Organic Chemistry, Loose-leaf Version
Organic Chemistry, Loose-leaf Version
8th Edition
ISBN: 9781305865549
Author: William H. Brown, Brent L. Iverson, Eric Anslyn, Christopher S. Foote
Publisher: Cengage Learning
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Chapter 29, Problem 29.33P

(a)

Interpretation Introduction

Interpretation:

The structural formula for the repeat unit of natural rubber has to be drawn.

(b)

Interpretation Introduction

Interpretation:

The structural formula of the product of oxidation of natural rubber by ozone followed by a workup in the presence of (CH3)2S has to be drawn.

(c)

Interpretation Introduction

Interpretation:

The reactivity of Ozone with natural rubber and polyethylene or polyvinyl chloride has to be comparatively explained.

(d)

Interpretation Introduction

Interpretation:

The elasticity of natural rubber and synthetic all-trans isomer has to be comparatively explained.

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a. The change in the Gibbs energy of a certain constant pressure process is found to fit the expression: AG-85.1 J mol −1 +36.5 J mol ¹K-1 × T A. Calculate the value of AS for the process. B. Next, use the Gibbs-Helmholtz equation: (a(AG/T)) ΔΗ - T2 to calculate the value of AH for the process.
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