The structure of the polymer formed from ring-opening metathesis polymerization of given monomer has to be drawn. Concept introduction: An unsaturated polymer in which the number of double bonds in the polymer is the same as that in the monomers polymerized. This process is called ring-opening metathesis polymerization.

Question

Q4: Rank the relative nucleophilicity of halide ions in water solution and DMF solution, respectively. F CI Br | Q5: Determine which of the substrates will and will not react with NaSCH3 in an SN2 reaction to have a reasonable yield of product. NH2 Br Br Br OH Br

Answer 1

Question

Definition Definition Chemical process in which one or more monomers combine to produce a very large chain-like molecule called a polymer. The functional groups present on the monomers and their steric effects are responsible for polymerization through a sequence of reactions that vary in complexity. There exists a stable covalent chemical bond between monomers that sets apart polymerization from other processes.

Chapter 29, Problem 29.38P

(a)

Interpretation Introduction

Interpretation:

The structure of the polymer formed from ring-opening metathesis polymerization of given monomer has to be drawn.

Concept introduction:

An unsaturated polymer in which the number of double bonds in the polymer is the same as that in the monomers polymerized. This process is called ring-opening metathesis polymerization.

(b)

Interpretation Introduction

Interpretation:

The structure of the polymer formed from ring-opening metathesis polymerization of given monomer has to be drawn.

Concept introduction:

An unsaturated polymer in which the number of double bonds in the polymer is the same as that in the monomers polymerized. This process is called ring-opening metathesis polymerization.

(c)

Interpretation Introduction

Interpretation:

The structure of the polymer formed from ring-opening metathesis polymerization of given monomer has to be drawn.

Concept introduction:

An unsaturated polymer in which the number of double bonds in the polymer is the same as that in the monomers polymerized. This process is called ring-opening metathesis polymerization.

(d)

Interpretation Introduction

Interpretation:

The structure of the polymer formed from ring-opening metathesis polymerization of given monomer has to be drawn.

Concept introduction:

An unsaturated polymer in which the number of double bonds in the polymer is the same as that in the monomers polymerized. This process is called ring-opening metathesis polymerization.

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Q4: Rank the relative nucleophilicity of halide ions in water solution and DMF solution, respectively. F CI Br | Q5: Determine which of the substrates will and will not react with NaSCH3 in an SN2 reaction to have a reasonable yield of product. NH2 Br Br Br OH Br

Q7: Rank the following groups in order of basicity, nucleophilicity, and leaving group ability. a) H₂O, OH, CH3COOT b) NH3, H₂O, H₂S

Q8: Rank the following compounds in order of increasing reactivity in a nucleophilic substitution reaction with CN as the nucleophile. Br A B NH2 LL F C D OH CI LLI E Q9: Complete the missing entities for following reactions (e.g., major product(s), reactants, and/or solvents) for the SN2 reactions to occur efficiently. Include curved-arrow mechanism for reactions a) to d). a) H "Cl D + -OCH 3 Page 3 of 5

Answer 2

Question

Definition Definition Chemical process in which one or more monomers combine to produce a very large chain-like molecule called a polymer. The functional groups present on the monomers and their steric effects are responsible for polymerization through a sequence of reactions that vary in complexity. There exists a stable covalent chemical bond between monomers that sets apart polymerization from other processes.

Chapter 29, Problem 29.38P

(a)

Interpretation Introduction

Interpretation:

The structure of the polymer formed from ring-opening metathesis polymerization of given monomer has to be drawn.

Concept introduction:

An unsaturated polymer in which the number of double bonds in the polymer is the same as that in the monomers polymerized. This process is called ring-opening metathesis polymerization.

(b)

Interpretation Introduction

Interpretation:

The structure of the polymer formed from ring-opening metathesis polymerization of given monomer has to be drawn.

Concept introduction:

An unsaturated polymer in which the number of double bonds in the polymer is the same as that in the monomers polymerized. This process is called ring-opening metathesis polymerization.

(c)

Interpretation Introduction

Interpretation:

The structure of the polymer formed from ring-opening metathesis polymerization of given monomer has to be drawn.

