Chemistry for Engineering Students
4th Edition
ISBN: 9781337398909
Author: Lawrence S. Brown, Tom Holme
Publisher: Cengage Learning
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Chapter 3, Problem 3.76PAE
Interpretation Introduction
To determine:
The electrolyte.
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1)A solution of Na2CO3 is prepared by dissolving 0.511 g of the solid in approximately 30 mL of water. How many moles of Na2CO3 does this solution contain?Express your answer to the correct number of significant figures.
2)Suppose the Na2CO3 solution described in Question 1 is added to a solution that contains excess CaCl2? What is the maximum number of moles of solid CaCO3 that can form in the resulting precipitation reaction?
Normal saline is an isotonic (to humans) solution which is used in medicine for volume resuscitation. Normal saline
comes in 1 Liter bags that have a sodium chloride (Nacl) concentration of 0.9% (or 0.9 g/dL).
What mass of sodium is in one bag of normal saline solution?
dL= deciliter (one tenth of a liter -> 100 mL)
Atomic mass of Na= 23
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la low
Mole is the term used to express the quantities of substances involved in a chemical reaction. Mole is defined as the amount of a substance that contains Avogadro's number of particles
(atoms, ions, molecules, etc.). Avogadro's number is defined as the number of atoms present in 12 g of carbon-12 isotope, with a numerical value equal to 6.022 x 1023. The mole is a
unit similar to a dozen; one dozen
equivalent to 12 the same way that one mole is equivalent to 6.022 x 1023.
You could use this information to write equalities:
12 molecules of H2O = 1 dozen of H2O
6.022 x 1023 molecules of H2O = 1 mol of H2O
For example, if I had 18 molecules of water, I would have
18 molecules of water x
dozen of water
= 1.5 dozen of water
12 molecules of water
Molar mass is the mass in grams of 1 mol of substance numerically equal to molecular weight in amu (atomic mass unit). Mass is a measure of quantity, and when you use a balance to
weigh a sample, the scale is using a set of standards to determine…
Chapter 3 Solutions
Chemistry for Engineering Students
Ch. 3 - • describe the chemical processes used in biomass...Ch. 3 - Prob. 2COCh. 3 - list at least three quantities that must be...Ch. 3 - Write balanced chemical equations for simple...Ch. 3 - Prob. 5COCh. 3 - Prob. 6COCh. 3 - Interconvert between mass, number of molecules,...Ch. 3 - Determine a chemical formula from elemental...Ch. 3 - define the concentration of a solution and...Ch. 3 - Calculate the molarity of solutions prepared by...
Ch. 3 - Prob. 11COCh. 3 - Prob. 12COCh. 3 - Prob. 13COCh. 3 - write molecular and ionic equations for acidbase...Ch. 3 - Prob. 3.1PAECh. 3 - Prob. 3.2PAECh. 3 - Prob. 3.3PAECh. 3 - A newspaper article states that biomass has...Ch. 3 - Prob. 3.5PAECh. 3 - Prob. 3.6PAECh. 3 - Which symbols are used to indicate solids,...Ch. 3 - How is the addition of heat symbolized in a...Ch. 3 - Prob. 3.9PAECh. 3 - 3.10 Define the term stoichiometric coefficient.Ch. 3 - 3.11 Balance these equations. (a) Al(s) + O2(g)(...Ch. 3 - 3.11 Balance the following equations. (a) CaC2(s)...Ch. 3 - 3.13 An explosive whose chemical formula is...Ch. 3 - 3.14 A number of compounds are used in cement, and...Ch. 3 - 3.15 Ethanol, C2H5OH is found in gasoline blends...Ch. 3 - 3.16 Balance the following equations. (a) reaction...Ch. 3 - 3.17 Write balanced chemical equations for the...Ch. 3 - 3.18 Diborane and related compounds were proposed...Ch. 3 - 3.19 Silicon nitride, Si3N4, is used as a...Ch. 3 - Prob. 3.21PAECh. 3 - Prob. 3.20PAECh. 3 - Prob. 3.23PAECh. 3 - Prob. 3.22PAECh. 3 - 3.24 Classify the following compounds as...Ch. 3 - 3.25 The following compounds are water-soluble....Ch. 3 - 3.26 Decide whether each of the following is...Ch. 3 - Prob. 3.27PAECh. 3 - 3.28 A packaging engineer is working on a new...Ch. 3 - 3.29 Classify each of these as an acid or a base....Ch. 3 - 3.30 Define the term spectator ion.Ch. 3 - 3.31 What is the difference between a total ionic...Ch. 3 - 3.32 Balance the following equations and then...Ch. 3 - 3.33 Balance the following equations, and then...Ch. 3 - 3.34 In principle, it may be possible to engineer...Ch. 3 - 3.35 Explain the concept of the mole in your own...Ch. 3 - 3.36 How many entities are present in each of the...Ch. 3 - 3.37 If atypical grain of sand occupies a volume...Ch. 3 - 3.38 Estimate the size of a particle 1 mole of...Ch. 3 - 3.39 Calculate the molar mass of each of the...Ch. 3 - 3.40 Calculate the molar masses (in grams per...Ch. 3 - 3.41 Calculate the molar mass of each of these...Ch. 3 - Prob. 3.42PAECh. 