Organic Chemistry; Modified MasteringChemistry with Pearson eText -- ValuePack Access Card; Study Guide and Student Solutions Manual for Organic Chemistry, Books a la Carte Edition (7th Edition)
7th Edition
ISBN: 9780134240152
Author: Paula Yurkanis Bruice
Publisher: PEARSON
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Chapter 27.4, Problem 14P
Draw a short segment of gutta-percha.
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Identify and provide an explanation of the operational principles behind a Atomic Absorption Spectrometer (AAS). List the steps involved.
Instructions: Complete the questions in the space provided. Show all your work
1. You are trying to determine the rate law expression for a reaction that you are completing at 25°C. You measure
the initial reaction rate and the starting concentrations of the reactions for 4 trials.
BrO³¯ (aq) + 5Br¯ (aq) + 6H* (aq) → 3Br₂ (l) + 3H2O (l)
Initial rate
Trial
[BrO3]
[H*]
[Br]
(mol/L)
(mol/L) | (mol/L)
(mol/L.s)
1
0.10
0.10
0.10
8.0
2
0.20
0.10
0.10
16
3
0.10
0.20
0.10
16
4
0.10
0.10
0.20
32
a.
Based on the above data what is the rate law expression?
b. Solve for the value of k (make sure to include proper units)
2. The proposed reaction mechanism is as follows:
i.
ii.
BrО¸¯ (aq) + H+ (aq) → HBrO3 (aq)
HBrO³ (aq) + H* (aq) → H₂BrO3* (aq)
iii.
H₂BrO³* (aq) + Br¯ (aq) → Br₂O₂ (aq) + H2O (l)
[Fast]
[Medium]
[Slow]
iv.
Br₂O₂ (aq) + 4H*(aq) + 4Br(aq) → 3Br₂ (l) + H2O (l)
[Fast]
Evaluate the validity of this proposed reaction. Justify your answer.
е.
Д
CH3
D*, D20
Chapter 27 Solutions
Organic Chemistry; Modified MasteringChemistry with Pearson eText -- ValuePack Access Card; Study Guide and Student Solutions Manual for Organic Chemistry, Books a la Carte Edition (7th Edition)
Ch. 27.2 - Prob. 1PCh. 27.2 - Prob. 2PCh. 27.2 - Prob. 3PCh. 27.2 - Prob. 4PCh. 27.2 - Prob. 5PCh. 27.2 - Prob. 6PCh. 27.2 - Prob. 7PCh. 27.2 - Rank the following groups of monomers from most...Ch. 27.2 - Why does methyl methacrylate not undergo cationic...Ch. 27.2 - Explain why, when propylene oxide undergoes...
Ch. 27.2 - Prob. 11PCh. 27.2 - Which monomer and which type of initiator can you...Ch. 27.2 - Prob. 13PCh. 27.4 - Draw a short segment of gutta-percha.Ch. 27.4 - Prob. 15PCh. 27.7 - Prob. 16PCh. 27.7 - Write an equation that explains what happens if a...Ch. 27.7 - Prob. 18PCh. 27.7 - What happens to polyester slacks if aqueous NaOH...Ch. 27.7 - a. Propose a mechanism for the formation of the...Ch. 27.7 - Explain why, when a small amount of glycerol is...Ch. 27.8 - Propose a mechanism for the formation of melmac.Ch. 27.8 - Prob. 23PCh. 27.10 - Prob. 24PCh. 27 - Draw short segments of the polymers obtained from...Ch. 27 - Prob. 26PCh. 27 - Draw the structure of the monomer or monomers used...Ch. 27 - Prob. 28PCh. 27 - Draw short segments of the polymers obtained from...Ch. 27 - Quiana is a synthetic fabric that feels very much...Ch. 27 - Prob. 31PCh. 27 - Prob. 32PCh. 27 - Poly(vinyl alcohol) is a polymer used to make...Ch. 27 - Five different repeating units are found in the...Ch. 27 - Prob. 35PCh. 27 - A particularly strong and rigid polyester used for...Ch. 27 - Prob. 37PCh. 27 - Which Monomer gives a greater yield of polymer,...Ch. 27 - Prob. 39PCh. 27 - Prob. 40PCh. 27 - Why do vinyl raincoats become brittle as they get...Ch. 27 - The polymer shown below is synthesized by...Ch. 27 - Prob. 43PCh. 27 - How can head-to-head poly(vinyl bromide) be...Ch. 27 - Delrin (polyoxymethylene) is a tough...
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