EBK PUSHING ELECTRONS
EBK PUSHING ELECTRONS
4th Edition
ISBN: 9781285633237
Author: Weeks
Publisher: CENGAGE LEARNING - CONSIGNMENT
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Chapter 3, Problem 2EQ
Interpretation Introduction

Interpretation:

The leaving group in the given molecule is to be determined in order identify the positively charged and negatively charged fragments produced during mechanism.

Concept Introduction:

Heterolytic cleavage of sigma bond occurs under a variety of conditions. The mechanism of bond cleavage is as shown below,

EBK PUSHING ELECTRONS, Chapter 3, Problem 2EQ

The arrow in the above mechanism indicates that the sigma electrons form A-B bond are leaving A and becoming the exclusive property of B. Since the fragment A is formally losing one electron, it must become positively charged and B must become negatively charged since it gains an electron.

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