The correct conversion factor for solving the problem “ 1 hour =? Seconds ” has to be identified from the given options, using dimensional analysis and unit pathway. Concept Introduction: Measurement is the measure of quantity, capacity, dimensions or extent of something. Mass, length, pressure, temperature, volume, time and concentration are some common type of measurements. English system and metric system are two types of measurement systems that are in use in the United States. Measurement wise both English system and metric system are precise. There are instance where measurements from one system has to be changed to their equivalent in other system. This is called the conversion factor. These conversion factors always appear as pairs. For example 60min is same as 1hr and vice versa. So two conversion factors are possible for this equality. In case of calculating dimensional analysis, numbers associated with units are used as guide for solving the problems.

Question

Identify and provide an explanation that distinguishes a qualitative and quantitative chemical analysis. Provide examples.

Answer 1

Question

Chapter 2.8, Problem 2QQ

Interpretation Introduction

Interpretation:

The correct conversion factor for solving the problem “1 hour =? Seconds ” has to be identified from the given options, using dimensional analysis and unit pathway.

Concept Introduction:

Measurement is the measure of quantity, capacity, dimensions or extent of something. Mass, length, pressure, temperature, volume, time and concentration are some common type of measurements. English system and metric system are two types of measurement systems that are in use in the United States. Measurement wise both English system and metric system are precise. There are instance where measurements from one system has to be changed to their equivalent in other system. This is called the conversion factor. These conversion factors always appear as pairs. For example 60min is same as 1hr and vice versa. So two conversion factors are possible for this equality. In case of calculating dimensional analysis, numbers associated with units are used as guide for solving the problems.

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Instructions: Complete the questions in the space provided. Show all your work 1. You are trying to determine the rate law expression for a reaction that you are completing at 25°C. You measure the initial reaction rate and the starting concentrations of the reactions for 4 trials. BrO³¯ (aq) + 5Br¯ (aq) + 6H* (aq) → 3Br₂ (l) + 3H2O (l) Initial rate Trial [BrO3] [H*] [Br] (mol/L) (mol/L) | (mol/L) (mol/L.s) 1 0.10 0.10 0.10 8.0 2 0.20 0.10 0.10 16 3 0.10 0.20 0.10 16 4 0.10 0.10 0.20 32 a. Based on the above data what is the rate law expression? b. Solve for the value of k (make sure to include proper units) 2. The proposed reaction mechanism is as follows: i. ii. BrО¸¯ (aq) + H+ (aq) → HBrO3 (aq) HBrO³ (aq) + H* (aq) → H₂BrO3* (aq) iii. H₂BrO³* (aq) + Br¯ (aq) → Br₂O₂ (aq) + H2O (l) [Fast] [Medium] [Slow] iv. Br₂O₂ (aq) + 4H*(aq) + 4Br‍(aq) → 3Br₂ (l) + H2O (l) [Fast] Evaluate the validity of this proposed reaction. Justify your answer.