Exploring Chemical Analysis
Exploring Chemical Analysis
5th Edition
ISBN: 9781429275033
Author: Daniel C. Harris
Publisher: Macmillan Higher Education
Question
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Chapter 3, Problem 3.14P

(a)

Interpretation Introduction

Interpretation:

The absolute and percent relative uncertainty with a reasonable number of significant figures has to be found out for [3.4(±0.2)+2.6(±0.1)]=?

Concept Introduction:

Uncertainty:

Uncertainty means state of not certain in predicting a value.  In a measured value, the last digit will have associated uncertainty. Uncertainty has two values, absolute uncertainty and relative uncertainty.

Absolute uncertainty:

  Expressed the marginal value associated with a measurement

Relative uncertainty:

Compares the size of absolute uncertainty with the size of its associated measurement

  Relative uncertainty = absolute uncertaintymagnitude of measurement

For a set measurements having uncertainty values as e1,e2 and e3, the uncertainty (e4) in addition and subtraction can be calculated as follows,

  e4=e12+e22+e32

Percent relative uncertainty:

  Percent relative uncertainty = 100 × relative uncertainty

(b)

Interpretation Introduction

Interpretation:

The absolute and percent relative uncertainty with a reasonable number of significant figures has to be found out for [3.4(±0.2)]÷2.6(±0.1)=?

Concept Introduction:

Refer part (a).

(c)

Interpretation Introduction

Interpretation:

The absolute and percent relative uncertainty with a reasonable number of significant figures has to be found out for [3.4(±0.2)×108]÷[2.6(±0.1)×103]=?.

Concept Introduction:

Refer part (a).

(d)

Interpretation Introduction

Interpretation:

The absolute and percent relative uncertainty with a reasonable number of significant figures has to be found out for [3.4(±0.2)2.6(±0.1)]×3.4(±0.2)=?.

Concept Introduction: Refer part (a).

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Please answer the question and provide a detailed drawing of the structure. If there will not be a new C – C bond, then the box under the drawing area will be checked.  Will the following reaction make a molecule with a new C – C bond as its major product:  Draw the major organic product or products, if the reaction will work. Be sure you use wedge and dash bonds if necessary, for example to distinguish between major products with different stereochemistry.
Please do not use AI.  AI cannot "see" the molecules properly, and it therefore gives the wrong answer while giving incorrect descriptions of the visual images we're looking at.  All of these compounds would be produced (I think).  In my book, I don't see any rules about yield in this case, like explaining that one product would be present in less yield for this reason or that reason.  Please explain why some of these produce less yield than others.
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