Chapter 3, Problem 3C.1BE

Interpretation Introduction

Interpretation: The value of $S_{\text{m}}\left(\text{10}\text{K}\right)-S_{\text{m}}\left(0\right)$ for silver has to be calculated.

Concept introduction: $C_{p,\text{m}}$ represents the molar heat capacity.  At low temperatures, the value of $C_{p,\text{m}}$ for solids is calculated by the Debye law.  The Debye law is expressed as,

  $C_{p,\text{m}}\left(T\right)=a{T}^3$

Where,

• • $C_{p,\text{m}}$ is the = molar heat capacity at constant pressure
• • $a$ is the = Debye’s constant
• • $T$ is the = temperature