(a) Interpretation: The polymer formed by radical polymerization of given monomer is to be predicted. Concept introduction: The simpler units which combine to form polymers are known as monomers. The process by which respective monomers combine to form polymers is known as polymerization.

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Answer 1

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Definition Definition Chemical process in which one or more monomers combine to produce a very large chain-like molecule called a polymer. The functional groups present on the monomers and their steric effects are responsible for polymerization through a sequence of reactions that vary in complexity. There exists a stable covalent chemical bond between monomers that sets apart polymerization from other processes.

Chapter 28.2, Problem 3P

Interpretation Introduction

(a)

Interpretation: The polymer formed by radical polymerization of given monomer is to be predicted.

Concept introduction: The simpler units which combine to form polymers are known as monomers. The process by which respective monomers combine to form polymers is known as polymerization.

Interpretation Introduction

(b)

Interpretation: The polymer formed by radical polymerization of given monomer is to be predicted.

Concept introduction: The simpler units which combine to form polymers are known as monomers. The process by which respective monomers combine to form polymers is known as polymerization.

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5. Use the MS data to answer the questions on the next page. 14.0 1.4 15.0 8.1 100- MS-IW-5644 26.0 2.8 27.0 6.7 28.0 1.8 29.0 80 4.4 38.0 1.0 39.0 1.5 41.0 1.2 42.0 11.2 43.0 100.0 44.0 4.3 79.0 1.9 80.0 2.6 Relative Intensity 40 81.0 1.9 82.0 2.5 93.0 8.7 20- 95.0 8.2 121.0 2.0 123.0 2.0 136.0 11.8 0 138.0 11.5 20 40 8. 60 a. Br - 0 80 100 120 140 160 180 200 220 m/z Identify the m/z of the base peak and molecular ion. 2 b. Draw structures for each of the following fragments (include electrons and charges): 43.0, 93.0, 95.0, 136.0, and 138.0 m/z. C. Draw a reasonable a-fragmentation mechanism for the fragmentation of the molecular ion to fragment 43.0 m/z. Be sure to include all electrons and formal charges. 6. Using the values provided in Appendix E of your lab manual, calculate the monoisotopic mass for the pyridinium ion (CsH6N) and show your work.

Answer 2

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Definition Definition Chemical process in which one or more monomers combine to produce a very large chain-like molecule called a polymer. The functional groups present on the monomers and their steric effects are responsible for polymerization through a sequence of reactions that vary in complexity. There exists a stable covalent chemical bond between monomers that sets apart polymerization from other processes.

Chapter 28.2, Problem 3P

Interpretation Introduction

(a)

Interpretation: The polymer formed by radical polymerization of given monomer is to be predicted.

Concept introduction: The simpler units which combine to form polymers are known as monomers. The process by which respective monomers combine to form polymers is known as polymerization.

Interpretation Introduction

(b)

Interpretation: The polymer formed by radical polymerization of given monomer is to be predicted.

Concept introduction: The simpler units which combine to form polymers are known as monomers. The process by which respective monomers combine to form polymers is known as polymerization.

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Answer 3

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Definition Definition Chemical process in which one or more monomers combine to produce a very large chain-like molecule called a polymer. The functional groups present on the monomers and their steric effects are responsible for polymerization through a sequence of reactions that vary in complexity. There exists a stable covalent chemical bond between monomers that sets apart polymerization from other processes.

Chapter 28.2, Problem 3P

Interpretation Introduction

(a)

Interpretation: The polymer formed by radical polymerization of given monomer is to be predicted.

Concept introduction: The simpler units which combine to form polymers are known as monomers. The process by which respective monomers combine to form polymers is known as polymerization.

Interpretation Introduction

(b)

Interpretation: The polymer formed by radical polymerization of given monomer is to be predicted.

Concept introduction: The simpler units which combine to form polymers are known as monomers. The process by which respective monomers combine to form polymers is known as polymerization.

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Answer 4

Question

Definition Definition Chemical process in which one or more monomers combine to produce a very large chain-like molecule called a polymer. The functional groups present on the monomers and their steric effects are responsible for polymerization through a sequence of reactions that vary in complexity. There exists a stable covalent chemical bond between monomers that sets apart polymerization from other processes.

Chapter 28.2, Problem 3P

Interpretation Introduction

(a)

Interpretation: The polymer formed by radical polymerization of given monomer is to be predicted.

Concept introduction: The simpler units which combine to form polymers are known as monomers. The process by which respective monomers combine to form polymers is known as polymerization.

