CHEMISTRY IN FOCUS (LL)-TEXT
7th Edition
ISBN: 9781337399845
Author: Tro
Publisher: CENGAGE L
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Chapter 3, Problem 1E
Why is it important to understand atoms?
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Part VII. The H-NMR of a compound with molecular formula C5 H 10 O2 is given below.
Find the following:
(a) The no. of protons corresponding to each signal in the spectra
(6) Give the structure of the compound and assign the signals to each
proton in the compound.
a
70.2
Integration Values
C5H10O2
b
47.7
C
46.5
d
69.5
3.6 3.5
3.4 3.3 3.2 3.1 3.0
2.9 2.8
2.7
2.6 2.5
2.4 2.3 2.2 2.1 2.0
Chemical Shift (ppm)
1.9
1.8
1.7 1.6
1.5
1.4 1.3 1.2
1.1 1.0
0.9 0.8
Part 111. 1 H-NMR spectrum of a compound with integration values in red is given below.
Answer the following:
(a) write the signals in the 'H-NMR spectrum to the corresponding protons on the structure
of the molecule below.
(b) Identify the theoretical multiplicities for each proton in the compound. Also give the possible.
complex splitting patterns assuming J values are not similar.
там
Br
22
2
3
6
4 7.2 7.0 6.8 6.6 6.4 6.2 6.0 5.8 5.6 5.4 5.2 5.0 4.8 4.6 4.4 4.2 4.0 3.8 3.6 3.4 3.2 3.0 2.8 2.6 2.4 2.2 2.0 1.8 1.6 1.4 1.2 1.0 0.8 0
Chemical Shift (ppm)
ra.
Br
2
3
6
6
2.5
2.4
2.3
2.2
2.1
2.0
1.9
1.8
1.7
1.6
1.5
1.4
1.3
1.2
1.1
1.0
0.9
0.8
Chemical Shift (ppm)
2
2
Br
7.3
7.2
7.1
7.0 6.9
6.7 6.6 6.5
6.4
6.3
6.2
6.1
6.0
Chemical Shift (ppm)
5.9
5.8 5.7
5.5 5.4 5.3 5.2
5.0 4.9
1600°
1538°C
1493°C
In the diagram, the letter L indicates
that it is a liquid. Indicate its
components in the upper region
where only L is indicated.
The
iron-iron carbide phase
diagram.
Temperature (°C)
1400
8
1394°C
y+L
1200
2.14
y, Austenite
10000
912°C
800a
0.76
0.022
600
400
(Fe)
a, Ferrite
Composition (at% C)
15
1147°C
a + Fe3C
2
3
Composition (wt% C)
L
2500
4.30
2000
y + Fe3C
727°C
1500
Cementite (Fe3C)
1000
4
5
6
6.70
Temperature (°F)
Chapter 3 Solutions
CHEMISTRY IN FOCUS (LL)-TEXT
Ch. 3 - Determining the Number of Protons and Electrons in...Ch. 3 - Prob. 3.2YTCh. 3 - Determining Protons, Neutrons, and Electrons How...Ch. 3 - Calculating Atomic Mass Magnesium has three...Ch. 3 - The Mole Concept A diamond, which is pure carbon,...Ch. 3 - The Mole Concept II Calculate the number of atoms...Ch. 3 - Your friend tells you about an article that he...Ch. 3 - Prob. 2SCCh. 3 - Prob. 3SCCh. 3 - Copper is composed of two naturally occurring...
