GENERAL,ORGANIC+BIOCHEM (LOOSELEAF)
10th Edition
ISBN: 9781264035090
Author: Denniston
Publisher: MCG
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Chapter 3, Problem 3.103QP
Interpretation Introduction
Interpretation:
The relationship between polarity of a bond and molecule has to be determined.
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Students have asked these similar questions
Kumada Coupling:
1. m-Diisobutylbenzene below could hypothetically be synthesized by Friedel-Crafts reaction. Write out the reaction with a
mechanism and give two reasons why you would NOT get the desired product.
Draw the reaction (NOT a mechanism) for a Kumada coupling to produce the molecule above from m-dichlorobenzene.
Calculate the theoretical yield for the reaction in question 2 using 1.5 g of p-dichlorobenzene and 3.0 mL isobutyl bromide.
What signals appeared/disappeared/shifted that indicate that you have your intended product and not starting material? What
other impurities are present in your product and how do you know?
Wintergreen from Aspirin:
1. In isolating the salicylic acid, why is it important to press out as much of the water as possible?
2. Write the mechanism of the esterification reaction you did.
3.
What characteristic absorption band changes would you expect in the IR spectrum on going from aspirin to salicyclic acid and
then to methyl salicylate as you did in the experiment today? Give approximate wavenumbers associated with each functional
group change.
What signals appeared/disappeared/shifted that indicate that you have your intended product and not starting material? What
other impurities are present in your product and how do you know?
Synthesis of ZybanⓇ:
1. Write a mechanism for the bromination of m-chloropropiophenone.
Br₂
CH2Cl2
Cl
Br
2. Give the expected m/z (to a round number) for the molecular ion from the product above (including isotopic peaks).
3. What signals appeared/disappeared/shifted that indicate that you have your intended product and not starting material? What
other impurities are present in your product and how do you know?
Chapter 3 Solutions
GENERAL,ORGANIC+BIOCHEM (LOOSELEAF)
Ch. 3.1 - Draw the Lewis symbol for oxygen, and indicate the...Ch. 3.1 - Prob. 3.2PPCh. 3.1 - Prob. 3.3PPCh. 3.2 - Prob. 3.4PPCh. 3.2 - Prob. 3.5PPCh. 3.2 - Prob. 3.1QCh. 3.2 - Prob. 3.2QCh. 3.2 - Prob. 3.6PPCh. 3.2 - Prob. 3.7PPCh. 3.2 - Prob. 3.8PP
Ch. 3.2 - Prob. 3.9PPCh. 3.4 - Prob. 3.10PPCh. 3.4 - Prob. 3.11PPCh. 3.4 - Prob. 3.12PPCh. 3.4 - Prob. 3.13PPCh. 3.4 - Prob. 3.3QCh. 3.4 - Prob. 3.4QCh. 3.4 - Prob. 3.14PPCh. 3.4 - Prob. 3.5QCh. 3.4 - Prob. 3.6QCh. 3.4 - Prob. 3.16PPCh. 3.4 - Prob. 3.7QCh. 3.4 - Prob. 3.8QCh. 3.4 - Prob. 3.9QCh. 3 - Prob. 3.13QPCh. 3 - Draw the appropriate Lewis symbol for each of the...Ch. 3 - Draw the appropriate Lewis symbol for each of the...Ch. 3 - Prob. 3.16QPCh. 3 - Describe the differences between covalent bonding...Ch. 3 - Describe the difference between nonpolar covalent...Ch. 3 - What is the periodic trend of electronegativity?
