Physical Chemistry
Physical Chemistry
3rd Edition
ISBN: 9780321812001
Author: ENGEL, Thomas/ Reid
Publisher: Pearson College Div
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Chapter 3, Problem 3.13NP
Interpretation Introduction

Interpretation:

From equation Cp= Cv+ TV(β2/K)  , the relation between Cp − Cv for an ideal gas needs to be identified.

Concept Introduction :

The relationship between Cpand Cv with β and K

is represented as follows:

  Cp= Cv+ TV(β2/κ) 

Here, Cpis the specific heat capacity at constant pressure, Cv is the specific heat capacity at constant volume, T is temperature, V is volume, β is the coefficient of volumetric thermal expansion at constant pressure.

and κ is isothermal compressibility.

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