(a) Interpretation: The structure of (R)- and (S)-penicillamine is to be drawn. Concept introduction: The chemical compounds in which carbon is bonded with acidic and basic group along with hydrocarbon side chain are known as amino acids. The configuration of compound is R and S when the substituents around stereogenic center, from higher priority to lower priority, are present in clockwise and anticlockwise direction, respectively.

Question

Want to see the full answer?

Answer 1

Question

Chapter 27, Problem 31P

Interpretation Introduction

(a)

Interpretation: The structure of (R)- and (S)-penicillamine is to be drawn.

Concept introduction: The chemical compounds in which carbon is bonded with acidic and basic group along with hydrocarbon side chain are known as amino acids. The configuration of compound is R and S when the substituents around stereogenic center, from higher priority to lower priority, are present in clockwise and anticlockwise direction, respectively.

Interpretation Introduction

(b)

Interpretation: The disulfide formed by the oxidation of (S)-penicillamine is to be predicted.

Concept introduction: The chemical compounds in which carbon is bonded with acidic and basic group along with hydrocarbon side chain are known as amino acids. A disulphide bond is formed when two amino acids containing −SH group undergoes oxidation.

Expert Solution & Answer

Want to see the full answer?

Check out a sample textbook solution

See solution

Students have asked these similar questions

The carbonyl group on D-glucose can be reduced to d-glucitol. Identify the reagents that can chrry out this reduction. A.water in acidic solution B. hydrogen with a Platinum catalyst (Hy/Pt) C. Sodium dichromate (NaCr2O) in acidic solution D. Benedict’s reagent E. Enzymes

1. Biogenic Amines are inactivated primarily by a. Sulfonation b. Glucoronidation c. Aromatic hydroxylation d. Methylation 2. A drug can exert its pharmacological effect only if it is a. Protein bound b. Protein unbound c. Free drug d. Both B & C e. Both A & C 3. In order for the drug to be ready and available for absorption, it must be release first from its dosage form with the exception of: a. Capsule b. Tablet c. Solution d. Suspension 4. All of the following are true, except a. Solubility increase with decrease particle size b. Solubility increase with increase surface area c. Solubility increase with increase particle size d. Solubility decrease with decrease surface area 5. The rate in which the drug appears in the bloodstream is also known as a. Half-life b. Potency c. Bioavailability d. Area under the curve

Chemistry Question

Answer 2

Question

Chapter 27, Problem 31P

Interpretation Introduction

(a)

Interpretation: The structure of (R)- and (S)-penicillamine is to be drawn.

Concept introduction: The chemical compounds in which carbon is bonded with acidic and basic group along with hydrocarbon side chain are known as amino acids. The configuration of compound is R and S when the substituents around stereogenic center, from higher priority to lower priority, are present in clockwise and anticlockwise direction, respectively.

Interpretation Introduction

(b)

Interpretation: The disulfide formed by the oxidation of (S)-penicillamine is to be predicted.

Concept introduction: The chemical compounds in which carbon is bonded with acidic and basic group along with hydrocarbon side chain are known as amino acids. A disulphide bond is formed when two amino acids containing −SH group undergoes oxidation.

Expert Solution & Answer

Want to see the full answer?

Check out a sample textbook solution

See solution

Answer 3

Question

Chapter 27, Problem 31P

Interpretation Introduction

(a)

Interpretation: The structure of (R)- and (S)-penicillamine is to be drawn.

Concept introduction: The chemical compounds in which carbon is bonded with acidic and basic group along with hydrocarbon side chain are known as amino acids. The configuration of compound is R and S when the substituents around stereogenic center, from higher priority to lower priority, are present in clockwise and anticlockwise direction, respectively.

Interpretation Introduction

(b)

Interpretation: The disulfide formed by the oxidation of (S)-penicillamine is to be predicted.

Concept introduction: The chemical compounds in which carbon is bonded with acidic and basic group along with hydrocarbon side chain are known as amino acids. A disulphide bond is formed when two amino acids containing −SH group undergoes oxidation.

Expert Solution & Answer

Want to see the full answer?