3 - 3.43 Calculate the molar mass of the following...Ch. 3 - 3.44 Determine the molar mass of these ceramic...Ch. 3 - A chemist needs exactly 2 moles of KNO3 to make a...Ch. 3 - 3.46 What mass of ozone (O3) contains 4.5 moles of...Ch. 3 - 3.47 Calculate the mass in grams of each the...Ch. 3 - 3.48 Calculate the mass in grams of 13.5 mol of...Ch. 3 - 3.49 How many moles are present in the given...Ch. 3 - 3.50 A test of an automobile engine's exhaust...Ch. 3 - 3.51 Modern instruments can measure a mass as...Ch. 3 - 3.52 How many H atoms are present in 7.52 g of...Ch. 3 - 3.53 How many O atoms are present in 214 g of...Ch. 3 - A sample of H2C2O4.2H2O of mass 3.35 g is heated...Ch. 3 - 3.55 An average person inhales roughly 2.5 g of O2...Ch. 3 - 3.56 A large family of boron-hydrogen compounds...Ch. 3 - Prob. 3.57PAECh. 3 - 3.58 Determine the simplest formulas of the...Ch. 3 - 3.59 The composition of materials such as alloys...Ch. 3 - 3.60 Copper can have improved wear resistance if...Ch. 3 - 3.61 Calculate the molarity of each of the...Ch. 3 - 3.62 What is the molarity of each ion present in...Ch. 3 - 3.63 How many moles of solute are present in each...Ch. 3 - 3.64 How many grams of solute are present in each...Ch. 3 - 3.65 Determine the final molarity for the...Ch. 3 - Prob. 3.66PAECh. 3 - Prob. 3.67PAECh. 3 - 3.68 Magnesium is lighter than other structural...Ch. 3 - Prob. 3.69PAECh. 3 - Prob. 3.70PAECh. 3 - 3.71 What is meant by the term carbon reservoir?...Ch. 3 - Prob. 3.72PAECh. 3 - Prob. 3.73PAECh. 3 - Prob. 3.74PAECh. 3 - 3.75 The following pictures show a molecular-scale...Ch. 3 - Prob. 3.76PAECh. 3 - 3.77 Answer each of the following questions. Note...Ch. 3 - 3.78 Consider two samples of liquid: I mole of...Ch. 3 - 3.79 Consider two samples. Sample A contains 2...Ch. 3 - 3.80 Which one of the following metal samples...Ch. 3 - 3.81 The particulate scale drawing shown depicts...Ch. 3 - 3.82 The particulate scale drawing shown depicts...Ch. 3 - 3.83 For the reaction of nitrogen, N2, and...Ch. 3 - 3.84 The picture shown depicts the species present...Ch. 3 - 3.85 The particulate drawing shown represents an...Ch. 3 - 3.86 When a solution is diluted, solvent is added...Ch. 3 - 3.87 Nitric acid (HNO3) can be produced by the...Ch. 3 - 3.88 One Step in the enrichment of uranium for use...Ch. 3 - 3.89 Pyridine has the molecular formula C5H5N....Ch. 3 - 3.90 Pyrrole has the molecular formula C4H5N. When...Ch. 3 - 3.91 Hydrogen cyanide (HCN) is extremely toxic,...Ch. 3 - 3.92 Many chemical reactions take place in the...Ch. 3 - 3.93 Adipic acid is used in the production of...Ch. 3 - 3.94 Calcium carbonate (limestone, CaCO3)...Ch. 3 - 3.95 Cumene is a hydrocarbon, meaning that it...Ch. 3 - 3.96 Methyl cyanoacrylate is the chemical name for...Ch. 3 - 3.97 A low-grade form of iron ore is called...Ch. 3 - 3.98 The characteristic odor of decaying flesh is...Ch. 3 - 3.99 Iron—platinum alloys may be useful as...Ch. 3 - 3.100 Some aluminum—lithium alloys display the...Ch. 3 - 3.101 Which (if any) of the following compounds...Ch. 3 - 3.102 Classify the following compounds as acids or...Ch. 3 - 3.103 What is the mass in grams of solute in 250.0...Ch. 3 - 3.104 What volume of 0.123 M NaOH in milliliters...Ch. 3 - 3.105 Nitric acid is often sold and transported as...Ch. 3 - 3.106 Twenty-five mL of a 0.388 M solution of...Ch. 3 - 3.107 As computer processor speeds increase, it is...Ch. 3 - 3.108 As chip speeds increase, the width of the...Ch. 3 - 3.109 Materials engineers often create new alloys...Ch. 3 - 3.110 The protein that carries oxygen in the blood...Ch. 3 - 3.111 The chlorophyll molecule responsible for...Ch. 3 - 3.112 In one experiment, the burning of 0.614 g of...Ch. 3 - 3.113 MgCl2 is often found as an impurity in table...Ch. 3 - Prob. 3.114PAECh. 3 - 3.115 The average person exhales 1.0 kg of carbon...Ch. 3 - 3.116 The simplest approximate chemical formula...Ch. 3 - 3.117 For the oxides of iron, FeO, Fe2O3, and...Ch. 3 - 3.118 Consider common sugars such as glucose...Ch. 3 - Prob. 3.119PAECh. 3 - 3.120 1f you have 32.6 g of sodium carbonate that...Ch. 3 - 3.121 If you have 21.1 g of iron(II) nitrate that...Ch. 3 - 3.122 What type of reasoning were we using when we...Ch. 3 - 3.123 Most periodic tables provide molar masses...
