Chemistry Principles And Practice
3rd Edition
ISBN: 9781305295803
Author: David Reger; Scott Ball; Daniel Goode
Publisher: Cengage Learning
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Chapter 3, Problem 3.102QE
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Using a cell of known pathlength b = 1.25115 x 10-3 cm, a water absorption spectrum was measured. The band at 1645 cm-1, assigned to the O-H bending, showed an absorbance, A, of 1.40.
a) Assuming that water density is 1.00 g/mL, calculate the water molar concentration c (hint: M= mole/L)
b) Calculate the molar absorptivity, a, of the 1645 cm-1 band
c) The transmitted light, I, can be written as I= Ioexp(-xb), where x is the absorption coefficient (sometimes designated as alpha), Io is the input light, and b is the cell pathlength. Prove that x= (ln10)*x*c. (Please provide a full derivation of the equation for x from the equation for I).
d) Calculate x for the 1645 cm-1 band
I need help with the follloaing
For a CARS experiment on a Raman band 918 cm-1, if omega1= 1280 nm, calculate the omega2 in wavelength (nm) and the CARS output in wavelength (nm).
Chapter 3 Solutions
Chemistry Principles And Practice
Ch. 3 - Prob. 3.1QECh. 3 - Prob. 3.2QECh. 3 - Using solid circles for H atoms and open circles...Ch. 3 - Prob. 3.4QECh. 3 - Prob. 3.5QECh. 3 - How many objects are in 1 mol? What is the common...Ch. 3 - Prob. 3.7QECh. 3 - Prob. 3.8QECh. 3 - Prob. 3.11QECh. 3 - Describe an experiment that would enable someone...
Ch. 3 - Only the empirical formula can be calculated from...Ch. 3 - Prob. 3.14QECh. 3 - Prob. 3.15QECh. 3 - Prob. 3.16QECh. 3 - Prob. 3.17QECh. 3 - Prob. 3.18QECh. 3 - Prob. 3.19QECh. 3 - A mixture of sulfur dioxide and oxygen gas reacts...Ch. 3 - Prob. 3.21QECh. 3 - Prob. 3.22QECh. 3 - Prob. 3.23QECh. 3 - Prob. 3.24QECh. 3 - Prob. 3.25QECh. 3 - Prob. 3.26QECh. 3 - Prob. 3.27QECh. 3 - Prob. 3.28QECh. 3 - Prob. 3.29QECh. 3 - Prob. 3.30QECh. 3 - Prob. 3.31QECh. 3 - Prob. 3.32QECh. 3 - Prob. 3.33QECh. 3 - Prob. 3.34QECh. 3 - Prob. 3.35QECh. 3 - Prob. 3.36QECh. 3 - Acetone, (CH3)2CO, is an important industrial...Ch. 3 - Prob. 3.38QECh. 3 - Prob. 3.39QECh. 3 - Prob. 3.40QECh. 3 - Prob. 3.41QECh. 3 - Prob. 3.42QECh. 3 - Prob. 3.43QECh. 3 - Prob. 3.44QECh. 3 - Prob. 3.45QECh. 3 - Prob. 3.46QECh. 3 - Prob. 3.47QECh. 3 - Prob. 3.48QECh. 3 -
One of the ways to remove nitrogen monoxide gas,...Ch. 3 - Prob. 3.50QECh. 3 - Prob. 3.51QECh. 3 - Prob. 3.52QECh. 3 - Prob. 3.53QECh. 3 - Prob. 3.54QECh. 3 - Prob. 3.55QECh. 3 - Prob. 3.56QECh. 3 - Prob. 3.57QECh. 3 - Prob. 3.58QECh. 3 - Prob. 3.59QECh. 3 - Prob. 3.60QECh. 3 - Prob. 3.61QECh. 3 - Prob. 3.62QECh. 3 - Prob. 3.63QECh. 3 - Prob. 3.64QECh. 3 - Prob. 3.65QECh. 3 - Prob. 3.66QECh. 3 - Prob. 3.67QECh. 3 - Prob. 3.68QECh. 3 - (a) Calculate the mass, in grams, of 3.50 mol NO2....Ch. 3 - Prob. 3.70QECh. 3 - Prob. 3.71QECh. 3 - Prob. 3.72QECh. 3 - Prob. 3.73QECh. 3 - Nickel tetracarbonyl, Ni(CO)4, is a volatile...Ch. 3 - Prob. 3.75QECh. 3 - Prob. 3.76QECh. 3 - Prob. 3.77QECh. 3 - Prob. 3.78QECh. 3 - Prob. 3.79QECh. 3 - Prob. 3.80QECh. 3 - Prob. 