Determine the differences in the Δ rxn S under standard conditions for the two following reactions: H 2 ( g ) + 1 2 O 2 ( g ) → H 2 O ( l ) H 2 ( g ) + 1 2 O 2 ( g ) → H 2 O ( g ) and justify the difference.
Determine the differences in the Δ rxn S under standard conditions for the two following reactions: H 2 ( g ) + 1 2 O 2 ( g ) → H 2 O ( l ) H 2 ( g ) + 1 2 O 2 ( g ) → H 2 O ( g ) and justify the difference.
Solution Summary: The author explains that entropy is used to represent the randomness in a system.
Last Name, Firs
Statifically more chances to abstract one of these 6H
11. (10pts total) Consider the radical chlorination of 1,3-diethylcyclohexane depicted below. 4
• 6H total $ 4th total
21 total
4H total
ZH
2H
Statistical
H < 3°C-H werkst
-
product
bund abstraction here
leads to the mo favored
a) (6pts) How many unique mono-chlorinated products can be formed and what are the
structures for the thermodynamically and statistically favored products?
Proclict
6
Number of Unique
Mono-Chlorinated Products
f
Thermodynamically
Favored Product
Statistically
Favored Product
b) (4pts) Draw the arrow pushing mechanism for the FIRST propagation step (p-1) for the
formation of the thermodynamically favored product. Only draw the p-1 step. You do
not need to include lone pairs of electrons. No enthalpy calculation necessary
'H
H-Cl
Waterfox
2. (a) Many main group oxides form acidic solutions when added to water. For example solid
tetraphosphorous decaoxide reacts with water to produce phosphoric acid. Write a balanced
chemical equation for this reaction.
(b) Calcium phosphate reacts with silicon dioxide and carbon graphite at elevated temperatures
to produce white phosphorous (P4) as a gas along with calcium silicate (Silcate ion is SiO3²-)
and carbon monoxide. Write a balanced chemical equation for this reaction.
I find the solution way too brief and unsatisfactory as it does not clearly explain the solution provided in the problem.
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The Laws of Thermodynamics, Entropy, and Gibbs Free Energy; Author: Professor Dave Explains;https://www.youtube.com/watch?v=8N1BxHgsoOw;License: Standard YouTube License, CC-BY