Ch. 3 - What role does electronegativity play in...Ch. 3 - Use electronegativity values to classify the bonds...Ch. 3 - Use electronegativity values to classify the bonds...Ch. 3 - When there is a reaction between each of these...Ch. 3 - Prob. 3.24QPCh. 3 - Explain, using Lewis symbols and the octet rule,...Ch. 3 - Explain, using Lewis symbols and the octet rule,...Ch. 3 - Prob. 3.27QPCh. 3 - Prob. 3.28QPCh. 3 - Name each of the following ions:
Na+
Cu+
Mg2+
Ch. 3 - Name each of the following ions:
Cu2+
Fe2+
Fe3+
Ch. 3 - Name each of the following ions:
HCO3–
H3O+
CO32−
Ch. 3 - Prob. 3.32QPCh. 3 - Prob. 3.33QPCh. 3 - Write the formula for each of the following...Ch. 3 - Prob. 3.35QPCh. 3 - Prob. 3.36QPCh. 3 - Prob. 3.37QPCh. 3 - Predict the formula of a compound formed...Ch. 3 - Prob. 3.39QPCh. 3 - Prob. 3.40QPCh. 3 - Prob. 3.41QPCh. 3 - Write the correct formula for each of the...Ch. 3 - Prob. 3.43QPCh. 3 - Write the correct formula for each of the...Ch. 3 - Prob. 3.45QPCh. 3 - Write the correct formula for each of the...Ch. 3 - Write a suitable formula for:
sodium...Ch. 3 - Write a suitable formula for:
aluminum...Ch. 3 - Prob. 3.49QPCh. 3 - Prob. 3.50QPCh. 3 - Prob. 3.51QPCh. 3 - Prob. 3.52QPCh. 3 - Write a suitable formula for:
silicon...Ch. 3 - Prob. 3.54QPCh. 3 - Contrast ionic and covalent compounds with respect...Ch. 3 - Prob. 3.56QPCh. 3 - Prob. 3.57QPCh. 3 - Prob. 3.58QPCh. 3 - Prob. 3.59QPCh. 3 - Prob. 3.60QPCh. 3 - Prob. 3.61QPCh. 3 - Prob. 3.62QPCh. 3 - Prob. 3.63QPCh. 3 - Prob. 3.64QPCh. 3 - Prob. 3.65QPCh. 3 - Prob. 3.66QPCh. 3 - How is the positive charge of a polyatomic cation...Ch. 3 - Prob. 3.68QPCh. 3 - Prob. 3.69QPCh. 3 - Prob. 3.70QPCh. 3 - Prob. 3.71QPCh. 3 - Prob. 3.72QPCh. 3 - Prob. 3.73QPCh. 3 - Prob. 3.74QPCh. 3 - Prob. 3.75QPCh. 3 - Prob. 3.76QPCh. 3 - Prob. 3.77QPCh. 3 - Prob. 3.78QPCh. 3 - Prob. 3.79QPCh. 3 - Prob. 3.80QPCh. 3 - Prob. 3.81QPCh. 3 - Prob. 3.82QPCh. 3 - Prob. 3.83QPCh. 3 - Prob. 3.84QPCh. 3 - Prob. 3.85QPCh. 3 - Prob. 3.86QPCh. 3 - Prob. 3.87QPCh. 3 - Prob. 3.88QPCh. 3 - Prob. 3.89QPCh. 3 - Prob. 3.90QPCh. 3 - Prob. 3.91QPCh. 3 - Prob. 3.93QPCh. 3 - Prob. 3.94QPCh. 3 - Prob. 3.95QPCh. 3 - Prob. 3.96QPCh. 3 - Prob. 3.97QPCh. 3 - Prob. 3.98QPCh. 3 - Prob. 3.99QPCh. 3 - Prob. 3.100QPCh. 3 - Prob. 3.101QPCh. 3 - Prob. 3.102QPCh. 3 - Prob. 3.103QPCh. 3 - Prob. 3.104QPCh. 3 - Prob. 3.107QPCh. 3 - Prob. 3.108QPCh. 3 - Prob. 3.109QPCh. 3 - Prob. 3.110QPCh. 3 - Prob. 3.112QPCh. 3 - Prob. 1MCPCh. 3 - Prob. 2MCPCh. 3 - Prob. 3MCPCh. 3 - Prob. 4MCPCh. 3 - Prob. 5MCPCh. 3 - Prob. 6MCPCh. 3 - Prob. 7MCPCh. 3 - Prob. 8MCPCh. 3 - Prob. 9MCPCh. 3 - Prob. 10MCP
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