Quantitative Chemical Analysis
Quantitative Chemical Analysis
9th Edition
ISBN: 9781464135385
Author: Daniel C. Harris
Publisher: W. H. Freeman
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Chapter 3, Problem 3.14P

(a)

Interpretation Introduction

Interpretation:

The given number has to be rewritten in the form of number (±absolute uncertainty)

Concept Introduction:

Uncertainty:

Uncertainty means state of not certain in predicting a value.  In a measured value, the last digit will have associated uncertainty. Uncertainty has two values, absolute uncertainty and relative uncertainty.

Absolute uncertainty:

Expressed the marginal value associated with a measurement

Relative uncertainty:

Compares the size of absolute uncertainty with the size of its associated measurement

Relative uncertainty = absolute uncertaintymagnitude of measurement

Percent relative uncertainty:

Percent relative uncertainty = 100 × relative uncertainty

To Rewrite: The given number in the form of number (±absolute uncertainty)

(b)

Interpretation Introduction

Interpretation:

The given number has to be rewritten in the form of number (±percent relative uncertainty)

Concept Introduction:

Uncertainty:

Uncertainty means state of not certain in predicting a value.  In a measured value, the last digit will have associated uncertainty. Uncertainty has two values, absolute uncertainty and relative uncertainty.

Absolute uncertainty:

Expressed the marginal value associated with a measurement

Relative uncertainty:

Compares the size of absolute uncertainty with the size of its associated measurement

Relative uncertainty = absolute uncertaintymagnitude of measurement

Percent relative uncertainty:

Percent relative uncertainty = 100 × relative uncertainty

To Rewrite: The given number in the form of number (±percent relative uncertainty)

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Done 11:14 ⚫ worksheets.beyondlabz.com 5 (a). Using the peak information you listed in the tables for both structures, assign each peak to that portion of the structure that produces the peak in the NMR spectrum. Draw this diagram on your own sheet of paper and attach the sketch of your drawing to this question. Question 6 5 (b). Using the peak information you listed in the tables for both structures, assign each peak to that portion of the structure that produces the peak in the NMR spectrum. Draw this diagram on your own sheet of paper and attach the sketch of your drawing to this question. Question 7 6. Are there any differences between the spectra you obtained in Beyond Labz and the predicted spectra? If so, what were the differences? <
2. Predict the NMR spectra for each of these two compounds by listing, in the NMR tables below, the chemical shift, the splitting, and the number of hydrogens associated with each predicted peak. Sort the peaks from largest chemical shift to lowest. **Not all slots must be filled** Peak Chemical Shift (d) 5.7 1 Multiplicity multiplate .......... 5.04 double of doublet 2 4.98 double of doublet 3 4.05 doublet of quartet 4 5 LO 3.80 quartet 1.3 doublet 6 Peak Chemical Shift (d) Multiplicity
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