Ch. 3 - Prob. 5SCCh. 3 - Which pair of elements do you expect to be most...Ch. 3 - Which statement is true of the quantum mechanical...Ch. 3 - Why is it important to understand atoms?Ch. 3 - Prob. 2ECh. 3 - What defines an element? How many naturally...Ch. 3 - Prob. 4ECh. 3 - Prob. 5ECh. 3 - Prob. 6ECh. 3 - Prob. 7ECh. 3 - Prob. 8ECh. 3 - Prob. 9ECh. 3 - Prob. 10ECh. 3 - Explain the quantum mechanical model for the atom....Ch. 3 - Give two examples of each: a. alkali metal b....Ch. 3 - Which elements exist as diatomic molecules?Ch. 3 - Explain the difference and similarity between...Ch. 3 - Prob. 15ECh. 3 - Determine the charge of each of the following: a...Ch. 3 - Determine the number of protons and electrons in...Ch. 3 - Determine the number of protons and electrons in...Ch. 3 - Give the atomic number (Z) and the mass number (A)...Ch. 3 - Prob. 20ECh. 3 - The following isotopes have applications in...Ch. 3 - The following isotopes are important in nuclear...Ch. 3 - 14C is used in carbon dating of artifacts....Ch. 3 - 40K is used to measure the age of Earth. Determine...Ch. 3 - Prob. 25ECh. 3 - Prob. 26ECh. 3 - Give electron configurations according to the Bohr...Ch. 3 - Give electron configurations according to the Bohr...Ch. 3 - Prob. 29ECh. 3 - How many valence electrons are in each element of...Ch. 3 - Prob. 31ECh. 3 - Draw electron configurations for each of the...Ch. 3 - Which two of the following elements would you...Ch. 3 - Group the following elements into three similar...Ch. 3 - We have seen that the reactivity of an element is...Ch. 3 - What is the electron configuration of Mg2+? How...Ch. 3 - Classify each of the following elements as a...Ch. 3 - Classify each of the following as a metal, a...Ch. 3 - Calculate the atomic mass of neon (Ne), which is...Ch. 3 - An element has two naturally occurring isotopes....Ch. 3 - A fictitious element has two naturally occurring...Ch. 3 - Copper has two naturally occurring isotopes. Cu-63...Ch. 3 - How many moles of titanium are present in 124 g of...Ch. 3 - Prob. 44ECh. 3 - How many moles are there in each sample? a. 45 mg...Ch. 3 - How many moles are there in each sample? a. 55.0 g...Ch. 3 - What is the mass of each sample? a.1.8 mol S...Ch. 3 - What is the mass of each sample? a.2.75 mol Fe...Ch. 3 - Determine the number of atoms in each sample....Ch. 3 - Determine the number of atoms in each sample....Ch. 3 - How many Ag atoms are present in a piece of pure...Ch. 3 - How many platinum atoms are in a pure platinum...Ch. 3 - A pure gold necklace has a volume of 1.8cm3. How...Ch. 3 - A titanium bicycle component has a volume of...Ch. 3 - An iron sphere has a radius of 3.4 cm. How many...Ch. 3 - Calculate the number of atoms in the universe. The...Ch. 3 - The introduction to this chapter states that...Ch. 3 - Suppose the absolute value of the charge of the...Ch. 3 - When we refer to doughnuts or cookies, we often...Ch. 3 - Prob. 60ECh. 3 - Why does Avogadros number have such an odd value?...Ch. 3 - Prob. 62ECh. 3 - Prob. 63ECh. 3 - Prob. 64ECh. 3 - Here are three fictitious elements and a molecular...Ch. 3 - Prob. 66ECh. 3 - Gather any two of the following items, measure...
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- Nonearrow_forwardPart II. Given below are the 'H-NMR spectrum at 300 MHz in CDC13 and mass spectrum using electron ionization of compound Brian. The FTIR of the said compound showed a strong peak at 1710 cm"). Determine the following: (a) molecular Formula and Degree of unsaturation of compound Brian (b) Basing on the given H-NMR spectrum tabulate the following (i) chemical shifts (ii) integration, ciii) multiplicity and (iv) interferences made for each signal (c) Draw the structure of compound Brian. ) ΕΙ 43 41 27 71 114 (M+) Hmmm 20 30 40 50 60 70 80 90 100 110 120 1H NMR spectrum 300 MHz in CDCl3 2.0 alle 1.0arrow_forwardThe iron-iron carbide phase diagram. In the diagram, the letter L indicates that it is a liquid. Indicate what its components are. Temperature (°C) 1600 10 Composition (at% C) 15 25 1538°C -1493°C 8 1400 1200 1394°C y+L L 2500 1147°C y. Austenite 2.14 4.30 2000 1000 912°C y + Fe3C 800ㅏ 0.76 0.022 600 a, Ferrite a + Fe3C 400 0 (Fe) Composition (wt% C) 727°C 1500 Cementite (Fe3C) 1000 6 6.70 Temperature (°F)arrow_forward
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