Chemistry: The Central Science, Books a la Carte Edition & Solutions to Red Exercises for Chemistry & Mastering Chemistry with Pearson eText -- Access Card Package
1st Edition
ISBN: 9780134024516
Author: Theodore E. Brown, H. Eugene LeMay, Bruce E. Bursten, Catherine Murphy, Patrick Woodward, Matthew E. Stoltzfus
Publisher: PEARSON
expand_more
expand_more
format_list_bulleted
Videos
Textbook Question
Chapter 2.8, Problem 2.13.2PE
The table below shows the normal boiling points of benzene and benzene derivatives.
- How many of these compounds exhibit dispersion interaction?
- How many of these compounds exhibit dipole-dipole interaction?
- How many of these compounds exhibit hydrogen bonding?
- Why is the boiling point of bromobenzene higher than that of chlorobenzene?
- Why is the boiling point of phenol the highest of all?
Expert Solution & Answer
Want to see the full answer?
Check out a sample textbook solution
Students have asked these similar questions
The boiling points of three compounds are tabulated here.
Molar Mass
Boiling Point
2-hexanone
100.16
128°C
heptane
100.20
98°C
1-hexanol
102.17
156°C
Answer the following questions without looking up the
structures for these molecules: Which compound experiences
hydrogen bonding? Which compound is polar but does not
experience hydrogen bonding? Which is neither polar nor
capable of hydrogen bonding? Explain your answers.
1. Each of the following substances is a liquid at -50°C. Place these liquids in order of increasing vapor pressure.
dimethyl ether (CH3OCH3), propane (C3H8), ethanol (CH3CH₂OH)
Essential oils are concentrated liquid containing metabolites extracted from plant sources and are widely used in the production of perfumes. The structures of some of these compounds present in essential oils are presented below.
Arrange the given compounds in terms of increasing boiling points.
An equal volume of COMPOUNDS A, B and C were stored in separate beakers which were left uncovered at room temperature.
If the three liquids were allowed to stand for about 10 minutes, which of the following will have the least amount of liquid remaining in the container?
What physical property is the basis of the answer?
Among the three liquids, what is the most recommended ingredient of a perfume that will have the most lasting scent.
Chapter 2 Solutions
Chemistry: The Central Science, Books a la Carte Edition & Solutions to Red Exercises for Chemistry & Mastering Chemistry with Pearson eText -- Access Card Package
Ch. 2.3 - Prob. 2.1.1PECh. 2.3 - Prob. 2.1.2PECh. 2.3 - Prob. 2.2.1PECh. 2.3 - Prob. 2.2.2PECh. 2.3 - Prob. 2.3.1PECh. 2.3 - Prob. 2.3.2PECh. 2.4 - Practice Exercise 1 The atomic weight of copper,...Ch. 2.4 - Prob. 2.4.2PECh. 2.5 - Prob. 2.5.1PECh. 2.5 - Prob. 2.5.2PE
Ch. 2.6 - 11.93 The vapor pressure of ethanol (C2H5OH) at 19...Ch. 2.6 - Prob. 2.6.2PECh. 2.7 - Prob. 2.7.1PECh. 2.7 - Prob. 2.7.2PECh. 2.7 - Prob. 2.8.1PECh. 2.7 - Consider the two-dimensional square lattice of...Ch. 2.7 - Prob. 2.9.1PECh. 2.7 - Given the ionic radii and molar masses of Sc3+...Ch. 2.7 - Prob. 2.10.1PECh. 2.7 - Prob. 2.10.2PECh. 2.8 - Prob. 2.11.1PECh. 2.8 - Prob. 2.11.2PECh. 2.8 - Prob. 2.12.1PECh. 2.8 - Prob. 2.12.2PECh. 2.8 - Prob. 2.13.1PECh. 2.8 - The table below shows the normal boiling points of...Ch. 2.8 - Prob. 2.14.1PECh. 2.8 - Prob. 2.14.2PECh. 2.9 - Prob. 2.15.1PECh. 2.9 - Prob. 2.15.2PECh. 2 - Prob. 1ECh. 2 - At 280C, raw milk sours in 4.0 h but takes 48 h to...Ch. 2 - At 900 o C, Kc = 0.0108 for the reaction CaCO3(g) ...Ch. 2 - Calculate the molar concentration of OH- in a...Ch. 2 - Pyridinium bromide (C5H5NHBr) is a strong...Ch. 2 - Prob. 6ECh. 2 - Prob. 7ECh. 2 - Prob. 8ECh. 2 - Prob. 9ECh. 2 - Indicate whether each statement is true or false:...Ch. 2 - Prob. 11ECh. 2 - Prob. 12ECh. 2 - Prob. 13ECh. 2 - At 20 oC, the vapor pressure of benzene (C6 H6) is...Ch. 2 - Summarize the evidence used by J. J. Thomson to...Ch. 2 - Prob. 16ECh. 2 - Prob. 17ECh. 2 - Prob. 18ECh. 2 - Suppose the rate law for the reaction in this...Ch. 2 - Practice Exercise 1 Using the data in Sample...Ch. 2 - Which of the following linear plots do you expect...Ch. 2 - A flask is charged with 0.100 mol of A and allowed...Ch. 2 - Prob. 23ECh. 2 - Prob. 24ECh. 2 - Prob. 25ECh. 2 - Prob. 26ECh. 2 - The addition of No accelerates the decomposition...Ch. 2 - Prob. 28ECh. 2 - Prob. 29ECh. 2 - The rates of many atmospheric reactions are...Ch. 2 - Prob. 31ECh. 2 - Prob. 32ECh. 2 - Prob. 33ECh. 2 - 15.23 The equilibrium constant for the...Ch. 2 - A mixture of 0.10 mol of NO, 0.050 mol of H2, and...Ch. 2 - Prob. 36ECh. 2 - Prob. 37ECh. 2 - Prob. 38ECh. 2 - Prob. 39ECh. 2 - Prob. 40ECh. 2 - Practice Exercise 1 Order the following three...Ch. 2 - Practice Exercise 1 What is the pH of a 0.28 M...Ch. 2 - Prob. 43ECh. 2 - Which of the following diagrams best represent an...Ch. 2 - Prob. 45ECh. 2 - Prob. 46ECh. 2 - Prob. 47ECh. 2 - Prob. 48ECh. 2 - Prob. 49ECh. 2 - 16.72 Calculate the molar concentration of OH- in...Ch. 2 - Prob. 51ECh. 2 - Prob. 52ECh. 2 - Prob. 53ECh. 2 - Prob. 54ECh. 2 - a. Given that Ka for acetic acid is 1.8 10-5 and...Ch. 2 - 16.78
a. Given that Kb for ammonia is 1.8 X 10 -5...Ch. 2 - Prob. 57ECh. 2 - Prob. 58ECh. 2 - Prob. 59ECh. 2 - Prob. 60ECh. 2 - Prob. 61ECh. 2 - Prob. 62ECh. 2 - 16.86 An unknown salt is either KBr, NH4 C1, KCN,...Ch. 2 - Prob. 64ECh. 2 - Prob. 65ECh. 2 - 16.89 Based on their compositions and structures...Ch. 2 - Prob. 67ECh. 2 - 16.91 Indicate whether each of the following...Ch. 2 - Prob. 69ECh. 2 - Prob. 70ECh. 2 - Prob. 71ECh. 2 - Prob. 72ECh. 2 - Prob. 73ECh. 2 - Prob. 74ECh. 2 - Prob. 75ECh. 2 - Prob. 76ECh. 2 - Prob. 77ECh. 2 - Prob. 78ECh. 2 - Prob. 79ECh. 2 - Benzoic acid (C6H5COOH) and aniline (C6H5NH2) are...Ch. 2 - Prob. 81ECh. 2 - Prob. 82ECh. 2 - Prob. 83ECh. 2 - Butyric acid is responsible for the foul smell of...Ch. 2 - Prob. 85ECh. 2 - Prob. 86ECh. 2 - Prob. 87AECh. 2 - 1S.113 Many moderately large organic molecules...Ch. 2 - Prob. 89AECh. 2 - Prob. 90AECh. 2 - Prob. 91AECh. 2 - Prob. 92AECh. 2 - Prob. 93AECh. 2 - 16.120 At 50 oC, the ion-product constant for H2...Ch. 2 - Prob. 95AECh. 2 - Prob. 96AECh. 2 - Prob. 97AECh. 2 - Prob. 98AECh. 2 - Prob. 99AECh. 2 - Which two statements about gas mixtures are true?...Ch. 2 - Prob. 101AECh. 2 - 13.6 If you compare the solubilities of the noble...Ch. 2 - Prob. 103AECh. 2 - Prob. 104AECh. 2 - Suppose you had a balloon made of some highly...Ch. 2 - Prob. 106AECh. 2 - Indicate whether each statement is true or false:...Ch. 2 - Indicate the type of solute-solvent interaction...Ch. 2 - An ionic compound has a very negative H soln in...Ch. 2 - Prob. 110AECh. 2 - Prob. 111AECh. 2 - The solubility of Cr (NO3)3 . 9 H2O in water is...
