Chemistry: An Atoms-Focused Approach
14th Edition
ISBN: 9780393912340
Author: Thomas R. Gilbert, Rein V. Kirss, Natalie Foster
Publisher: W. W. Norton & Company
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Question
Chapter 3, Problem 3.33QA
Interpretation Introduction
To find:
The energy of a photon of UV light with a specified wavelength
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Instructions: Complete the questions in the space provided. Show all your work
1. You are trying to determine the rate law expression for a reaction that you are completing at 25°C. You measure
the initial reaction rate and the starting concentrations of the reactions for 4 trials.
BrO³¯ (aq) + 5Br¯ (aq) + 6H* (aq) → 3Br₂ (l) + 3H2O (l)
Initial rate
Trial
[BrO3]
[H*]
[Br]
(mol/L)
(mol/L) | (mol/L)
(mol/L.s)
1
0.10
0.10
0.10
8.0
2
0.20
0.10
0.10
16
3
0.10
0.20
0.10
16
4
0.10
0.10
0.20
32
a.
Based on the above data what is the rate law expression?
b. Solve for the value of k (make sure to include proper units)
2. The proposed reaction mechanism is as follows:
i.
ii.
BrО¸¯ (aq) + H+ (aq) → HBrO3 (aq)
HBrO³ (aq) + H* (aq) → H₂BrO3* (aq)
iii.
H₂BrO³* (aq) + Br¯ (aq) → Br₂O₂ (aq) + H2O (l)
[Fast]
[Medium]
[Slow]
iv.
Br₂O₂ (aq) + 4H*(aq) + 4Br(aq) → 3Br₂ (l) + H2O (l)
[Fast]
Evaluate the validity of this proposed reaction. Justify your answer.
е.
Д
CH3
D*, D20
C.
NaOMe,
Br
Br
Chapter 3 Solutions
Chemistry: An Atoms-Focused Approach
Ch. 3 - Prob. 3.10VPCh. 3 - Prob. 3.11VPCh. 3 - Prob. 3.12VPCh. 3 - Prob. 3.13QACh. 3 - Prob. 3.14QACh. 3 - Prob. 3.15QACh. 3 - Prob. 3.16QACh. 3 - Prob. 3.17QACh. 3 - Prob. 3.18QACh. 3 - Prob. 3.19QA
Ch. 3 - Prob. 3.20QACh. 3 - Prob. 3.21QACh. 3 - Prob. 3.22QACh. 3 - Prob. 3.23QACh. 3 - Prob. 3.24QACh. 3 - Prob. 3.25QACh. 3 - Prob. 3.26QACh. 3 - Prob. 3.27QACh. 3 - Prob. 3.28QACh. 3 - Prob. 3.29QACh. 3 - Prob. 3.30QACh. 3 - Prob. 3.31QACh. 3 - Prob. 3.32QACh. 3 - Prob. 3.33QACh. 3 - Prob. 3.34QACh. 3 - Prob. 3.35QACh. 3 - Prob. 3.36QACh. 3 - Prob. 3.37QACh. 3 - Prob. 3.38QACh. 3 - Prob. 3.39QACh. 3 - Prob. 3.40QACh. 3 - Prob. 3.41QACh. 3 - Prob. 3.42QACh. 3 - Prob. 3.43QACh. 3 - Prob. 3.44QACh. 3 - Prob. 3.45QACh. 3 - Prob. 3.46QACh. 3 - Prob. 3.47QACh. 3 - Prob. 3.48QACh. 3 - Prob. 3.49QACh. 3 - Prob. 3.50QACh. 3 - Prob. 3.51QACh. 3 - Prob. 3.52QACh. 3 - Prob. 3.53QACh. 3 - Prob. 3.54QACh. 3 - Prob. 3.55QACh. 3 - Prob. 3.56QACh. 3 - Prob. 3.58QACh. 3 - Prob. 3.59QACh. 3 - Prob. 3.60QACh. 3 - Prob. 3.61QACh. 3 - Prob. 3.62QACh. 3 - Prob. 3.63QACh. 3 - Prob. 3.64QACh. 3 - Prob. 3.65QACh. 3 - Prob. 3.66QACh. 3 - Prob. 3.67QACh. 3 - Prob. 3.68QACh. 3 - Prob. 3.69QACh. 3 - Prob. 3.70QACh. 3 - Prob. 3.71QACh. 3 - Prob. 3.72QACh. 3 - Prob. 3.73QACh. 3 - Prob. 3.74QACh. 3 - Prob. 3.75QACh. 3 - Prob. 3.76QACh. 3 - Prob. 3.77QACh. 3 - Prob. 3.78QACh. 3 - Prob. 3.79QACh. 3 - Prob. 3.80QACh. 3 - Prob. 3.81QACh. 3 - Prob. 3.82QACh. 3 - Prob. 3.83QACh. 3 - Prob. 3.84QACh. 3 - Prob. 3.85QACh. 3 - Prob. 3.86QACh. 3 - Prob. 3.87QACh. 3 - Prob. 3.88QACh. 3 - Prob. 3.89QACh. 3 - Prob. 3.90QACh. 3 - Prob. 3.91QACh. 3 - Prob. 3.92QACh. 3 - Prob. 3.93QACh. 3 - Prob. 3.94QACh. 3 - Prob. 3.95QACh. 3 - Prob. 3.96QACh. 3 - Prob. 3.97QACh. 3 - Prob. 3.98QACh. 3 - Prob. 3.99QACh. 3 - Prob. 3.100QACh. 3 - Prob. 3.101QACh. 3 - Prob. 3.102QACh. 3 - Prob. 3.103QACh. 3 - Prob. 3.104QACh. 3 - Prob. 3.105QACh. 3 - Prob. 3.106QACh. 3 - Prob. 3.107QACh. 3 - Prob. 3.108QACh. 3 - Prob. 3.109QACh. 3 - Prob. 3.110QACh. 3 - Prob. 3.111QACh. 3 - Prob. 3.112QACh. 3 - Prob. 3.113QACh. 3 - Prob. 3.114QACh. 3 - Prob. 3.115QACh. 3 - Prob. 3.116QACh. 3 - Prob. 3.117QACh. 3 - Prob. 3.118QACh. 3 - Prob. 3.119QACh. 3 - Prob. 3.120QACh. 3 - Prob. 3.121QACh. 3 - Prob. 3.122QACh. 3 - Prob. 3.123QACh. 3 - Prob. 3.124QACh. 3 - Prob. 3.125QACh. 3 - Prob. 3.126QACh. 3 - Prob. 3.127QACh. 3 - Prob. 3.128QACh. 3 - Prob. 3.129QACh. 3 - Prob. 3.130QACh. 3 - Prob. 3.131QACh. 3 - Prob. 3.132QA
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