OWLv2 for Bettelheim/Brown/Campbell/Farrell/Torres' Introduction to General, Organic and Biochemistry, 11th Edition, [Instant Access], 1 term (6 months)
11th Edition
ISBN: 9781305106734
Author: Frederick A. Bettelheim; William H. Brown; Mary K. Campbell; Shawn O. Farrell; Omar Torres
Publisher: Cengage Learning US
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Question
Chapter 27, Problem 27.60P
Interpretation Introduction
(a)
Interpretation:
Draw the structure differences between the ATP and GTP.
Concept Introduction:
ATP and GTP are primary source of biochemical reactions.
ATP − Adenosine tri phosphate.
GTP- Guanosine tri phosphate.
Interpretation Introduction
(b)
Interpretation:
Compared with ATP, would you expect GTP to carry more, less or about the sameamount of energy.
Concept Introduction:
ATP and GTP are primary source of biochemical reactions.
ATP − Adenosine tri phosphate.
GTP- Guanosine tri phosphate.
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Part VII. The H-NMR of a compound with molecular formula C5 H 10 O2 is given below.
Find the following:
(a) The no. of protons corresponding to each signal in the spectra
(6) Give the structure of the compound and assign the signals to each
proton in the compound.
a
70.2
Integration Values
C5H10O2
b
47.7
C
46.5
d
69.5
3.6 3.5
3.4 3.3 3.2 3.1 3.0
2.9 2.8
2.7
2.6 2.5
2.4 2.3 2.2 2.1 2.0
Chemical Shift (ppm)
1.9
1.8
1.7 1.6
1.5
1.4 1.3 1.2
1.1 1.0
0.9 0.8
Part 111. 1 H-NMR spectrum of a compound with integration values in red is given below.
Answer the following:
(a) write the signals in the 'H-NMR spectrum to the corresponding protons on the structure
of the molecule below.
(b) Identify the theoretical multiplicities for each proton in the compound. Also give the possible.
complex splitting patterns assuming J values are not similar.
там
Br
22
2
3
6
4 7.2 7.0 6.8 6.6 6.4 6.2 6.0 5.8 5.6 5.4 5.2 5.0 4.8 4.6 4.4 4.2 4.0 3.8 3.6 3.4 3.2 3.0 2.8 2.6 2.4 2.2 2.0 1.8 1.6 1.4 1.2 1.0 0.8 0
Chemical Shift (ppm)
ra.
Br
2
3
6
6
2.5
2.4
2.3
2.2
2.1
2.0
1.9
1.8
1.7
1.6
1.5
1.4
1.3
1.2
1.1
1.0
0.9
0.8
Chemical Shift (ppm)
2
2
Br
7.3
7.2
7.1
7.0 6.9
6.7 6.6 6.5
6.4
6.3
6.2
6.1
6.0
Chemical Shift (ppm)
5.9
5.8 5.7
5.5 5.4 5.3 5.2
5.0 4.9
1600°
1538°C
1493°C
In the diagram, the letter L indicates
that it is a liquid. Indicate its
components in the upper region
where only L is indicated.
The
iron-iron carbide phase
diagram.
