Chemistry: An Atoms-Focused Approach
Chemistry: An Atoms-Focused Approach
14th Edition
ISBN: 9780393912340
Author: Thomas R. Gilbert, Rein V. Kirss, Natalie Foster
Publisher: W. W. Norton & Company
Question
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Chapter 3, Problem 3.41QA
Interpretation Introduction

To find:

a) which metal among potassium and sodium would emit electrons with the greater velocity.

b) Velocity of the ejected electrons.

Expert Solution & Answer
Check Mark

Answer to Problem 3.41QA

Solution:

a) Potassium metal would emit the electrons with greater velocity.

b) Velocity of the ejected electrons is 8.04 x 105 m/s.

Explanation of Solution

1) Concept:

We have to use the formula of work function relating kinetic energy. We have given wavelength of the radiation and also work functions of the metals. We have to first calculate the kinetic energy and then velocity of the ejected electrons.

ɸ=hv-KEelectrons

ɸ=hcλ-KEelectrons

KEelectrons=hcλ-ɸ

2) Formula: for the velocity of the ejected electrons is,

KEelectrons=12mv2

v=2KEelectronsm

Where, m is the mass of the electron.

3) Given:

i. Wavelength of the radiation = 300 nm = 3.00 x 10-7 m

ii. Work function of potassium = 3.68 x 10-19 J.

iii. Work function of sodium = 4.41 x 10-19 J.

iv. Mass of electron = 9.1 x 10-31 Kg.

4) Calculations:

Potassium:

KEelectrons=hcλ-ɸ

KEelectrons=(6.626×10-34 J.s)×(2.998×108 m/s)(3.00×10-7 m)-(3.68×10-19 J)

KEelectrons=6.626×10-19 J-(3.68×10-19 J)

KEelectrons=2.946×10-19 J

Now velocity of the ejected electrons,

v=2(2.946×10-19 J)(9.1×10-31 Kg)

v=8.04×105m/s

Sodium:

KEelectrons=hcλ-ɸ

KEelectrons=(6.626×10-34 J.s)×(2.998×108 m/s)(3.00×10-7 m)-(4.41×10-19 J)

KEelectrons=6.626×10-19 J-(4.41×10-19 J)

KEelectrons=2.216×10-19 J

Now velocity of the ejected electrons,

v=2(2.216×10-19 J)(9.1×10-31 Kg)

v=7.00×105m/s

Comparing the two velocities we can say, potassium will emit electrons with greater velocity – 8.04×105m/s

Conclusion:

The work function of potassium is less than the work function of sodium. This means the kinetic energy and therefore the velocity of the electrons emitted by potassium would be greater than those emitted by sodium.

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Chapter 3 Solutions

Chemistry: An Atoms-Focused Approach

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