your friend tells you about an article that he...Ch. 3 - Prob. 2SCCh. 3 - Prob. 3SCCh. 3 - Copper is composed of two naturally occurring...
Ch. 3 - Prob. 5SCCh. 3 - Which pair of elements do you expect to be most...Ch. 3 - Which statement is true of the quantum mechanical...Ch. 3 - Why is it important to understand atoms?Ch. 3 - Prob. 2ECh. 3 - What defines an element? How many naturally...Ch. 3 - Prob. 4ECh. 3 - Prob. 5ECh. 3 - Prob. 6ECh. 3 - Prob. 7ECh. 3 - Prob. 8ECh. 3 - Prob. 9ECh. 3 - Prob. 10ECh. 3 - Explain the quantum mechanical model for the atom....Ch. 3 - Give two examples of each: a. alkali metal b....Ch. 3 - Which elements exist as diatomic molecules?Ch. 3 - Explain the difference and similarity between...Ch. 3 - Prob. 15ECh. 3 - Determine the charge of each of the following: a...Ch. 3 - Determine the number of protons and electrons in...Ch. 3 - Determine the number of protons and electrons in...Ch. 3 - Give the atomic number (Z) and the mass number (A)...Ch. 3 - Prob. 20ECh. 3 - The following isotopes have applications in...Ch. 3 - The following isotopes are important in nuclear...Ch. 3 - 14C is used in carbon dating of artifacts....Ch. 3 - 40K is used to measure the age of Earth. Determine...Ch. 3 - Prob. 25ECh. 3 - Prob. 26ECh. 3 - Give electron configurations according to the Bohr...Ch. 3 - Give electron configurations according to the Bohr...Ch. 3 - Prob. 29ECh. 3 - How many valence electrons are in each element of...Ch. 3 - Prob. 31ECh. 3 - Draw electron configurations for each of the...Ch. 3 - Which two of the following elements would you...Ch. 3 - Group the following elements into three similar...Ch. 3 - We have seen that the reactivity of an element is...Ch. 3 - What is the electron configuration of Mg2+? How...Ch. 3 - Classify each of the following elements as a...Ch. 3 - Classify each of the following as a metal, a...Ch. 3 - Calculate the atomic mass of neon (Ne), which is...Ch. 3 - An element has two naturally occurring isotopes....Ch. 3 - A fictitious element has two naturally occurring...Ch. 3 - Copper has two naturally occurring isotopes. Cu-63...Ch. 3 - How many moles of titanium are present in 124 g of...Ch. 3 - Prob. 44ECh. 3 - How many moles are there in each sample? a. 45 mg...Ch. 3 - How many moles are there in each sample? a. 55.0 g...Ch. 3 - What is the mass of each sample? a.1.8 mol S...Ch. 3 - What is the mass of each sample? a.2.75 mol Fe...Ch. 3 - Determine the number of atoms in each sample....Ch. 3 - Determine the number of atoms in each sample....Ch. 3 - How many Ag atoms are present in a piece of pure...Ch. 3 - How many platinum atoms are in a pure platinum...Ch. 3 - A pure gold necklace has a volume of 1.8cm3. How...Ch. 3 - A titanium bicycle component has a volume of...Ch. 3 - An iron sphere has a radius of 3.4 cm. How many...Ch. 3 - Calculate the number of atoms in the universe. The...Ch. 3 - The introduction to this chapter states that...Ch. 3 - Suppose the absolute value of the charge of the...Ch. 3 - When we refer to doughnuts or cookies, we often...Ch. 3 - Prob. 60ECh. 3 - Why does Avogadros number have such an odd value?...Ch. 3 - Prob. 62ECh. 3 - Prob. 63ECh. 3 - Prob. 64ECh. 3 - Here are three fictitious elements and a molecular...Ch. 3 - Prob. 66ECh. 3 - Gather any two of the following items, measure...
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- Q5: For the two reactions below: a) Use curved electron-pushing arrows to show the mechanism for the reaction in the forward direction. Redraw the compounds to explicitly illustrate all bonds that are broken and all bonds that are formed. b) Label Bronsted acids and bases in the left side of the reactions. c) For reaction A, which anionic species is the weakest base? Which neutral compound is the stronger acid? Is the forward or reverse reaction favored? d) Label Lewis acids and bases, nucleophiles and electrophiles in the left side of the reactions. A. 용 CH3OH я хон CH3O OH B. HBr CH3ONa NaBr CH3OHarrow_forwardpotential energy Br b) Translate the Newman projection below to its wedge-and-dash drawing. F H. OH CH3 CI c) Isopentane (2-methylbutane) is a compound containing a branched carbon chain. Draw a Newman projection of six conformations about the C2-C3 bond of isopentane. On the curve of potential energy versus angle of internal rotation for isopentane, label each energy maximum and minimum with one of the conformations. 0° 。 F A B D C angle of internal rotation E F 360° (=0°) JDownlarrow_forwardQ7: Identify the functional groups in these molecules a) CH 3 b) Aspirin: HO 'N' Capsaicin HO O CH3 CH 3arrow_forward
- Q2: Name the following alkanesarrow_forward1. Complete the following table in your laboratory notebook. Substance Formula Methanol CH3OH Ethanol C2H5OH 1-Propanol C3H7OH 1-Butanol C4H9OH Pentane C5H12 Hexane C6H14 Water H₂O Acetone C3H60 Structural Formula Molecular Weight (g/mol) Hydrogen Bond (Yes or No)arrow_forwardQ1: Compare the relative acidity in each pair of compounds. Briefly explain. (a) CH3OH vs NH 3 (b) HF vs CH3COOH (c) NH3 vs CH4 (d) HCI vs HI (e) CH3COOH vs CH3SH (f) H₂C=CH2 vs CH3 CH3 (g) compare the acidity of the two bolded hydrogens O. H N- (h) compare the acidity of the two bolded hydrogens, draw resonance structures to explain H H Harrow_forward
- Q3: Rank the following molecules in order of decreasing boiling point: (a) 3-methylheptane; (b) octane; (c) 2,4-dimethylhexane; (d) 2,2,4-trimethylpentane.arrow_forwardQ5: Conformations of Alkanes a) Draw a Newman Projection of the compound below about the C2-C3 bond. H3C Cli... H IIIH Br CH3arrow_forwardThe ability of atoms to associate with each other depends ona) the electronic structure and its spatial orientation.b) the electron affinity.c) The other two answers are correct.arrow_forward
- What is the final volume after you reach the final temperature? I put 1.73 but the answer is wrong not sure why The initial volume of gas is 1.60 LL , the initial temperature of the gas is 23.0 °C°C , and the system is in equilibrium with an external pressure of 1.2 bar (given by the sum of a 1 bar atmospheric pressure and a 0.2 bar pressure due to a brick that rests on top of the piston). Then, as you did in Exercise 1, you heat the gas slowly until the temperature reaches 48.2 °Carrow_forwardQ4: Identify the type of Carbon ( methyl, primary, secondary, etc. ) indicated by this arrow.arrow_forwardQ3: Curved Arrows, Lewis Acids & Bases, Nucleophiles and Electrophiles Considering the following reactions: a) Predict the products to complete the reactions. b) Use curved electron-pushing arrows to show the mechanism for the reaction in the forward direction. Redraw some of the compounds to explicitly illustrate all bonds that are broken and all bonds that are formed. c) Label Lewis acids and bases, nucleophiles and electrophiles in the reactions. A. S + AICI 3 B. + H₂Oarrow_forward
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