3.81QECh. 3 - Prob. 3.82QECh. 3 - Prob. 3.83QECh. 3 - Prob. 3.84QECh. 3 - A chemist prepared a compound that she thought had...Ch. 3 - Prob. 3.86QECh. 3 - Prob. 3.87QECh. 3 - Prob. 3.88QECh. 3 - Prob. 3.89QECh. 3 - Prob. 3.90QECh. 3 - Prob. 3.91QECh. 3 - Prob. 3.92QECh. 3 - Prob. 3.93QECh. 3 - Prob. 3.94QECh. 3 - Prob. 3.95QECh. 3 - Prob. 3.96QECh. 3 - Prob. 3.97QECh. 3 - Prob. 3.98QECh. 3 - Prob. 3.99QECh. 3 - Prob. 3.100QECh. 3 - Prob. 3.101QECh. 3 - Prob. 3.102QECh. 3 - Prob. 3.103QECh. 3 - Prob. 3.104QECh. 3 - Prob. 3.105QECh. 3 - Prob. 3.106QECh. 3 - Prob. 3.107QECh. 3 - Prob. 3.108QECh. 3 - Prob. 3.109QECh. 3 - Prob. 3.110QECh. 3 - Prob. 3.111QECh. 3 - Prob. 3.112QECh. 3 - Prob. 3.113QECh. 3 - Prob. 3.114QECh. 3 - A compound contains 62.0% carbon, 10.4% hydrogen,...Ch. 3 - Mandelic acid is an organic acid composed of...Ch. 3 - Acetic acid gives vinegar its sour taste. Analysis...Ch. 3 - Prob. 3.118QECh. 3 - Prob. 3.119QECh. 3 - Prob. 3.120QECh. 3 - Prob. 3.121QECh. 3 - Prob. 3.122QECh. 3 - Aluminum metal reacts with sulfuric acid, H2SO4,...Ch. 3 - Prob. 3.124QECh. 3 - Lithium metal reacts with O2 to form lithium...Ch. 3 - Prob. 3.126QECh. 3 - A mixture of hydrogen and nitrogen gas reacts as...Ch. 3 - Prob. 3.128QECh. 3 - Prob. 3.129QECh. 3 - Prob. 3.130QECh. 3 - Prob. 3.131QECh. 3 - Prob. 3.132QECh. 3 - Prob. 3.133QECh. 3 - A reaction of 43.1 g CS2 with excess Cl2 yields...Ch. 3 - The reaction of 9.66 g O2 with 9.33 g NO produces...Ch. 3 - Prob. 3.136QECh. 3 - The combustion of 33.5 g C3H6 with 127 g O2 yields...Ch. 3 - Prob. 3.138QECh. 3 - Prob. 3.139QECh. 3 - When heated, potassium chlorate, KClO3, melts and...Ch. 3 - Prob. 3.141QECh. 3 - Prob. 3.142QECh. 3 - Prob. 3.143QECh. 3 - Prob. 3.144QECh. 3 - Prob. 3.145QECh. 3 - Prob. 3.146QECh. 3 - Prob. 3.147QECh. 3 - Prob. 3.149QECh. 3 - Prob. 3.150QECh. 3 - Prob. 3.151QECh. 3 - Prob. 3.152QECh. 3 - The compound dinitrogen monoxide, N2O, is a...Ch. 3 - Prob. 3.154QECh. 3 - Prob. 3.155QECh. 3 - Prob. 3.156QECh. 3 - Prob. 3.157QECh. 3 - Prob. 3.159QECh. 3 - Prob. 3.160QECh. 3 - The reaction of equal molar amounts of benzene,...Ch. 3 - Although copper does not usually react with acids,...
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- Using a cell of known pathlength b = 1.25115 x 10-3 cm, a water absorption spectrum was measured. The band at 1645 cm-1, assigned to the O-H bending, showed an absorbance, A, of 1.40. a) Assuming that water density is 1.00 g/mL, calculate the water molar concentration c (hint: M= mole/L) b) Calculate the molar absorptivity, a, of the 1645 cm-1 band c) The transmitted light, I, can be written as I= Ioexp(-xb), where x is the absorption coefficient (sometimes designated as alpha), Io is the input light, and b is the cell pathlength. Prove that x= (ln10)*x*c d) Calculate x for the 1645 cm-1 bandarrow_forwardConvert 1.38 eV into wavelength (nm) and wavenumber (cm-1) (c = 2.998 x 108 m/s; h = 6.626 x 10-34 J*s).arrow_forwardCan you help me understand the CBC method on metal bridging by looking at this problem?arrow_forward
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