ORGANIC CHEM +SG +SAPLING >IP<
ORGANIC CHEM +SG +SAPLING >IP<
6th Edition
ISBN: 9781319171179
Author: LOUDON
Publisher: MAC HIGHER
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Chapter 28, Problem 28.36AP
Interpretation Introduction

Interpretation:

Heptafulvalene undergoes a thermal reaction with tetracyanoethylene (TCNE) to give the adduct shown in Fig. P28.36.The stereochemistry of this adduct is to be explained.

ORGANIC CHEM +SG +SAPLING >IP<, Chapter 28, Problem 28.36AP

Concept introduction:

Cycloaddition reaction can be referred as a reaction of two different π-electron systems to form a ring product. Notably, in this reaction two new sigma bonds are formed in product with the disappearance of two fewer π-bonds. In other words, cyclo addition reaction can be best described as the reaction of number of electrons involved. In [4+2] cycloaddition one component is having four electrons and other component is having two electrons.

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