Check out a sample textbook solution

See solution

Answer 4

Question

Chapter 27, Problem 31P

Interpretation Introduction

(a)

Interpretation: The structure of (R)- and (S)-penicillamine is to be drawn.

Concept introduction: The chemical compounds in which carbon is bonded with acidic and basic group along with hydrocarbon side chain are known as amino acids. The configuration of compound is R and S when the substituents around stereogenic center, from higher priority to lower priority, are present in clockwise and anticlockwise direction, respectively.

Interpretation Introduction

(b)

Interpretation: The disulfide formed by the oxidation of (S)-penicillamine is to be predicted.

Concept introduction: The chemical compounds in which carbon is bonded with acidic and basic group along with hydrocarbon side chain are known as amino acids. A disulphide bond is formed when two amino acids containing −SH group undergoes oxidation.

Expert Solution & Answer

Want to see the full answer?

Check out a sample textbook solution

See solution

Answer 5

Chapter 27, Problem 31P

Interpretation Introduction

(a)

Interpretation: The structure of (R)- and (S)-penicillamine is to be drawn.

Concept introduction: The chemical compounds in which carbon is bonded with acidic and basic group along with hydrocarbon side chain are known as amino acids. The configuration of compound is R and S when the substituents around stereogenic center, from higher priority to lower priority, are present in clockwise and anticlockwise direction, respectively.

Interpretation Introduction

(b)

Interpretation: The disulfide formed by the oxidation of (S)-penicillamine is to be predicted.

Concept introduction: The chemical compounds in which carbon is bonded with acidic and basic group along with hydrocarbon side chain are known as amino acids. A disulphide bond is formed when two amino acids containing −SH group undergoes oxidation.

Answer 6

Chapter 27, Problem 31P

Interpretation Introduction

(a)

Interpretation: The structure of (R)- and (S)-penicillamine is to be drawn.

Concept introduction: The chemical compounds in which carbon is bonded with acidic and basic group along with hydrocarbon side chain are known as amino acids. The configuration of compound is R and S when the substituents around stereogenic center, from higher priority to lower priority, are present in clockwise and anticlockwise direction, respectively.

Answer 7

Chapter 27, Problem 31P

Interpretation Introduction

(a)

Interpretation: The structure of (R)- and (S)-penicillamine is to be drawn.

Concept introduction: The chemical compounds in which carbon is bonded with acidic and basic group along with hydrocarbon side chain are known as amino acids. The configuration of compound is R and S when the substituents around stereogenic center, from higher priority to lower priority, are present in clockwise and anticlockwise direction, respectively.

Answer 8

Interpretation Introduction

(b)

Interpretation: The disulfide formed by the oxidation of (S)-penicillamine is to be predicted.

Concept introduction: The chemical compounds in which carbon is bonded with acidic and basic group along with hydrocarbon side chain are known as amino acids. A disulphide bond is formed when two amino acids containing −SH group undergoes oxidation.

Answer 9

Interpretation Introduction

(b)

Interpretation: The disulfide formed by the oxidation of (S)-penicillamine is to be predicted.

Concept introduction: The chemical compounds in which carbon is bonded with acidic and basic group along with hydrocarbon side chain are known as amino acids. A disulphide bond is formed when two amino acids containing −SH group undergoes oxidation.

Answer 10

Expert Solution & Answer

Answer 11

Expert Solution & Answer

Answer 12

Want to see the full answer?

Check out a sample textbook solution

See solution

Answer 13

Ch. 27.1 - Prob. 1P Ch. 27.1 - Problem 29.2 What form exists at the isoelectric...Ch. 27.1 - Problem 29.3 Explain why the of the group of an...Ch. 27.1 - Prob. 4P Ch. 27.2 - Problem 29.5 What -halo carbonyl compound is...Ch. 27.2 - Problem 29.6 The enolate derived from diethyl...Ch. 27.2 - Problem 29.7 What amino acid is formed when is...Ch. 27.2 - Problem 29.8 What aldehyde is needed to synthesize...Ch. 27.2 - Problem 29.9 Draw the products of each...Ch. 27.3 - Prob. 10P

Concept explainers

Want to see the full answer?

Chapter 27 Solutions