CNCT ORG CHEM 6 2020
6th Edition
ISBN: 9781266807244
Author: SMITH
Publisher: MCG
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Chapter 29, Problem 44P
Interpretation Introduction
Interpretation: The mechanism for the given reaction is to be drawn.
Concept introduction: In biological reactions, allylic carbocations are the intermediates that are required for the formation of Farnesyl diphosphate.
The general steps involved in the biological formation of Farnesyl diphosphate are stated below.
➢ The first step is the generation of allylic carbocation by the loss of the diphosphate group.
➢ The second step is the nucleophilic attack of isopentyl diphosphate to form new bond.
➢ The third step is the deprotonation to give final product.
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Laser. Indicate the relationship between metastable state and stimulated emission.
The table includes macrostates characterized by 4 energy levels (&) that are
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a) Calculate the energy of all the macrostates (in joules). See if they all have
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b) Calculate the macrostate that is most likely to exist. For this macrostate,
show that the population of the levels is consistent with the Boltzmann
distribution.
macrostate 1 macrostate 2 macrostate 3
ε/k (K) Populations
Populations
Populations
300
5
3
4
200
7
9
8
100
15
17
16
0
33
31
32
DATO: k = 1,38×10-23 J K-1
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Chapter 29 Solutions
CNCT ORG CHEM 6 2020
Ch. 29.2 - Problem 31.1
One component of jojoba oil is a wax...Ch. 29.3 - Problem 31.2
How would you expect the melting...Ch. 29.3 - Problem 31.3
Draw the products formed when...Ch. 29.3 - Problem 31.4
The main fatty acid component of the...Ch. 29.3 - Prob. 5PCh. 29.7 - Problem 31.10
Locate the isoprene units in each...Ch. 29.7 - Problem 31.11
Locate the isoprene units in...Ch. 29.7 - Problem 31.12
Write a stepwise mechanism for the...Ch. 29.7 - Prob. 14PCh. 29.8 - Prob. 15P
Ch. 29.8 - Prob. 16PCh. 29.8 - Prob. 17PCh. 29 - 31.17 Locate the isoprene units in each...Ch. 29 - Prob. 25PCh. 29 - Locate the isoprene units in each compound. a. e....Ch. 29 - 31.27 Classify each terpene and terpenoid in...Ch. 29 - Prob. 33PCh. 29 - Draw three-dimensional structures f or each...Ch. 29 - Prob. 37PCh. 29 - Prob. 38PCh. 29 - Prob. 39PCh. 29 - Prob. 40PCh. 29 - 31.38 Draw the products formed when cholesterol is...Ch. 29 - 31.39 Draw a stepwise mechanism for the following...Ch. 29 - 31.40 Draw a stepwise mechanism for the following...Ch. 29 - Prob. 44P
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