Concept introduction:

An unsaturated polymer in which the number of double bonds in the polymer is the same as that in the monomers polymerized. This process is called ring-opening metathesis polymerization.

(d)

Interpretation Introduction

Interpretation:

The structure of the polymer formed from ring-opening metathesis polymerization of given monomer has to be drawn.

Concept introduction:

An unsaturated polymer in which the number of double bonds in the polymer is the same as that in the monomers polymerized. This process is called ring-opening metathesis polymerization.

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Answer 3

Question

Definition Definition Chemical process in which one or more monomers combine to produce a very large chain-like molecule called a polymer. The functional groups present on the monomers and their steric effects are responsible for polymerization through a sequence of reactions that vary in complexity. There exists a stable covalent chemical bond between monomers that sets apart polymerization from other processes.

Chapter 29, Problem 29.38P

(a)

Interpretation Introduction

Interpretation:

The structure of the polymer formed from ring-opening metathesis polymerization of given monomer has to be drawn.

Concept introduction:

An unsaturated polymer in which the number of double bonds in the polymer is the same as that in the monomers polymerized. This process is called ring-opening metathesis polymerization.

(b)

Interpretation Introduction

Interpretation:

The structure of the polymer formed from ring-opening metathesis polymerization of given monomer has to be drawn.

Concept introduction:

An unsaturated polymer in which the number of double bonds in the polymer is the same as that in the monomers polymerized. This process is called ring-opening metathesis polymerization.

(c)

Interpretation Introduction

Interpretation:

The structure of the polymer formed from ring-opening metathesis polymerization of given monomer has to be drawn.

Concept introduction:

An unsaturated polymer in which the number of double bonds in the polymer is the same as that in the monomers polymerized. This process is called ring-opening metathesis polymerization.

(d)

Interpretation Introduction

Interpretation:

The structure of the polymer formed from ring-opening metathesis polymerization of given monomer has to be drawn.

Concept introduction:

An unsaturated polymer in which the number of double bonds in the polymer is the same as that in the monomers polymerized. This process is called ring-opening metathesis polymerization.

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Answer 4

Question

Definition Definition Chemical process in which one or more monomers combine to produce a very large chain-like molecule called a polymer. The functional groups present on the monomers and their steric effects are responsible for polymerization through a sequence of reactions that vary in complexity. There exists a stable covalent chemical bond between monomers that sets apart polymerization from other processes.

Chapter 29, Problem 29.38P

(a)

Interpretation Introduction

Interpretation:

The structure of the polymer formed from ring-opening metathesis polymerization of given monomer has to be drawn.

Concept introduction:

An unsaturated polymer in which the number of double bonds in the polymer is the same as that in the monomers polymerized. This process is called ring-opening metathesis polymerization.

(b)

Interpretation Introduction

Interpretation:

The structure of the polymer formed from ring-opening metathesis polymerization of given monomer has to be drawn.

Concept introduction:

An unsaturated polymer in which the number of double bonds in the polymer is the same as that in the monomers polymerized. This process is called ring-opening metathesis polymerization.

(c)

Interpretation Introduction

Interpretation:

The structure of the polymer formed from ring-opening metathesis polymerization of given monomer has to be drawn.

Concept introduction:

An unsaturated polymer in which the number of double bonds in the polymer is the same as that in the monomers polymerized. This process is called ring-opening metathesis polymerization.

(d)

Interpretation Introduction

Interpretation:

The structure of the polymer formed from ring-opening metathesis polymerization of given monomer has to be drawn.

Concept introduction:

An unsaturated polymer in which the number of double bonds in the polymer is the same as that in the monomers polymerized. This process is called ring-opening metathesis polymerization.

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Answer 5

Chapter 29, Problem 29.38P

(a)

Interpretation Introduction

Interpretation:

The structure of the polymer formed from ring-opening metathesis polymerization of given monomer has to be drawn.

Concept introduction:

An unsaturated polymer in which the number of double bonds in the polymer is the same as that in the monomers polymerized. This process is called ring-opening metathesis polymerization.

(b)

Interpretation Introduction

Interpretation:

The structure of the polymer formed from ring-opening metathesis polymerization of given monomer has to be drawn.

