BNDL: ACP ORGANIC CHEMISTRY:CH EM 231(W/ACCESS CARD)
8th Edition
ISBN: 9781337687539
Author: Brown/Iverson/Anslyn/ Foote
Publisher: CENGAGE C
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Chapter 28, Problem 28.7P
Interpretation Introduction
Interpretation:
The structural formulas for the enethiol forms of 6-mercaptopurine and 6-thioguanine has to be drawn.
Concept Introduction:
The
Expert Solution & Answer
Explanation of Solution
The enethiol is also the enol form which contains Sulphur molecule instead of Oxygen. The enethiol form is the alcoholic form of the Sulphur. The double bonded Sulphur is converted to thiol form of the Sulphur.
The enethiol form of 6-mercaptopurine is
The enethiol form of 6-thioguanine is
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A pioneer in designing and synthesizing antimetabolites that could destroy cancer cells
was George Hitchings at the Burroughs Wellcome Company. In 1942, he initiated a pro-
gram to discover DNA antimetabolites, and in 1948, he and Gertrude Elion synthesized
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HN
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6-Mercaptopurine
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amylose and cellulose
Match the words in the left column to the appropriate blanks in the sentences on the right.
a(16)
B(14)
a(12)
glucose
a(14)
8(16)
a(12)
fructose
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a(12)
B(16)
a(16)
cellulose and chitin
Match the words in the left column to the appropriate blanks in the sentences on the right.
glucose
-tose also called - Search
a(14)
fructose
8(14)
B(12)
x | +
Both are linear polysaccharides composed entirely of
linkages are
but in cellulose, they are
Both are linear polysaccharides with
2
DELL
and chitin contains N-acetylglucosamine.
A Q
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In amylose, the glycosidic
glycosidic bonds. Cellulose contains
he
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Constants
Q23:
Dr. Alghe has just performed a restriction digest on DNA she extracted from her samples. She must now run her DNA out on a gel to separate the fragments based on size. To do this she must prepare a 1.1% agarose gel, where the percentage is determined as mass/vol.
How many grams of agarose must she add to 413 mL of buffer in order to arrive at the correct percentage? (answer to 2 decimals)
**Assume the dissolution of agarose will not alter the final volume of the solution**
Chapter 28 Solutions
BNDL: ACP ORGANIC CHEMISTRY:CH EM 231(W/ACCESS CARD)
Ch. 28.1 - Prob. 28.1PCh. 28.2 - Prob. 28.2PCh. 28.2 - Prob. 28.3PCh. 28.3 - Here is a portion of the nucleotide sequence in...Ch. 28.4 - The following section of DNA codes for oxytocin, a...Ch. 28.5 - Prob. 28.6PCh. 28 - Prob. 28.7PCh. 28 - Following are structural formulas for cytosine and...Ch. 28 - Prob. 28.9PCh. 28 - Prob. 28.10P
Ch. 28 - Prob. 28.11PCh. 28 - Prob. 28.12PCh. 28 - Prob. 28.13PCh. 28 - Prob. 28.14PCh. 28 - Prob. 28.15PCh. 28 - Draw a structural formula of the DNA...Ch. 28 - List the postulates of the Watson-Crick model of...Ch. 28 - Prob. 28.18PCh. 28 - Prob. 28.19PCh. 28 - Prob. 28.20PCh. 28 - Prob. 28.21PCh. 28 - Prob. 28.22PCh. 28 - Prob. 28.23PCh. 28 - Prob. 28.24PCh. 28 - Write the DNA complement for 5-ACCGTTAAT-3. Be...Ch. 28 - Prob. 28.26PCh. 28 - Prob. 28.27PCh. 28 - Compare DNA and RNA is these ways. (a)...Ch. 28 - What type of RNA has the shortest lifetime in...Ch. 28 - Prob. 28.30PCh. 28 - Prob. 28.31PCh. 28 - Prob. 28.32PCh. 28 - Write the mRNA codons for the following. (a)...Ch. 28 - Prob. 28.34PCh. 28 - Prob. 28.35PCh. 28 - Prob. 28.36PCh. 28 - Prob. 28.37PCh. 28 - Prob. 28.38PCh. 28 - Prob. 28.39PCh. 28 - What polypeptide is coded for by this mRNA...Ch. 28 - The alpha chain of human hemoglobin has 141 amino...Ch. 28 - Prob. 28.42P
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Nucleic acids - DNA and RNA structure; Author: MEDSimplified;https://www.youtube.com/watch?v=0lZRAShqft0;License: Standard YouTube License, CC-BY