Knowledge Booster
Learn more about
Need a deep-dive on the concept behind this application? Look no further. Learn more about this topic, chemistry and related others by exploring similar questions and additional content below.Similar questions
- Indicate whether each of the following statements concerning boiling and boiling point is true or false. a. A liquid can be made to boil at temperatures higher than its normal boiling point. b. A liquid can be made to boil at temperatures lower than its normal boiling point. c. In a boiling liquid, vapor formation occurs within the body of the liquid. d. To compare the boiling points of two different liquids, the external pressure should be the same.arrow_forwardWhat are intermolecular forces? How do they differ from intramolecular forces? What are dipole-dipole forces? How do typical dipole-dipole forces differ from hydrogen bonding interactions? In what ways are they similar? What are London dispersion forces? How do typical London dispersion forces differ from dipole-dipole forces? In what ways are they similar? Describe the relationship between molecular size and strength of London dispersion forces. Place the major types of intermolecular forces in order of increasing strength. Is there some overlap? That is, can the strongest London dispersion forces be greater than some dipole-dipole forces? Give an example of such an instance.arrow_forwardWhich contains the compounds listed correctly in order of increasing boiling points? (a) N2CS2H2OKCl (b) H2ON2CS2KCl (c) N2KClCS2H2O (d) CS2N2KClH2O (e) KClH2OCS2N2arrow_forward
- True or false? Methane (CH4) is more likely In form stronger hydrogen bonding than is water because each methane molecule has twice as many hydrogen alums. Provide a concise explanation of hydrogen bonding to go with your answer.arrow_forwardHomologous series The alkanes are a homologous series of compounds containing only carbon and hydrogen that have the general formula C,H2n+2. Members of this series include butane (C,H10), 3,3-dimethylpentane (C,H16), hexane (C H14), and heptane ( CH16). Part A The boiling points for a set of compounds in a homologous series can be qualitatively predicted using intermolecular force strengths. Using their condensed structural formulas, rank the homologous series for a set of alkanes by their boiling point Rank from highest to lowest boiling point. To rank items as equivalent, overlap them.arrow_forwardEssential oils are concentrated liquid containing metabolites extracted from plant sources and are widely used in the production of perfumes. The structures of some of these compounds present in essential oils are presented below. Arrange the given compounds in terms of increasing boiling points.arrow_forward
- This graph shows how the vapor pressure of three liquids varies with temperature: vapor pressure, torr 900- 800 700 600- 500 400- 3001 200 1002 0. 100 110 120 Which liquid is the most volatile? Which is the least volatile? 130 temperature, °C Use the graph to answer the following questions: What is the normal boiling point of each liquid? Note: your answer must be within 1°C of the exact answer to be -ethylbenzene -acetic acid pyrrole Suppose a beaker of acetic acid is put inside a sealed tank containing acetic acid gas at 104. degree C and 478. torr. After ten minutes, will there be more liquid in the beaker, less liquid, or the same amount? 140 most volatile: least volatile: ethylbenzene: acetic acid: pyrrole: O more O less O the same choose one choose one °C 0 °℃ °℃ X ✪ ✪arrow_forwardRank compounds in order of decreasing of their normal boiling points. H2O, Al2O3, Br2, F2, NaCl, IClarrow_forwardThis graph shows how the vapor pressure of three liquids varies with temperature: 900 800 700- 600 500 400 300 - cyclohexane 200 methanol 100 - isopropyl acetate 50 60 80 90 temperature, °C Use the graph to answer the following questions: Which liquid is the most volatile? most volatile: choose one Which is the least volatile? least volatile: choose one cyclohexane: What is the normal boiling point of each liquid? Note: your answer must be within 1°C of the exact answer to be graded correct. methanol: isopropyl acetate: O more Suppose a beaker of methanol is put inside a sealed tank containing methanol gas at 53. degree C and 222. torr. After ten minutes, will there be more liquid in the beaker, less liquid, or the same amount? less the same vapor pressure, torrarrow_forward
