Organic Chemistry
Organic Chemistry
3rd Edition
ISBN: 9781119338352
Author: Klein
Publisher: WILEY
Question
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Chapter 27, Problem 49CP

(a)

Interpretation Introduction

Interpretation:

Identify the monomer required for making the given alternating copolymer

Concept introduction:

Polymer constructed from a single type of monomer is known as homopoylmers.  If the polymer is constructed from two or more type of monomer then they are called as copolymersCarbocation is initially formed, which undergo rearrangement to a more stable carbocation.  Copolymers are usually classified based on the distribution of monomer units.  If the monomer unit is present in an alternating fashion then it is known as alternating copolymer while if it is in random fashion then it is known as random copolymer.  If the copolymer consists of homopolymer subunits connected in a block fashion then it is known as block copolymer.  If the homopolymer subunit is grafted onto another homopolymer subunit then it is known as grafter copolymer. These four types of copolymer can be represented as,

Organic Chemistry, Chapter 27, Problem 49CP , additional homework tip  1

To explain : To explain why two different repeating units are present in the polymer.

(b)

Interpretation Introduction

Interpretation:

Identify the monomer required for making the given alternating copolymer

Concept introduction:

Polymer constructed from a single type of monomer is known as homopoylmers.  If the polymer is constructed from two or more type of monomer then they are called as copolymersCarbocation is initially formed, which undergo rearrangement to a more stable carbocation.  Copolymers are usually classified based on the distribution of monomer units.  If the monomer unit is present in an alternating fashion then it is known as alternating copolymer while if it is in random fashion then it is known as random copolymer.  If the copolymer consists of homopolymer subunits connected in a block fashion then it is known as block copolymer.  If the homopolymer subunit is grafted onto another homopolymer subunit then it is known as grafter copolymer. These four types of copolymer can be represented as,

Organic Chemistry, Chapter 27, Problem 49CP , additional homework tip  2

To draw: To draw the structure of the repeating unit of random copolymer.

(c)

Interpretation Introduction

Interpretation:

Identify the monomer required for making the given alternating copolymer

Concept introduction:

Polymer constructed from a single type of monomer is known as homopoylmers.  If the polymer is constructed from two or more type of monomer then they are called as copolymersCarbocation is initially formed, which undergo rearrangement to a more stable carbocation.  Copolymers are usually classified based on the distribution of monomer units.  If the monomer unit is present in an alternating fashion then it is known as alternating copolymer while if it is in random fashion then it is known as random copolymer.  If the copolymer consists of homopolymer subunits connected in a block fashion then it is known as block copolymer.  If the homopolymer subunit is grafted onto another homopolymer subunit then it is known as grafter copolymer. These four types of copolymer can be represented as,

Organic Chemistry, Chapter 27, Problem 49CP , additional homework tip  3

To justify: To justify whether 3,3-dimethyl-1-butene produce random copolymer

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> You are trying to decide if there is a single reagent you can add that will make the following synthesis possible without any other major side products: 1. ☑ CI 2. H3O+ O Draw the missing reagent X you think will make this synthesis work in the drawing area below. If there is no reagent that will make your desired product in good yield or without complications, just check the box under the drawing area and leave it blank. Click and drag to start drawing a structure. Explanation Check ? DO 18 Ar B © 2025 McGraw Hill LLC. All Rights Reserved. Terms of Use | Privacy Center | Accessibility
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Consider a solution of 0.00304 moles of 4-nitrobenzoic acid (pKa = 3.442) dissolved in 25 mL water and titrated with 0.0991 M NaOH. Calculate the pH at the equivalence point
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