Chemical Principles in the Laboratory
Chemical Principles in the Laboratory
11th Edition
ISBN: 9781305264434
Author: Emil Slowinski, Wayne C. Wolsey, Robert Rossi
Publisher: Brooks Cole
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Chapter 28, Problem 3ASA

A 100-mL sample of hard water is titrated with the EDTA solution in Problem 2. The same amount of Mg2+ is added as previously, and the volume of EDTA required is 31.84 mL.

a. What volume of EDTA is used in titrating the Ca2+ in the hard water? _____________mL

b. How many moles of EDTA are there in that volume? _____________ moles

c. How many moles of Ca2+ are there in the 100 mL of water? _____________ moles

d. If the Ca2+ comes from CaCO3, how many moles of CaCO3 are there in one liter of the water? How many grams of CaCO3 are present per liter of the water? _____________ mol / L _____________ g / L

e. If 1 ppm CaCO3 = 1 mg per liter, what is the water hardness in ppm CaCO3? _____________ ppm CaCO3

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02. A 10.00 mL sample of phosphoric acid was titrated to endpoint with a 0.2222 M NaOH solution. The titer was 45.15 mL. The concentration of the phosphoric acid is __________ M.
50 mL of a sample known to contain Mg+2 was taken and titrated with 0.075 M EDTA standard solution by adding pH 10 buffer and EBT indicator. Since the EDTA consumption is 10.5 mL, which of the following is the amount of magnesium in the sample in ppm? (Mg:24 g/mol) A.  378  B.  302  C.  214  D.  251
How many mL of 0.1200 M KSCN will be needed in the back titration after addition of 30 mL 0.110 M AgNO3 solution to 0.3655g KI dissolved in 100 mL water? a. 1.1951 mL b. 5.1919 mL c. 9.1519 mL d. 1.5911 mL

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Chemical Principles in the Laboratory

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