- Which one of the following exhibits dipole-dipole attraction between molecules? BeH2 C7H16 SbF5 N2 HFarrow_forwardThis graph shows how the vapor pressure of three liquids varies with temperature: 900 800 700 600 500 400 300 - cyclohexanone benzaldehyde dimethyl sulfoxide 200 100 150 160 170 180 190 temperature, °C Use the graph to answer the following questions: Which liquid is the most volatile? most volatile: choose one Which is the least volatile? least volatile: choose one cyclohexanone: What is the normal boiling point of each liquid? Note: your answer must be within 1°C of the exact answer to be graded correct. benzaldehyde: dimethyl sulfoxide: | °C Suppose a beaker of benzaldehyde is put inside a sealed tank containing benzaldehyde gas at 169. degree C and 704. torr. After ten minutes, will there be more liquid in the beaker, less liquid, or the same amount? more less the same vapor pressure, torrarrow_forwardwhich of the following should have the lowest boiling point? NH3 N2 Na2S H2O HFarrow_forward
arrow_back_ios
SEE MORE QUESTIONS
arrow_forward_ios
Recommended textbooks for you
World of Chemistry, 3rd editionChemistryISBN:9781133109655Author:Steven S. Zumdahl, Susan L. Zumdahl, Donald J. DeCostePublisher:Brooks / Cole / Cengage Learning
Principles of Modern ChemistryChemistryISBN:9781305079113Author:David W. Oxtoby, H. Pat Gillis, Laurie J. ButlerPublisher:Cengage Learning
Introductory Chemistry: A FoundationChemistryISBN:9781337399425Author:Steven S. Zumdahl, Donald J. DeCostePublisher:Cengage Learning
General Chemistry - Standalone book (MindTap Cour...ChemistryISBN:9781305580343Author:Steven D. Gammon, Ebbing, Darrell Ebbing, Steven D., Darrell; Gammon, Darrell Ebbing; Steven D. Gammon, Darrell D.; Gammon, Ebbing; Steven D. Gammon; DarrellPublisher:Cengage Learning
Chemistry: Principles and PracticeChemistryISBN:9780534420123Author:Daniel L. Reger, Scott R. Goode, David W. Ball, Edward MercerPublisher:Cengage Learning
Introductory Chemistry: An Active Learning Approa...ChemistryISBN:9781305079250Author:Mark S. Cracolice, Ed PetersPublisher:Cengage Learning
World of Chemistry, 3rd edition
Chemistry
ISBN:9781133109655
Author:Steven S. Zumdahl, Susan L. Zumdahl, Donald J. DeCoste
Publisher:Brooks / Cole / Cengage Learning
Principles of Modern Chemistry
Chemistry
ISBN:9781305079113
Author:David W. Oxtoby, H. Pat Gillis, Laurie J. Butler
Publisher:Cengage Learning
Introductory Chemistry: A Foundation
Chemistry
ISBN:9781337399425
Author:Steven S. Zumdahl, Donald J. DeCoste
Publisher:Cengage Learning
General Chemistry - Standalone book (MindTap Cour...
Chemistry
ISBN:9781305580343
Author:Steven D. Gammon, Ebbing, Darrell Ebbing, Steven D., Darrell; Gammon, Darrell Ebbing; Steven D. Gammon, Darrell D.; Gammon, Ebbing; Steven D. Gammon; Darrell
Publisher:Cengage Learning
Chemistry: Principles and Practice
Chemistry
ISBN:9780534420123
Author:Daniel L. Reger, Scott R. Goode, David W. Ball, Edward Mercer
Publisher:Cengage Learning
Introductory Chemistry: An Active Learning Approa...
Chemistry
ISBN:9781305079250
Author:Mark S. Cracolice, Ed Peters
Publisher:Cengage Learning
Liquids: Crash Course Chemistry #26; Author: Crash Course;https://www.youtube.com/watch?v=BqQJPCdmIp8;License: Standard YouTube License, CC-BY
Chemistry of Group 16 elements; Author: Ch-11 Chemical Engg, Chemistry and others;https://www.youtube.com/watch?v=5B1F0aDgL6s;License: Standard YouTube License, CC-BY