ORG CHEM CONNECT CARD
6th Edition
ISBN: 9781264860746
Author: SMITH
Publisher: MCG
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Chapter 27, Problem 28P
With reference to the following peptide: (a) Identify the
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7. The standard reduction potentials for two half-reactions are shown above. Which of the
statements listed below will be true for the following reaction taking place under standard
conditions?
a. E°
b. E°
c. E°
=
d. E°
e. E° =
Al (s) + Cr³+
→ Al³+ + Cr (s)
0.93 V, and the reaction is not spontaneous
0.93 V, and the reaction is spontaneous
2.39 V, and the reaction is not spontaneous
2.39 V, and the reaction is not spontaneous
0.93 V, and the reaction is spontaneous
Cu2+ + 2e
→ Cu
E° = +0.34 V
Zn2+ + 2e
→ Zn
E° = -0.76 V
E° = -1.18 V
Mn2+ + 2e → Mn
8. Based on the above reduction potential, which of the following reactions will occur
spontaneously?
a. Mn²+ + Cu → Mn + Cu2+
b. Mn²+ + Zn → Mn + Zn²+
c. Zn2+ + Cu → Zn + Cu²+
d. Zn²+ + Mn → Zn + Mn2+
e. Cu²+ + Zn²+ → Cu + Zn
14.35 For which compounds can a second resonance structure be drawn?
Draw an additional resonance structure and the hybrid for each
resonance-stabilized compound.
a.
OCH3
OCH 3
b.
C.
d.
CH3
NHCH3
pls help on all, inlcude all steps.
Chapter 27 Solutions
ORG CHEM CONNECT CARD
Ch. 27.1 - Prob. 1PCh. 27.1 - Problem 29.2
What form exists at the isoelectric...Ch. 27.1 - Problem 29.3
Explain why the of the group of an...Ch. 27.1 - Prob. 4PCh. 27.2 - Problem 29.5
What -halo carbonyl compound is...Ch. 27.2 - Problem 29.6
The enolate derived from diethyl...Ch. 27.2 - Problem 29.7
What amino acid is formed when is...Ch. 27.2 - Problem 29.8
What aldehyde is needed to synthesize...Ch. 27.2 - Problem 29.9
Draw the products of each...Ch. 27.3 - Prob. 10P
Ch. 27.3 - Prob. 11PCh. 27.3 - Prob. 12PCh. 27.4 - Problem 29.13
What alkene is needed to synthesize...Ch. 27.5 - Problem 29.14
Draw the structure of each peptide....Ch. 27.5 - Problem 29.15
Name each peptide using both the...Ch. 27 - Draw the product formed when the following amino...Ch. 27 - With reference to the following peptide: a...Ch. 27 - Prob. 31PCh. 27 - Histidine is classified as a basic amino acid...Ch. 27 - Tryptophan is not classified as a basic amino acid...Ch. 27 - What is the structure of each amino acid at its...Ch. 27 - What is the predominant form of each of the...Ch. 27 - 29.37 What is the predominant form of each of the...Ch. 27 - a. Draw the structure of the tripeptide A–A–A, and...Ch. 27 - 29.39 Draw the organic products formed in each...Ch. 27 - 29.40 What alkyl halide is needed to synthesize...Ch. 27 - Prob. 50PCh. 27 - Draw the structure for each peptide: (a) Phe–Ala;...Ch. 27 - 29.52 For the tetrapeptide Asp–Arg–Val–Tyr:
a....Ch. 27 - Prob. 53PCh. 27 - Prob. 54PCh. 27 - 29.55 Draw the amino acids and peptide fragments...Ch. 27 - Prob. 56PCh. 27 - Prob. 57PCh. 27 - Prob. 58PCh. 27 - 29.59 An octapeptide contains the following amino...Ch. 27 - 29.60 Draw the organic products formed in each...Ch. 27 - 29.65 Draw the mechanism for the reaction that...Ch. 27 - 29.66 Which of the following amino acids are...Ch. 27 - 29.67 After the peptide chain of collagen has been...Ch. 27 - Prob. 68PCh. 27 - Prob. 69PCh. 27 - 29.70 The anti-obesity drug orlistat works by...Ch. 27 - Prob. 71P
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