The class of hydrocarbons to which the reactant in the given reaction belong is to be identified and the IUPAC name of the reactant molecule is to be written, the carbon that is oxidized in the formation of each product is to be identified by IUPAC locant and the relation between the alcohols in the product is to be determined. Concept introduction: The bicyclic alkanes in which one atom is common in the two hydrocarbon rings are called spiro compounds. While determining the locants for the given alakne, the direction is chosen in such a way that the lower locant is given the first point of difference. The substituents are then listed in alphabetical order, and the locants and substituents are written first in the name of the alkane. The isomers that have the same molecular formula but differ in the way the different atoms are connected in their structure are constitutional isomers.

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Chapter 3, Problem 24P

Interpretation Introduction

Interpretation:

The class of hydrocarbons to which the reactant in the given reaction belong is to be identified and the IUPAC name of the reactant molecule is to be written, the carbon that is oxidized in the formation of each product is to be identified by IUPAC locant and the relation between the alcohols in the product is to be determined.

Concept introduction:

The bicyclic alkanes in which one atom is common in the two hydrocarbon rings are called spiro compounds.

While determining the locants for the given alakne, the direction is chosen in such a way that the lower locant is given the first point of difference. The substituents are then listed in alphabetical order, and the locants and substituents are written first in the name of the alkane.

The isomers that have the same molecular formula but differ in the way the different atoms are connected in their structure are constitutional isomers.

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Interpreting NMR spectra is a skill that often requires some amount of practice, which, in turn, necessitates access to a collection of NMR spectra. Beyond Labz Organic Synthesis and Organic Qualitative Analysis have spectral libraries containing over 700 1H NMR spectra. In this assignment, you will take advantage of this by first predicting the NMR spectra for two closely related compounds and then checking your predictions by looking up the actual spectra in the spectra library. After completing this assignment, you may wish to select other compounds for additional practice. 1. Write the IUPAC names for the following two structures: Question 2 Question 3 2. Predict the NMR spectra for each of these two compounds by listing, in the NMR tables below, the chemical shift, the splitting, and the number of hydrogens associated with each predicted peak. Sort the peaks from largest chemical shift to lowest. **Not all slots must be filled**

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