Concept introduction:

An unsaturated polymer in which the number of double bonds in the polymer is the same as that in the monomers polymerized. This process is called ring-opening metathesis polymerization.

(c)

Interpretation Introduction

Interpretation:

The structure of the polymer formed from ring-opening metathesis polymerization of given monomer has to be drawn.

Concept introduction:

An unsaturated polymer in which the number of double bonds in the polymer is the same as that in the monomers polymerized. This process is called ring-opening metathesis polymerization.

(d)

Interpretation Introduction

Interpretation:

The structure of the polymer formed from ring-opening metathesis polymerization of given monomer has to be drawn.

Concept introduction:

An unsaturated polymer in which the number of double bonds in the polymer is the same as that in the monomers polymerized. This process is called ring-opening metathesis polymerization.

Answer 6

Chapter 29, Problem 29.38P

(a)

Interpretation Introduction

Interpretation:

The structure of the polymer formed from ring-opening metathesis polymerization of given monomer has to be drawn.

Concept introduction:

An unsaturated polymer in which the number of double bonds in the polymer is the same as that in the monomers polymerized. This process is called ring-opening metathesis polymerization.

Answer 7

Chapter 29, Problem 29.38P

(a)

Interpretation Introduction

Interpretation:

The structure of the polymer formed from ring-opening metathesis polymerization of given monomer has to be drawn.

Concept introduction:

An unsaturated polymer in which the number of double bonds in the polymer is the same as that in the monomers polymerized. This process is called ring-opening metathesis polymerization.

Answer 8

(b)

Interpretation Introduction

Interpretation:

The structure of the polymer formed from ring-opening metathesis polymerization of given monomer has to be drawn.

Concept introduction:

An unsaturated polymer in which the number of double bonds in the polymer is the same as that in the monomers polymerized. This process is called ring-opening metathesis polymerization.

Answer 9

(b)

Interpretation Introduction

Interpretation:

The structure of the polymer formed from ring-opening metathesis polymerization of given monomer has to be drawn.

Concept introduction:

An unsaturated polymer in which the number of double bonds in the polymer is the same as that in the monomers polymerized. This process is called ring-opening metathesis polymerization.

Answer 10

(c)

Interpretation Introduction

Interpretation:

The structure of the polymer formed from ring-opening metathesis polymerization of given monomer has to be drawn.

Concept introduction:

An unsaturated polymer in which the number of double bonds in the polymer is the same as that in the monomers polymerized. This process is called ring-opening metathesis polymerization.

Answer 11

(c)

Interpretation Introduction

Interpretation:

The structure of the polymer formed from ring-opening metathesis polymerization of given monomer has to be drawn.

Concept introduction:

An unsaturated polymer in which the number of double bonds in the polymer is the same as that in the monomers polymerized. This process is called ring-opening metathesis polymerization.

Answer 12

(d)

Interpretation Introduction

Interpretation:

The structure of the polymer formed from ring-opening metathesis polymerization of given monomer has to be drawn.

Concept introduction:

An unsaturated polymer in which the number of double bonds in the polymer is the same as that in the monomers polymerized. This process is called ring-opening metathesis polymerization.

Answer 13

(d)

Interpretation Introduction

Interpretation:

The structure of the polymer formed from ring-opening metathesis polymerization of given monomer has to be drawn.

Concept introduction:

An unsaturated polymer in which the number of double bonds in the polymer is the same as that in the monomers polymerized. This process is called ring-opening metathesis polymerization.

Answer 14

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Ch. 29.2 - Prob. 29.1P Ch. 29.5 - Prob. 29.2P Ch. 29.6 - Prob. AQ Ch. 29.6 - Prob. BQ Ch. 29.6 - Prob. CQ Ch. 29.6 - Prob. DQ Ch. 29.6 - Prob. EQ Ch. 29.6 - Prob. FQ Ch. 29.6 - Prob. 29.3P Ch. 29.6 - Prob. 29.4P

Solution Summary: The author describes ring-opening metathesis polymerization and ROMP reactions.

Chapter 29 Solutions