ORGANIC CHEMISTRY-PRINT COMPANION (LL)
ORGANIC CHEMISTRY-PRINT COMPANION (LL)
3rd Edition
ISBN: 9781119444251
Author: Klein
Publisher: WILEY
Question
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Chapter 27, Problem 49CP

(a)

Interpretation Introduction

Interpretation:

Identify the monomer required for making the given alternating copolymer

Concept introduction:

Polymer constructed from a single type of monomer is known as homopoylmers.  If the polymer is constructed from two or more type of monomer then they are called as copolymersCarbocation is initially formed, which undergo rearrangement to a more stable carbocation.  Copolymers are usually classified based on the distribution of monomer units.  If the monomer unit is present in an alternating fashion then it is known as alternating copolymer while if it is in random fashion then it is known as random copolymer.  If the copolymer consists of homopolymer subunits connected in a block fashion then it is known as block copolymer.  If the homopolymer subunit is grafted onto another homopolymer subunit then it is known as grafter copolymer. These four types of copolymer can be represented as,

ORGANIC CHEMISTRY-PRINT COMPANION (LL), Chapter 27, Problem 49CP , additional homework tip  1

To explain : To explain why two different repeating units are present in the polymer.

(b)

Interpretation Introduction

Interpretation:

Identify the monomer required for making the given alternating copolymer

Concept introduction:

Polymer constructed from a single type of monomer is known as homopoylmers.  If the polymer is constructed from two or more type of monomer then they are called as copolymersCarbocation is initially formed, which undergo rearrangement to a more stable carbocation.  Copolymers are usually classified based on the distribution of monomer units.  If the monomer unit is present in an alternating fashion then it is known as alternating copolymer while if it is in random fashion then it is known as random copolymer.  If the copolymer consists of homopolymer subunits connected in a block fashion then it is known as block copolymer.  If the homopolymer subunit is grafted onto another homopolymer subunit then it is known as grafter copolymer. These four types of copolymer can be represented as,

ORGANIC CHEMISTRY-PRINT COMPANION (LL), Chapter 27, Problem 49CP , additional homework tip  2

To draw: To draw the structure of the repeating unit of random copolymer.

(c)

Interpretation Introduction

Interpretation:

Identify the monomer required for making the given alternating copolymer

Concept introduction:

Polymer constructed from a single type of monomer is known as homopoylmers.  If the polymer is constructed from two or more type of monomer then they are called as copolymersCarbocation is initially formed, which undergo rearrangement to a more stable carbocation.  Copolymers are usually classified based on the distribution of monomer units.  If the monomer unit is present in an alternating fashion then it is known as alternating copolymer while if it is in random fashion then it is known as random copolymer.  If the copolymer consists of homopolymer subunits connected in a block fashion then it is known as block copolymer.  If the homopolymer subunit is grafted onto another homopolymer subunit then it is known as grafter copolymer. These four types of copolymer can be represented as,

ORGANIC CHEMISTRY-PRINT COMPANION (LL), Chapter 27, Problem 49CP , additional homework tip  3

To justify: To justify whether 3,3-dimethyl-1-butene produce random copolymer

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