Optical activity of the given compound has to be checked when there is restricted rotation along the central carbon-carbon bond and also optical rotation at elevated temperatures when the rotation becomes less restricted has to be explained. Concept Introduction: Atropisomers: Stereoisomers that occur when rotation around a central carbon-carbon bond is sufficient to allow isolation of individual conformers are called as an atropisomers.

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Answer 1

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Chapter 3, Problem 3.35P

Interpretation Introduction

Interpretation:

Optical activity of the given compound has to be checked when there is restricted rotation along the central carbon-carbon bond and also optical rotation at elevated temperatures when the rotation becomes less restricted has to be explained.

Concept Introduction:

Atropisomers:

Stereoisomers that occur when rotation around a central carbon-carbon bond is sufficient to allow isolation of individual conformers are called as an atropisomers.

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Will the following compound show any optical activity if there is restricted rotation along the central C-C bond? What will happen to the optical activity at elevated temperatures as the rotation becomes less restricted? CH3 CI H Cl CH3

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How can we decide whether an observed rotation of a solution of an optically active compound is +170° and not actually -190°?

Answer 2

Question

Chapter 3, Problem 3.35P

Interpretation Introduction

Interpretation:

Optical activity of the given compound has to be checked when there is restricted rotation along the central carbon-carbon bond and also optical rotation at elevated temperatures when the rotation becomes less restricted has to be explained.

Concept Introduction:

Atropisomers:

Stereoisomers that occur when rotation around a central carbon-carbon bond is sufficient to allow isolation of individual conformers are called as an atropisomers.

Expert Solution & Answer

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Answer 3

Question

Chapter 3, Problem 3.35P

Interpretation Introduction

Interpretation:

Optical activity of the given compound has to be checked when there is restricted rotation along the central carbon-carbon bond and also optical rotation at elevated temperatures when the rotation becomes less restricted has to be explained.

Concept Introduction:

Atropisomers:

Stereoisomers that occur when rotation around a central carbon-carbon bond is sufficient to allow isolation of individual conformers are called as an atropisomers.

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Answer 4

Question

Chapter 3, Problem 3.35P

Interpretation Introduction

Interpretation:

Optical activity of the given compound has to be checked when there is restricted rotation along the central carbon-carbon bond and also optical rotation at elevated temperatures when the rotation becomes less restricted has to be explained.

Concept Introduction:

Atropisomers:

Stereoisomers that occur when rotation around a central carbon-carbon bond is sufficient to allow isolation of individual conformers are called as an atropisomers.

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Answer 5

Chapter 3, Problem 3.35P

Interpretation Introduction

Interpretation:

Optical activity of the given compound has to be checked when there is restricted rotation along the central carbon-carbon bond and also optical rotation at elevated temperatures when the rotation becomes less restricted has to be explained.

Concept Introduction:

Atropisomers:

Stereoisomers that occur when rotation around a central carbon-carbon bond is sufficient to allow isolation of individual conformers are called as an atropisomers.

Answer 6

Chapter 3, Problem 3.35P

Interpretation Introduction

Interpretation:

Optical activity of the given compound has to be checked when there is restricted rotation along the central carbon-carbon bond and also optical rotation at elevated temperatures when the rotation becomes less restricted has to be explained.

Concept Introduction:

Atropisomers:

Stereoisomers that occur when rotation around a central carbon-carbon bond is sufficient to allow isolation of individual conformers are called as an atropisomers.

Answer 7

Chapter 3, Problem 3.35P

Interpretation Introduction

Interpretation:

Optical activity of the given compound has to be checked when there is restricted rotation along the central carbon-carbon bond and also optical rotation at elevated temperatures when the rotation becomes less restricted has to be explained.

Concept Introduction:

Atropisomers:

Stereoisomers that occur when rotation around a central carbon-carbon bond is sufficient to allow isolation of individual conformers are called as an atropisomers.

Answer 8

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Answer 9

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Answer 10

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Answer 11

Ch. 3.2 - Prob. 3.1P Ch. 3.3 - Assign priorities to the groups in each set. (a)...Ch. 3.3 - Prob. 3.3P Ch. 3.4 - Following are stereorepresentations for the four...Ch. 3.4 - Prob. 3.5P Ch. 3.4 - Prob. 3.6P Ch. 3.5 - How many stereoisomers exist for...Ch. 3.5 - How many stereoisomers exist for...Ch. 3.7 - Prob. 3.9P Ch. 3.7 - Prob. 3.10P

Solution Summary: The author explains that Optical activity of a compound has to be checked when there is restricted rotation along the central carbon-carbon bond and optical rotation at elevated temperatures when the rotation becomes less restricted.

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Chapter 3 Solutions