Temperature (°C)
1400
8
1394°C
y+L
1200
2.14
y, Austenite
10000
912°C
800a
0.76
0.022
600
400
(Fe)
a, Ferrite
Composition (at% C)
15
1147°C
a + Fe3C
2
3
Composition (wt% C)
L
2500
4.30
2000
y + Fe3C
727°C
1500
Cementite (Fe3C)
1000
4
5
6
6.70
Temperature (°F)
Chapter 27 Solutions
OWLv2 for Bettelheim/Brown/Campbell/Farrell/Torres' Introduction to General, Organic and Biochemistry, 11th Edition, [Instant Access], 1 term (6 months)
Ch. 27 - Prob. 27.1PCh. 27 - Prob. 27.2PCh. 27 - (a) How many membranes do mitochondria have? (b)...Ch. 27 - Prob. 27.4PCh. 27 - Prob. 27.5PCh. 27 - Prob. 27.6PCh. 27 - Prob. 27.7PCh. 27 - Prob. 27.8PCh. 27 - Prob. 27.9PCh. 27 - Prob. 27.10P
Ch. 27 - What kind of chemical bond exists between the...Ch. 27 - Prob. 27.12PCh. 27 - Which atoms in the flavin portion of FAD are...Ch. 27 - NAD+ has two ribose units in its structure; FAD...Ch. 27 - Prob. 27.15PCh. 27 - The ribitol in FAD is bound to phosphate. What is...Ch. 27 - What kind Of chemical bond exists between the...Ch. 27 - Prob. 27.18PCh. 27 - Prob. 27.19PCh. 27 - Prob. 27.20PCh. 27 - Prob. 27.21PCh. 27 - Prob. 27.22PCh. 27 - Prob. 27.23PCh. 27 - Prob. 27.24PCh. 27 - Prob. 27.25PCh. 27 - Prob. 27.26PCh. 27 - Prob. 27.27PCh. 27 - Prob. 27.28PCh. 27 - Prob. 27.29PCh. 27 - Prob. 27.30PCh. 27 - Prob. 27.31PCh. 27 - Prob. 27.32PCh. 27 - Prob. 27.33PCh. 27 - Prob. 27.34PCh. 27 - Prob. 27.35PCh. 27 - Prob. 27.36PCh. 27 - Prob. 27.37PCh. 27 - Prob. 27.38PCh. 27 - Prob. 27.39PCh. 27 - Prob. 27.40PCh. 27 - Prob. 27.41PCh. 27 - Prob. 27.42PCh. 27 - Prob. 27.43PCh. 27 - Prob. 27.44PCh. 27 - Prob. 27.45PCh. 27 - Prob. 27.46PCh. 27 - Prob. 27.47PCh. 27 - Prob. 27.48PCh. 27 - Prob. 27.49PCh. 27 - A hexose (C6) enters the common metabolic pathway...Ch. 27 - Prob. 27.51PCh. 27 - Prob. 27.52PCh. 27 - Prob. 27.53PCh. 27 - Prob. 27.54PCh. 27 - (Chemical Connections 27A) Oligomycin is an anti-...Ch. 27 - Prob. 27.56PCh. 27 - Prob. 27.57PCh. 27 - Prob. 27.58PCh. 27 - Prob. 27.59PCh. 27 - Prob. 27.60PCh. 27 - Prob. 27.61PCh. 27 - What is the basic difference in the functional...Ch. 27 - Prob. 27.63PCh. 27 - Prob. 27.64PCh. 27 - Prob. 27.65PCh. 27 - Prob. 27.66PCh. 27 - Prob. 27.67PCh. 27 - Prob. 27.68PCh. 27 - Prob. 27.69PCh. 27 - Prob. 27.70PCh. 27 - Prob. 27.71PCh. 27 - Prob. 27.72PCh. 27 - Prob. 27.73PCh. 27 - Prob. 27.74PCh. 27 - Prob. 27.75PCh. 27 - Prob. 27.76PCh. 27 - Prob. 27.77PCh. 27 - Prob. 27.78PCh. 27 - Some soft drinks contain citric acid as flavoring....Ch. 27 - Prob. 27.80PCh. 27 - Prob. 27.81PCh. 27 - Prob. 27.82PCh. 27 - Prob. 27.83PCh. 27 - Prob. 27.84PCh. 27 - Prob. 27.85PCh. 27 - Prob. 27.86PCh. 27 - Prob. 27.87PCh. 27 - Prob. 27.88PCh. 27 - Prob. 27.89PCh. 27 - Why is it somewhat misleading to study biochemi-...Ch. 27 - Prob. 27.91PCh. 27 - Prob. 27.92PCh. 27 - Prob. 27.93PCh. 27 - Prob. 27.94PCh. 27 - Prob. 27.95PCh. 27 - Prob. 27.96PCh. 27 - Prob. 27.97PCh. 27 - Prob. 27.98PCh. 27 - Prob. 27.99PCh. 27 - Prob. 27.100PCh. 27 - Prob. 27.101PCh. 27 - Prob. 27.102PCh. 27 - Prob. 27.103PCh. 27 - Prob. 27.104P
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