Interpretation Introduction

(b)

Interpretation: The polymer formed by radical polymerization of given monomer is to be predicted.

Concept introduction: The simpler units which combine to form polymers are known as monomers. The process by which respective monomers combine to form polymers is known as polymerization.

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Answer 5

Chapter 28.2, Problem 3P

Interpretation Introduction

(a)

Interpretation: The polymer formed by radical polymerization of given monomer is to be predicted.

Concept introduction: The simpler units which combine to form polymers are known as monomers. The process by which respective monomers combine to form polymers is known as polymerization.

Interpretation Introduction

(b)

Interpretation: The polymer formed by radical polymerization of given monomer is to be predicted.

Concept introduction: The simpler units which combine to form polymers are known as monomers. The process by which respective monomers combine to form polymers is known as polymerization.

Answer 6

Chapter 28.2, Problem 3P

Interpretation Introduction

(a)

Interpretation: The polymer formed by radical polymerization of given monomer is to be predicted.

Concept introduction: The simpler units which combine to form polymers are known as monomers. The process by which respective monomers combine to form polymers is known as polymerization.

Answer 7

Chapter 28.2, Problem 3P

Interpretation Introduction

(a)

Interpretation: The polymer formed by radical polymerization of given monomer is to be predicted.

Concept introduction: The simpler units which combine to form polymers are known as monomers. The process by which respective monomers combine to form polymers is known as polymerization.

Answer 8

Interpretation Introduction

(b)

Interpretation: The polymer formed by radical polymerization of given monomer is to be predicted.

Concept introduction: The simpler units which combine to form polymers are known as monomers. The process by which respective monomers combine to form polymers is known as polymerization.

Answer 9

Interpretation Introduction

(b)

Interpretation: The polymer formed by radical polymerization of given monomer is to be predicted.

Concept introduction: The simpler units which combine to form polymers are known as monomers. The process by which respective monomers combine to form polymers is known as polymerization.

Answer 10

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Answer 11

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Answer 12

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Answer 13

Ch. 28.1 - Prob. 1P Ch. 28.2 - Prob. 2P Ch. 28.2 - Prob. 3P Ch. 28.2 - Draw the mechanism for the radical polymerization...Ch. 28.2 - Prob. 8P Ch. 28.2 - Prob. 9P Ch. 28.2 - Prob. 10P Ch. 28.3 - Problem 30.12 What polymer is formed by anionic...Ch. 28.5 - Prob. 12P Ch. 28.5 - Prob. 13P

(a) Interpretation: The polymer formed by radical polymerization of given monomer is to be predicted. Concept introduction: The simpler units which combine to form polymers are known as monomers. The process by which respective monomers combine to form polymers is known as polymerization.

Solution Summary: The author explains that the polymer formed by radical Polymerization of given monomer is to be predicted.

(a)

Interpretation: The polymer formed by radical polymerization of given monomer is to be predicted.

Concept introduction: The simpler units which combine to form polymers are known as monomers. The process by which respective monomers combine to form polymers is known as polymerization.

(b)

Interpretation: The polymer formed by radical polymerization of given monomer is to be predicted.

Concept introduction: The simpler units which combine to form polymers are known as monomers. The process by which respective monomers combine to form polymers is known as polymerization.

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Chapter 28 Solutions

(a) Interpretation: The polymer formed by radical polymerization of given monomer is to be predicted. Concept introduction: The simpler units which combine to form polymers are known as monomers. The process by which respective monomers combine to form polymers is known as polymerization.

Solution Summary: The author explains that the polymer formed by radical Polymerization of given monomer is to be predicted.

(a) Interpretation: The polymer formed by radical polymerization of given monomer is to be predicted. Concept introduction: The simpler units which combine to form polymers are known as monomers. The process by which respective monomers combine to form polymers is known as polymerization.

(b) Interpretation: The polymer formed by radical polymerization of given monomer is to be predicted. Concept introduction: The simpler units which combine to form polymers are known as monomers. The process by which respective monomers combine to form polymers is known as polymerization.

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Chapter 28 Solutions

(a)

Interpretation: The polymer formed by radical polymerization of given monomer is to be predicted.

Concept introduction: The simpler units which combine to form polymers are known as monomers. The process by which respective monomers combine to form polymers is known as polymerization.

(b)

Interpretation: The polymer formed by radical polymerization of given monomer is to be predicted.

Concept introduction: The simpler units which combine to form polymers are known as monomers. The process by which respective monomers combine to form polymers is known as polymerization.