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- 3.122 What type of reasoning were we using when we developed the equation for dilution, MiVi=MfVf ?arrow_forward3.68 Magnesium is lighter than other structural metals, so it is increasingly important in the design of more efficient vehicles. Mg2+ ions are present in seawater, and the metal is often prepared by "harvesting" these ions and converting them to Mg metal. The average magnesium content of the oceans is about 1270 g Mg2+ per ton of seawater, and the density of seawater is about 1.03 g/mL. What is the molarity of Mg2+ ions in seawater? The design for a concept car calls for 103 kg of magnesium per vehicle. How many gallons of seawater would be required to supply enough magnesium to build one of these ears?arrow_forwardColorful fireworks often involve the decomposition of barium nitrate and potassium chlorate and the reaction of the metals magnesium, aluminum, and iron with oxygen. (a) Write the formulas of barium nitrate and potassium chlorate. (b) The decomposition of solid potassium chlorate leads to the formation of solid potassium chloride and diatomic oxygen gas. Write an equation for the reaction. (c) The decomposition of solid barium nitrate leads to the formation of solid barium oxide, diatomic nitrogen gas, and diatomic oxygen gas. Write an equation for the reaction. (d) Write separate equations for the reactions of the solid metals magnesium, aluminum, and iron with diatomic oxygen gas to yield the corresponding metal oxides. (Assume the iron oxide contains Fe3+ ions.)arrow_forward
- 3.121 If you have 21.1 g of iron(II) nitrate that is dissolved to give 1.54 L of solution, what is the molarity of the solution? What is the molarity of the nitrate ions?arrow_forwardThe present average concentration (mass percent) of magnesium ions in seawater is 0.13%. A chemistry textbook estimates that if 1.00 × 108 tons Mg were taken out of the sea each year, it would take one million years for the Mg concentration to drop to 0.12%. Do sufficient calculations to either verify or refute this statement. Assume that Earth is a sphere with a diameter of 8000 mi, 67% of which is covered by oceans to a depth of 1 mi, and that no Mg is washed back into the oceans at any time.arrow_forwardA student wants to prepare 1.00 L of a 1.00-M solution of NaOH (molar mass = 40.00 g/mol). If solid NaOH is available, how would the student prepare this solution? If 2.00 M NaOH is available, how would the student prepare the solution? To help ensure three significant figures in the NaOH molarity, to how many significant figures should the volumes and mass be determined?arrow_forward
- 3.109 Materials engineers often create new alloys in an effort to improve the properties of an existing material. ZnO based semiconductors show promise in applications like light-emitting diodes, but their performance can be enhanced by the addition of small amounts of cadmium. One material that has been studied can he represented by the formula Zn0.843Cd0.157O. (These materials are solid solutions, and so they can have variable compositions. The noninteger coefficients do not imply fractional atoms.) Express the composition of this alloy in terms of (a) at%, (b) mol%, and (c) wt%.arrow_forwardMany cereals are made with high moisture content so that the cereal can be formed into various shapes before it is dried. A cereal product containing 58% H2O by mass is produced at the rate of 1000. kg/h. What mass of water must be evaporated per hour if the final product contains only 20.% water?arrow_forwardBacterial digestion is an economical method of sewage treatment. The reaction is an intermediate step in the conversion of the nitrogen in organic compounds into nitrate ions. What mass of bacterial tissue is produced in a treatment plant for every 1.0 104 kg of wastewater containing 3.0% NH4+ ions by mass? Assume that 95% of the ammonium ions are consumed by the bacteria.arrow_forward
- 3.120 1f you have 32.6 g of sodium carbonate that is dissolved to give 2.10 L of solution, what is the molarity of the solution? What is the molarity of the sodium ions?arrow_forwardMany over-the-counter antacid tablets are now formulated using calcium carbonate as the active ingredient, which enables such tablets to also be used as dietary calcium supplements. As an antacid for gastric hyperacidity, calcium carbonate reacts by combining with hydrochloric acid found in the stomach, producing a solution of calcium chloride, converting the stomach acid to water, and releasing carbon dioxide gas (which the person suffering from stomach problems may feel as a “burp”). Write the unbalanced chemical equation for this process.arrow_forwardA 2.00-L bottle of a solution of concentrated HCl was purchased for the general chemistry laboratory. The solution contained 868.8 g of HCl. What is the molarity of the solution?arrow_forward
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